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22 - Carbonates and other minerals with triangular anion groups. Sedimentary origins

from Part IV - A systematic look at mineral groups



Carbonates are the primary representative of compounds with an (XO3)n- radical. About 170 different carbonate minerals are known. Most of them are simple salts of carbonic acid (H2CO3), such as calcite (CaCO3) and dolomite (CaMg(CO3)2). Others contain additional anions -for example, malachite (Cu2(CO3)(OH)2) – and a few are mixed chemical compounds (sulfate-carbonates, phosphate-carbonates, arsenate-carbonates, borate-carbonates, nitride-carbonates, silicate-carbonates). We have mentioned two of these, burkeite (Na2CO3(SO4)2) and hanksite (Na2K(SO4)9(CO3)2Cl), in Chapter 21.

Apart from its role in carbonates, the (XO3)n- radical is also present in nitrates and borates. In some borates, the BO33- groups are isolated as in calcite, but in most the planar triangular groups are linked to form chains and sheets. Moreover, there are also borates with BO45- tetrahedra in their crystal structures, or with combinations of BO33- triangles and BO45- tetrahedra.

A list of the important carbonates, nitrates, and simple borates is given in Table 22.1. The most common carbonates, calcite and dolomite, comprise nearly 2.5% of the volume of the earth's crust.

Characteristic features of composition and crystal chemistry of carbonates and borates

By their chemical nature, the carbonate minerals are the most stable salts of carbonic acid. This acid is relatively weak and prefers to bond with elements of low ionization potentials (sodium, potassium, calcium, strontium) that are not too small in size (such as lithium).

Further reading
Aristarain, L. F. and Hurlbut, C. S. (1972). Boron minerals and deposits. Mineral. Rec., 3, 165–172
Kistler, R. B. and Helvaci, C. (1994). Boron and borates. In Industrial Minerals and Rocks, 6th edn. ed. D. Carr, pp. 171–186. Society of Mining, Metallurgy and Exploration. Littleton, Co
Lippmann, F. (1973). Carbonate Minerals. Springer-Verlag, Berlin, 228pp
Reeder, R. J. (ed). (1983). Carbonates: Mineralogy and Chemistry. Rev. Mineral., vol. 11. Mineralogical Society of America, Washington, DC, 394pp
Tucker, M. E. (1991). Sedimentary Petrology: An Introduction to the Origin of Sedimentary Rocks. Blackwell Scientific Publ., Oxford, 260pp
Tucker, M. E. and Wright, V. P. (1990). Carbonate Sedimentology. Blackwell Scientific Publ., Oxford, 480pp