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The oxides and hydroxides of iron and their structural inter-relationships

Published online by Cambridge University Press:  14 March 2018

J. D. Bernal ,
D. R. Dasgupta  and
A. L. Mackay
J. D. Bernal
Affiliation:
Birkbeck College, 21 Torrington Square, LondonW.C.I.
D. R. Dasgupta
Affiliation:
Birkbeck College, 21 Torrington Square, LondonW.C.I.
A. L. Mackay
Affiliation:
Birkbeck College, 21 Torrington Square, LondonW.C.I.
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Abstract

The transformations in the iron oxide-hydroxide system have been interpreted in a rational crystallochemical manner, some being characterized as topotactic and some as non-topotactic. Crystallographic measurements have been made on the more reactive or metastable phases, particularly on the “green rusts.” The oxyhydroxides β-FeOOH and δ-FeOOH have been examined more fully, but data on all the phases have been checked. New data on transformations, such as FeCO3 → FeO and Fe(OH)2 → FeO are reported.

Type
Research Article
Information
Clay Minerals Bulletin , Volume 4 , Issue 21 , August 1959 , pp. 15 - 30
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1959

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