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25 - Oxides and hydroxides. Review of ionic crystals

from Part IV - A systematic look at mineral groups

Hans-Rudolf Wenk
Affiliation:
University of California, Berkeley
Andrei Bulakh
Affiliation:
St Petersburg State University
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Summary

Introduction

The oxide and hydroxide groups each include about 200 minerals, or about 10% of all mineral species. We have discussed quartz and other silica minerals in Chapter 19. Quartz comprises nearly 12 vol.% of the earth's crust. Another oxide that is just as important as quartz is crystalline H2O (ice). This mineral occurs only as a “seasonal” phase at moderate latitudes, forms polar ice shields (crucial for the earth's climate), and glaciers. Besides its occurrence on the earth's surface, ice is one of the two major minerals building up the polar caps on Mars and has recently been documented on the moon. It is also found as particles forming the rings around Saturn, and may form a large part of the composition of some satellites of Saturn, Jupiter, and Uranus. Another important oxide is CO2, which does not occur on earth in the solid state but is present as a mineral on Mars and on the satellites of the outer planets, as well as in meteorites. In contrast to quartz and ice, iron oxides and hydroxides contribute only about 0.2% to the crust of the earth, but the minerals magnetite (Fe3O4) and hematite (Fe2O3) are the two major constituents of iron ores, and without iron the present state of our civilization is unimaginable.

Type
Chapter
Information
Minerals
Their Constitution and Origin
, pp. 406 - 424
Publisher: Cambridge University Press
Print publication year: 2004

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References

Franzen, H. F. (1986). Physical Chemistry of Inorganic Crystalline Solids. Springer-Verlag, Berlin, 158pp
Galasso, F. S. (1970). Structure and Properties of Inorganic Solids. Pergamon Press, Oxford, 297pp
Lindsley, D. H. (ed.) (1991). Oxide Minerals: Petrologic and Magnetic Significance. Rev. Mineral., vol. 25, Mineralogical Society of America, Washington, DC, 509pp
Navrotsky, A. and Weidner, D. J. (eds.) (1989). Perovskite: A Structure of Great Interest to Geophysics and Materials Science. Geophys. Monogr. no. 45. American Geophysical Union, Washington, DC, 146ppCrossRef
Rumble, D. (ed.) (1976). Oxide Minerals. Rev. Mineral., vol. 3, Mineralogical Society of America, Washington, DC
Turner, S.and Buseck, P. R.(1979). Manganese oxide tunnel structures and their intergrowths. Science, 203, 143–146CrossRefGoogle ScholarPubMed

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