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An Evaluation of Correction Algorithms, Using Theoretically Calculated Intensities

Published online by Cambridge University Press:  06 March 2019

Bruno A. R. Vrebos  and
J. A. Helsen
Bruno A. R. Vrebos
Affiliation:
Dept. Metallurgy and Materials Engineering Katholieke Universiteit Leuven, De Croylaan 2 3030 Heverlee (Belgium)
J. A. Helsen
Affiliation:
Dept. Metallurgy and Materials Engineering Katholieke Universiteit Leuven, De Croylaan 2 3030 Heverlee (Belgium)
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Extract

Several correction algorithms (Lachance & Traill (L-T), Rasberry & Heinrich (R-H), Lachance & Claisse (L-C) and Claisse & Quintin (C-Q) have been inter compared. All these algorithms assume that the effects of the matrixelements can be added in a linear way. Tertian, however, has shown that this is perfectly valid only when absorption is the only interelement effect to be taken into account. When enhancement is involved, corrections for crossed-effects are necessary. We have also evaluated the application of crossed-effect correction. Calculations were done, using theoretically calculated relative intensities. Influence coefficients were calculated by a regression method.

Type
II. Mathematical Models and Computer Applications in XRF
Information
Advances in X-Ray Analysis , Volume 28: Thirty-Third Annual Conference on Applications of X-ray Analysis, July 30 - August 3, 1984 , 1984 , pp. 31 - 35
Copyright
Copyright © International Centre for Diffraction Data 1984

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References

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