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Interpretation of D.T.A. diagrams: the low temperature endothermic peak

Published online by Cambridge University Press:  14 March 2018

R. Greene-Kelly*
Affiliation:
Pedology Department, Rothamsted Experimental Station, Harpenden, Herts.
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Extract

Differential thermal analysis has been used by Hendricks, Nelson and Alexander (1940) to study the sorption of water by montmorillonite. They measured the water uptake at a number of different relative humidities and then traced the low temperature endothermic peak of the resultant material on a differential thermal apparatus. They found that the resultant curves of Mg, Ca, Sr, Ba and Li-montmorillonite showed a division into two components at low relative humidities. Assuming that the area under the D.T.A. curve was proportional to the weight of water lost, a division of the total sorbed water was made between the two peaks. The authors found that for Mg2+, Ca2+, Sr2+ and Ba2+ the high temperature component represented approximately 5—6 water molecules per exchange ion, whilst for Li+ it corresponded to 3·3 water molecules per exchange ion.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1953

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References

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