Hostname: page-component-7bb8b95d7b-l4ctd Total loading time: 0 Render date: 2024-09-11T23:17:49.892Z Has data issue: false hasContentIssue false
  • English
  • Français

Reactions of expanding-lattice clay minerals with glycerol and ethylene glycol

Published online by Cambridge University Press:  14 March 2018

G. F. Walker
G. F. Walker*
Affiliation:
C.S.I.R.O., Chemical Research Laboratories, Melbourne, Australia
Get access

Abstract

Under certain circumstances, both glycerol and ethylene glycol form interlayer complexes with vermiculites resembling those formed with the smectites. The rate and degree of complex formation are related to the surface charge on the silicate layers, to the type of interlayer cation present and to crystal size. With glycerol, but not with ethylene glycol, the hydration state of the mineral immediately prior to complex formation is of some importance.

Type
Research Article
Information
Clay Minerals Bulletin , Volume 3 , Issue 20 , December 1958 , pp. 302 - 313
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1958

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Barshad, I. 1950. Amer. Min., 35, 225-38.Google Scholar
Bradley, W. F. 1945a. J. Amer. chem. Soc, 67, 975-81.CrossRefGoogle Scholar
Bradley, W. F. 1945b. Amer. Min., 30, 704-13.Google Scholar
Bradley, W. F. 1950. Proc. Fourth Int. Conf. Soil Sci. (Amsterdam), 1, 101-5.Google Scholar
MacEwan, D. M. C. 1944. Nature, Lond., 154, 577.Google Scholar
MacEwan, D. M. C. 1946. J. Soc. Chem. Ind., 65, 298-305.Google Scholar
MacEwan, D. M. C. 1951. Chap. IV. in “X-ray Identification and Structures of Clay Minerals,” Miner. Soc. Monograph, London.Google Scholar
Mathieson, A. McL. 1958. Amer. Min., 43, 216-27.Google Scholar
Mathieson, A. McL. and Walker, G. F. 1954. Amer. Min., 29, 231-55.Google Scholar
Walker, G. F. 1951. Chap. VII in “X-ray Identification and Structures of Clay Minerals,” Miner. Soc. Monograph, London.Google Scholar
Walker, G. F. 1956. Proc. Fourth Nat. Conf. Clays(Penn. State), 101-15.Google Scholar
Walker, G. F. 1957. Clay Min. Bull., 3, 154-63.Google Scholar
Walker, G. F. and Cole, W. F. 1957. Chap. VII in “The Differential Thermal Analysis of Clays,” Miner. Soc. Monograph, London.Google Scholar
Weiss, von A., Koch, G. and Hofmann, U. 1955. Ber. dtsch. keram. Ges., 32, 12-7.Google Scholar
Wesson, L. G. 1948. Tables of Electric Dipole Moments. Technology Press, M.I.T.Google Scholar