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A study of temperature and pressure induced structural and electronic changes in SbCl5 intercalated graphite: Part II. Experimental data for c-axis resistivity

  • O.E. Andersson (a1), B. Sundqvist (a1), E. McRae (a2), J.F. Marêché (a2) and M. Lelaurain (a2)...

Abstract

We present experimental data for the c-axis resistivity ρc of stage s = 2, 3, 4, 5, and 8, SbCl5 intercalated graphite, over the temperature range 40 to 300 K and the pressure range 0 to 0.8 GPa (0–8 kbar). For most specimens studied, resistance anomalies are observed below 230 K at atmospheric pressure and at pressures up to 0.5 GPa at 293 K. These anomalies are explained in terms of structural changes from a disordered or partly crystallized in-plane intercalate structure at atmospheric pressure and T > 230 K to an almost completely crystallized structure below this temperature, or at elevated pressures, as discussed in a companion paper. In the crystallized phases ρc is approximately linear in T except for stage 8, for which a nonlinear behavior, with a negative temperature coefficient of resistivity below 200 K, is observed. The results are compared with previously available literature data, and the p-T phase diagram is briefly discussed.

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1Intercalated Layered Materials, edited by Lévy, F. (D. Reidel, Dordrecht, Holland, 1979).
2Dresselhaus, M. S. and Dresselhaus, G., Adv. Phys. 30, 139 (1981).
3Graphite Intercalation Compounds I: Structure and Dynamics, edited by Zabel, H. and Solin, S.A. (Springer-Verlag, Berlin, Germany, 1990).
4Proc. 5th Int. Symp. on Graphite Intercalation Compounds, Berlin, May 1989, published in Synth. Metals 34 (1989).
5Proc. 6th Int. Symp. on Intercalation Compounds, Orléans, France, May 1991, published in Mater. Sci. Forum 91-93 (1992).
6Vogel, F. L., J. Mater. Sci. 12, 982 (1977)
Vogel, F. L., Foley, G. M. T., Zeller, C., Falardeau, E. R., and Gan, J., Mater. Sci. Eng. 31, 261 (1977)
Foley, G.M.T., Zeller, C., Falardeau, E.R., and Vogel, F.L., Solid State Commun. 24, 371 (1977).
7Lelaurain, M., Marêché, J. F., McRae, E., Andersson, O.E., and Sundqvist, B., J. Mater. Res. 7, pg. 2978 (1992).
8Wortmann, G., Godler, F., Perscheid, B., Kaindl, G., and Schlogl, R., Synth. Metals 26, 109 (1988).
9Salamanca-Riba, L., Roth, G., Gibson, J. M., Kortan, A. R., Dresselhaus, G., and Birgenau, R. J., Phys. Rev. B 33, 2738 (1986).
10Elzinga, M., Morelli, D.T., and Uher, C., Phys. Rev. B 26, 3312 (1982).
11Blinowski, J., Hau, N. Hy, Rigaux, C., and Vieren, J.P., J. Phys. Soc. Jpn. 49, Suppl. A, 915 (1980).
12Blinowski, J., Hau, N. Hy, Rigaux, C., Vieren, J.P., Toullec, R. Le, Furdin, G., Hérold, A., and Mélin, J., J. Phys. (France) 41, 47 (1980).
13Takahashi, O., lye, Y., and Tanuma, S., Solid State Commun. 37, 863 (1981).
14Zaleski, H., Ummat, P.K., and Datars, W.R., J. Phys. C 17, 3167 (1984); ibid., Phys. Rev. B 35, 2958 (1987).
15Wang, G., Zaleski, H., Ummat, P. K., and Datars, W. R., Phys. Rev. B 37, 9029 (1988).
16Hwang, D.M. and Nicolaides, G., Solid State Commun. 49, 483 (1984).
17Hwang, D. M., in Intercalated Graphite, edited by Dresselhaus, M. S., Dresselhaus, G., Fischer, J. E., and Moran, M. J. (Mater. Res. Soc. Symp. Proc. 20, Elsevier, New York, 1983), p. 295.
18Groot, K. de, Maurer, D., Müller, V., Geiser, V., and Güntherodt, H J., Synth. Metals 34, 335 (1989).
19Rolla, S., Walmsley, L., Suematsu, H., Torriani, I., Rettori, C., and Yosida, Y., Solid State Commun. 58, 333 (1986).
20Clarke, R., Elzinga, M., Gray, J. N., Homma, H., Morelli, D. T., Winokur, M. J., and Uher, C., Phys. Rev. B 26, 5250 (1982).
21Morelli, D.T. and Uher, C., Phys. Rev. B 27, 2477 (1983).
22Uher, C. and Morelli, D. T., in Intercalated Graphite, edited by Dresselhaus, M. S., Dresselhaus, G., Fischer, J. E., and Moran, M. J. (Mater. Res. Soc. Symp. Proc. 20, Elsevier, New York, 1983), p. 163.
23Piraux, L., Issi, J P., and Eklund, P. C., Solid State Commun. 56, 413 (1985).
24Avdeev, V.V., Brandt, N.B., Ionov, S.G., Kuvshinnikov, S.V., Mukhanov, V. A., and Semenenko, K. N., Inorg. Mater. 21, 1065 (1985).
25Bittner, D.N. and Bretz, M., Phys. Rev. B 31, 1060 (1985).
26Yosida, Y. and Tanuma, S., J. Phys. Soc. Jpn. 54, 650 (1985).
27Clarke, R. and Uher, C., Adv. Phys. 33, 469 (1984).
28Houser, B., Homma, H., and Clarke, R., Phys. Rev. B 30, 4802 (1984).
29Sundqvist, B. and Lundberg, B., J. Phys. C 19, 6915 (1986).
30lye, Y., Takahashi, O., Tanuma, S., Tsuji, K., and Minomura, S., Physica B 105, 185 (1981); ibid., J. Phys. Soc. Jpn. 51, 475 (1982).
31Andersson, G. and Sundqvist, B., Solid State Commun. 65, 735 (1988).
32Sundqvist, B., Synth. Metals 23, 345 (1988).
33Andersson, O.E., Lelaurain, M., Marêché, J.F., McRae, E., and Sundqvist, B., Synth. Metals 34, 187 (1989).
34Andersson, O.E., Lelaurain, M., Marêché, J.F., McRae, E., and Sundqvist, B., Mater. Sci. Forum 91-93, 301 (1992).
35Syassen, K., Sonnenschein, R., Hanfland, M., and Beister, M. J., Synth. Metals 34, 293 (1989).
36Alzyab, B., Perry, C.H., Zahopoulos, C., Pringle, O.A., and Nicklow, R.M., Phys. Rev. B 38, 1544 (1988).
37Andersson, O.E., McRae, E., Sundqvist, B., Marêché, J.F., and Lelaurain, M. (in preparation).
38Andersson, O., Sundqvist, B., and Bäckstrom, G., High Pressure Res. (1992, in press).
39Sundqvist, B., J. Phys. E 20, 984 (1987).
40Spain, I. L., in Physics and Chemistry of Carbon, edited by Walker, P. L. and Thrower, P. A. (Marcel Dekker, New York, 1981), Vol. 16, p. 120.
41Soule, D.E. and McClure, J. W., J. Phys. Chem. Solids 8, 29 (1959).
42Ono, S., J. Phys. Soc. Jpn. 40, 498 (1976).
43Kawamura, K., Ouchi, Y., Oshima, H., and Tsuzuku, T., J. Phys. Soc. Jpn. 46, 587 (1979).
44Tsuzuku, T., Carbon 17, 293 (1979).
45Uher, C., Hockey, R.L., and Ben-Jacob, E., Phys. Rev. B 35, 4483 (1987).
46Matsubara, K., Sugihara, K., and Tsuzuku, T., Phys. Rev. B 41, 969 (1990).
47Bevington, P. R., Data Reduction and Error Analysis for the Physical Sciences (McGraw-Hill, New York, 1969), p. 198.
48Rossiter, P. L., The Electrical Resistivity of Metals and Alloys (Cambridge Univ. Press, Cambridge, U. K., 1987).
49Onn, D.G., Foley, G.M.T., and Fischer, J.E., Phys. Rev. B 19, 6474 (1979)
Lundberg, B. and Sundqvist, B., Solid State Commun. 58, 747 (1986).
50McRae, E. and Marêché, J. F., J. Mater. Res. 3, 75 (1988).

A study of temperature and pressure induced structural and electronic changes in SbCl5 intercalated graphite: Part II. Experimental data for c-axis resistivity

  • O.E. Andersson (a1), B. Sundqvist (a1), E. McRae (a2), J.F. Marêché (a2) and M. Lelaurain (a2)...

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