Principle and overview

Phenomenology

Optical pumping (Happer 1972) is one of the earliest examples wherein optical radiation qualitatively modifies the properties of a material system. In its original implementation, it corresponds to a selective population of specific angular momentum states, starting from thermal equilibrium.

In the idealised process depicted in Figure 5.1, the light brings the atomic system from the initially disordered state, in which the populations of degenerate levels are equal, into an ordered state where the internal state of all atoms is the same. If we consider only the material system, it appears as if the evolution from the initially disordered state into an ordered state, where the population of one level is higher than that of another level, violated the second law of thermodynamics. This process does not proceed spontaneously, however. It is the interaction with polarised light that drives the system and increased disorder in the radiation field compensates for the increase in the population difference in the material system (Enk and Nienhuis 1992).