Hostname: page-component-848d4c4894-8bljj Total loading time: 0 Render date: 2024-06-28T18:41:28.000Z Has data issue: false hasContentIssue false
  • English
  • Français

Powder X-ray diffraction of oriented and intercalated lead iodide

Published online by Cambridge University Press:  05 March 2012

Richard W. Schaeffer  and
Monica Ardelean
Richard W. Schaeffer*
Affiliation:
Chemistry Department, Franklin and Marshall College, Lancaster, Pennsylvania 17604
Monica Ardelean
Affiliation:
Chemistry Department, Franklin and Marshall College, Lancaster, Pennsylvania 17604
*
a)Author to whom correspondence should be addressed; electronic mail: R_Schaeffer@fandm.edu
Get access Rights & Permissions [Opens in a new window]

Abstract

Polycrystalline lead iodide, PbI2, was recrystallized from hot water to reproducibly obtain flat plate-like crystals, which manifested extreme preferred orientation greatly favoring the 001, 002, 003, and 004 planes. Polycrystalline samples of PbI2 were intercalated with tripropylamine, simultaneously producing a “new” intercalate 001 peak at 7.791°2θ (d=1.1347 nm) and diminishing the host PbI2 001 peak at 12.67°2θ (d=0.6980 nm). This is consistent with large increases in the c direction of the unit cell associated with inserting a guest between adjacent iodide layers of the host PbI2. Experimental powder diffraction results are compared to theoretical values calculated using CRYSTALMAKER and CRYSTALDIFFRACT software

Keywords

X-ray diffractionlead(II) iodideintercalationguest–host interactionspreferred orientationlayered materials
Type
Technical Articles
Information
Powder Diffraction , Volume 16 , Issue 1 , March 2001 , pp. 16 - 19
Copyright
Copyright © Cambridge University Press 2001

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Coleman, C. C., Goldwhite, H., and Tikanen, W. (1998). “A Review of Intercalation in Heavy Metal Iodides,” Chem. Mater. CMATEX 10, 2794–2800. cma, CMATEXCrossRefGoogle Scholar
International Tables for X-ray Crystallography, Vol. C: Mathematical, Physical, and Chemical Tables, edited by A. J. C. Wilson (Kluwer, Dordrecht, 1992).Google Scholar
Levy, F. (1976). Crystallography and Crystal Chemistry of Materials with Layered Structures (Reidel, Dordrecht).CrossRefGoogle Scholar
Mak, T. C. W., and Zhou, G. D. (1992). Crystallography in Modern Chemistry: A Resource Book of Crystal Structures (Wiley, New York).Google Scholar
Palmer, D. (2000). CRYSTALMAKER: Intercative Software for MacOS, P.O. Box 183, Bicester, Oxfordshire, OX6 7BS, UK. Information and demonstration available at www.crystalmaker.co.uk.Google Scholar
PDF-2 (1996). International Centre for Diffraction Data, Newtown Square, PA, pattern number 07-0235.Google Scholar
Rao, C. N. R. (1994). Chemical Approaches to the Synthesis of Inorganic Materials (Wiley, New York).CrossRefGoogle Scholar
Warren, R. F., and Liang, W. Y. (1993). “Raman Spectroscopy of New Lead Iodide Intercalation Compounds,” Phys. Rev. B JCOMEL 5, 6407–6418. jcz, JCOMEL Google Scholar