A continuous, detailed, 200-years record of the anionic species, chloride, nitrate and sulphate, has been measured on an ice core from Dolleman Island (70°35.2′ S, 60°55.5′ W), Antarctic Peninsula. The site lies on the east coast of the Peninsula, and the chemistry of the core is dominated by the changing pattern of sea-ice distribution and storm activity in the Wed dell Sea. Strong annual cycles in chloride and non sea salt sulphate reflect the dominance of the seasonal cycle in sea-ice distribution in the Weddell Sea, observed in time series derived from satellite imagery since the early 1970s. However, in the case of chloride there is also an exceptionally strong interannual variability, which in many parts of the core dominates the seasonal cycle.

Secular variations in the sea-ice extent appear to have a strong influence on the climate of the region and may play a major role in determining how long-term climate change in the Antarctic Peninsula relates to global climate change. The paper examines documented evidence for sea-ice extent in the Weddell Sea sector, and evaluates the usefulness of ice-core data for reconstructing this parameter in the earlier period.