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XXIII.—On the Reaction of Natural Waters with Soluble Lead Salts

Published online by Cambridge University Press:  17 January 2013

Arthur Connell Esq.
Affiliation:
Professor of Chemistry in the University of St Andrews

Extract

In a former communication to the Society, I noticed a reaction presented by all spring, well, and river waters which I had examined, that, even after being boiled, they yielded, with acetate of lead, a precipitate readily soluble, in whole or in great part, in acetic acid. This easy solubility in acetic acid shewed that the precipitate was neither a sulphate nor a phosphate, and the comparatively slight action of nitrate of silver proved that it was not a chloride. There seemed, therefore, to remain only the conclusion that it was either a carbonate, or was due to organic matter. The former alternative, of course, depended on whether the solution in acetic acid was attended with effervescence or not; and as this seemed usually not to be the case, and as, on decomposing some of the precipitate by sulphuretted hydrogen, some organic matter in solution was obtained, the conclusion seemed to be, that the appearance was caused by organic matter, probably of the nature of the crenic and apocrenic acids of Berzelius. I have since, however, found that by very careful observation, effervescence may be noticed during the solution of the precipitate more frequently than I at first supposed. It is not so easy as might be imagined to determine this point.

Type
Research Article
Copyright
Copyright © Royal Society of Edinburgh 1847

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References

page 360 note * Dr Christison informs me that moss-water is not precipitated by acetate of lead. This, I have no doubt is a correct observation; but still other states of organic matter may occasion a precipitate. The crenic and apocrenic acids are both known to precipitate lead salts.

Although fluorine is now known to be occasionally present in ordinary natural waters, and although fluoride of lead is sparingly soluble in water, yet I am not aware that fluorine is ever present in such quantity in such waters as to affect lead salts; and, if it were, acetic acid might very likely not dissolve the precipitate. Dr Wilson mentions that fluoride of barium is less soluble in acids than carbonate or phosphate of barytes.