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CHAPTER XII - ELECTRIC RESISTANCE OF SUBSTANCES

Published online by Cambridge University Press:  05 July 2011

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Summary

359.] There are three classes in which we may place different substances in relation to the passage of electricity through them.

The first class contains all the metals and their alloys, some sulphurets, and other compounds containing metals, to which we must add carbon in the form of gas-coke, and selenium in the crystalline form.

In all these substances conduction takes place without any decomposition, or alteration of the chemical nature of the substance, either in its interior or where the current enters and leaves the body. In all of them the resistance increases as the temperature rises.

The second class consists of substances which are called electrolytes, because the current is associated with a decomposition of the substance into two components which appear at the electrodes. As a rule a substance is an electrolyte only when in the liquid form, though certain colloid substances, such as glass at 100°C, which are apparently solid, are electrolytes. It would appear from the experiments of Sir B. C. Brodie that certain gases are capable of electrolysis by a powerful electromotive force.

In all substances which conduct by electrolysis the resistance diminishes as the temperature rises.

The third class consists of substances the resistance of which is so great that it is only by the most refined methods that the passage of electricity through them can be detected. These are called Dielectrics.

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Publisher: Cambridge University Press
Print publication year: 2010
First published in: 1873

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