We have observed 79 supernova remnants (SNRs) with the Urumqi 25 m telescope at λ6 cm during the Sino-German λ6 cm polarization survey of the Galactic plane. We measured flux densities of SNRs at λ6 cm, some of which are the first ever measured or the measurements at the highest frequency, so that we can determine or improve spectra of SNRs. Our observations have ruled out spectral breaks or spectral flattening that were suggested for a few SNRs, and confirmed the spectral break of S147. By combining our λ6 cm maps with λ11 cm and λ21 cm maps from the Effelsberg 100 m telescope, we calculated the spectral index maps of several large SNRs. For many remnants we obtained for the first time polarization images, which show the intrinsic magnetic field structures at λ6 cm. We disapproved three objects as being SNRs, OA184, G192.8−1.1 and G16.8−1.1, which show a thermal spectrum and no polarization. We have discovered two large supernova remnants, G178.2−4.2 and G25.1−2.3., in the survey maps.