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Adsorption of crystal violet on kaolinite clay: kinetic and equilibrium study using non-linear models

Published online by Cambridge University Press:  24 August 2022

Ali Boukhemkhem ,
Bamhammed Aissa-Ouaissi-Sekkouti ,
Jorge Bedia Open the ORCID record for Jorge Bedia [Opens in a new window] ,
Carolina Belver  and
Carmen B. Molina Open the ORCID record for Carmen B. Molina [Opens in a new window]
Ali Boukhemkhem
Affiliation:
Laboratory Interactions Materials – Environment (LIME), University of Mohamed Seddik Ben Yahia, Jijel, 18000, Algeria
Bamhammed Aissa-Ouaissi-Sekkouti
Affiliation:
Department of Process Engineering, University of Ammar Telidji, Laghouate, 03000, Algeria
Jorge Bedia
Affiliation:
Chemical Engineering Department, Faculty of Sciences, Universidad Autónoma de Madrid, Cantoblanco, 28049, Madrid, Spain
Carolina Belver
Affiliation:
Chemical Engineering Department, Faculty of Sciences, Universidad Autónoma de Madrid, Cantoblanco, 28049, Madrid, Spain
Carmen B. Molina*
Affiliation:
Chemical Engineering Department, Faculty of Sciences, Universidad Autónoma de Madrid, Cantoblanco, 28049, Madrid, Spain
*
*E-mail: carmenbelen.molina@uam.es
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Abstract

This work studied the efficiency of Tamazert kaolinite clay for adsorbing the cationic dye crystal violet from an aqueous solution in a batch system. The kinetics of the process and the equilibrium of adsorption were studied using non-linear models. The characterization of Tamazert kaolinite clay showed that it has structural, textural and surface properties that are suitable for adsorption. The effects of various process parameters such as contact time, initial dye concentration, initial pH, adsorbent dose and temperature were tested. The kinetic study using non-linear regression showed that the pseudo-second order model best fitted the experimental data. The intra-particle model was also used to estimate the contribution of intra-particle diffusion to this process. The adsorption isotherms were fitted to Freundlich, Langmuir and Redlich–Peterson models, showing that the adsorption is limited to a monolayer with a monolayer adsorption capacity of 44.2 mg g–1. The thermodynamic study indicated that the process is exothermic, spontaneous and accompanied by a decrease in entropy.

Keywords

adsorptioncrystal violetequilibriumkineticsLangmuirTamazert kaolinite claythermodynamics
Type
Article
Information
Clay Minerals , Volume 57 , Issue 1 , March 2022 , pp. 41 - 50
Copyright
Copyright © The Author(s), 2022. Published by Cambridge University Press on behalf of The Mineralogical Society of Great Britain and Ireland

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References

Abbasi, F., Yaraki, M.T., Farrokhnia, A. & Bamdad, M. (2020) Keratin nanoparticles obtained from human hair for removal of crystal violet from aqueous solution: optimized by Taguchi method. International Journal of Biological Macromolecules, 143, 492–500.CrossRefGoogle ScholarPubMed
Abraham, T., Lam, N., Xu, J., Zhang, D., Whadhawan, H., Kim, H.J. et al. (2019) Collapse of house-of-cards clay structures and corresponding tailings dewatering induced by alternating electric field. Drying Technology, 37, 1053–1067.CrossRefGoogle Scholar
Al-Bastaki, N. (2004) Removal of methyl orange dye and Na2SO4 salt from synthetic waste water using reverse osmosis. Chemical Engineering and Processing: Process Intensification, 43, 1561–1567.CrossRefGoogle Scholar
Al-Futaisi, A., Jamrah, A. & Al-Hanai, R. (2007) Aspects of cationic dye molecule adsorption to palygorskite. Desalination, 214, 327–342.CrossRefGoogle Scholar
Ali, H. & Muhammad, S.K. (2008) Biosorption of crystal violet from water on leaf biomass of Calotropis procera. Journal of Environmental Science and Technology, 1, 143–150.CrossRefGoogle Scholar
Amari, A., Chlendi, M., Gannouni, A. & Bellagi, A. (2010) Optimised activation of bentonite for toluene adsorption. Applied Clay Science, 47, 457–461.CrossRefGoogle Scholar
Askari, N., Farhadian, M., Razmjou, A. & Hashtroodi, H. (2016) Nanofiltration performance in the removal of dye from binary mixtures containing anthraquinones dyes. Desalination and Water Treatment, 57, 18194–18201.CrossRefGoogle Scholar
Auta, M. & Hameed, B. H. (2012) Modified mesoporous clay adsorbent for adsorption isotherm and kinetics of methylene blue. Chemical Engineering Journal, 198–199, 219–227.CrossRefGoogle Scholar
Banerjee, S., Dubey, S., Guatam, R.K., Chattopadhyaya, M.C. & Sharma, Y.C. (2019) Adsorption characteristics of alumina nanoparticles for the removal of hazardous dye, Orange G from aqueous solutions. Arabian Journal of Chemistry, 12, 5339–5354.CrossRefGoogle Scholar
Belal, R.M., Zayed, M.A., El-Sherif, R.M. & Abdel Ghani, N.A. (2021) Advanced electrochemical degradation of basic yellow 28 textile dye using IrO2/Ti meshed electrode in different supporting electrolytes. Journal of Electroanalytical Chemistry, 882, 114979.CrossRefGoogle Scholar
Benhabiles, S. & Rida, K. (2021) Production of efficient activated carbon from sawdust for the removal of dyes in single and binary systems – a full factorial design. Particulate Science and Technology, 39, 237–251.CrossRefGoogle Scholar
Boukhemkhem, A. & Rida, K. (2017) Improvement adsorption capacity of methylene blue onto modified Tamazert kaolin. Adsorption Science and Technology, 35, 753–773.CrossRefGoogle Scholar
Boukhemkhem, A., Rida, K., Pizarro, A.H., Molina, C.B. & Rodriguez, J.J. (2019) Iron catalyst supported on modified kaolin for catalytic wet peroxide oxidation. Clay Minerals, 54, 67–73.CrossRefGoogle Scholar
Boukhemkhem, A., Pizarro, A.H. & Molina, C.B. (2020) Enhancement of the adsorption properties of two natural bentonites by ion exchange: equilibrium, kinetics and thermodynamic study. Clay Minerals, 55, 132–141.CrossRefGoogle Scholar
Bujdák, J. (2020) Adsorption kinetics models in clay systems. The critical analysis of pseudo-second order mechanism. Applied Clay Science, 191, 105630.CrossRefGoogle Scholar
Dargahzadeh, M., Molaei, M. & Karimipour, M. (2018) Completely quenching of the trap states emission of CdSeQDs by CdS/ZnS shell growth using a one pot photochemical approach and application for dye photo-degradation. Journal of Luminescence, 203, 723–729.CrossRefGoogle Scholar
de Lima, S.A., Murad, M.A., Moyn, C.A. & Stemmelen, D. (2010) Three-scale model of pH-dependent flows and ion transport with equilibrium adsorption in kaolinite clays: I. Homogenization analysis. Transport in Porous Media, 85, 23–44.CrossRefGoogle Scholar
Eren, E. & Afsin, E. (2007) Investigation of a basic dye adsorption from aqueous solution onto raw and pre-treated sepiolite surfaces. Dyes and Pigments, 73, 162–167.CrossRefGoogle Scholar
Fabbri, B., Gualtieri, S. & Leonardi, C. (2013) Modification induced by thermal treatment of kaolin and determination of reactivity of metakaolin. Applied Clay Science, 73, 2–10.CrossRefGoogle Scholar
Feng, H., Li, C. & Shan, H. (2009) Effect of calcination temperature of kaolin microspheres on the in situ synthesis of ZSM-5. Catalysis Letters, 129, 71–78.CrossRefGoogle Scholar
Gadekar, R.M. & Ahammed, M.M. (2016) Coagulation/flocculation process for dye removal using water treatment residuals: modeling through artificial neural networks. Desalination and Water Treatment, 57, 26392–26400.CrossRefGoogle Scholar
Geethakarthi, A. & Phanikumar, B.R. (2011) Adsorption of reactive dyes from aqueous solutions by tannery sludge developed activated carbon: kinetic and equilibrium studies. International Journal of Environment Science and Technology, 8, 561–570.CrossRefGoogle Scholar
Giannakoudakis, D.A., Kyzas, G.Z., Avranas, A. & Lazaridis, N.K. (2016) Multi-parametric adsorption effects of the reactive dye removal with commercial activated carbons. Journal of Molecular Liquids, 213, 381–389.CrossRefGoogle Scholar
Hachemaoui, M., Boukoussa, B., Mokhtar, A., Mekki, A., Beldjilali, M., Benaissa, M. et al. (2020) Dyes adsorption, antifungal and antibacterial properties of metal loaded mesoporous silica: effect of metal and calcination treatment. Materials Chemistry and Physics, 256, 123704.CrossRefGoogle Scholar
Hamdaoui, O. & Naffrechoux, E. (2007) Modeling of adsorption isotherms of phenol and chlorophenols onto granular activated carbon. Part I. Two parameter models and equations allowing determination of thermodynamic parameters. Journal of Hazardous Materials, 147, 381–394.CrossRefGoogle ScholarPubMed
Hamza, W., Dammak, N., Bel, H., Eloussaief, M. & Mourad, B. (2018) Sono-assisted adsorption of cristal violet dye onto Tunisian smectite clay. Ecotoxicology and Environmental Safety, 163, 365–371.CrossRefGoogle ScholarPubMed
Hassen, H. & Hameed, B.H. (2011) Fe–clay as effective heterogeneous Fenton catalyst for the decolorization of Reactive Blue 4. Chemical Engineering Journal, 171, 912–918.CrossRefGoogle Scholar
Intachai, S., Suppaso, C. & Khaorapapong, N. (2021) A novel process for intercalating alkylammonium ions in a Thai bentonite and its effect on adsorption performance. Clays and Clay Minerals, 69, 477–488.CrossRefGoogle Scholar
Issa, A.A., Al-Degs, Y.S., Al-Ghouti, M.A. & Olimat, A.A.M. (2014) Studying competitive sorption behavior of methylene blue and malachite green using multivariate calibration. Chemical Engineering Journal, 240, 554–564.CrossRefGoogle Scholar
Jiang, M., Wang, Q., Jin, X. & Chen, Z. (2009) Removal of Pb(II) from aqueous solution using modified and unmodified kaolinite clay. Journal of Hazardous Materials, 170, 332–339.CrossRefGoogle ScholarPubMed
Jiang, X., Zhang, H., Yue, M., Zhang, S., Li, Y. & Xu, W. (2019) Synthesis of organic hybrid super-microporous silicas as an adsorbent for dyes removal from water. Microporous and Mesoporous Materials, 288, 109598.CrossRefGoogle Scholar
Karatas, D., Senol-Arslan, D. & Ozdemir, O. (2018) Experimental and atomic modeling of the adsorption of acid azo dye 57 to sepiolite. Clays and Clay Minerals, 66, 426–437.CrossRefGoogle Scholar
Khairy, M., Ayoub, H.A., Rashwan, F.A. & Abdel-Hafez, H.F. (2018) Chemical modification of commercial kaolin for mitigation of organic pollutants in environment via adsorption and generation of inorganic pesticides. Applied Clay Science, 153, 124–133.CrossRefGoogle Scholar
Konan, K.L., Peyratout, C., Smith, A., Bonnet, J.P., Rossignol, S. & Oyetola, S. (2009) Comparison of surface properties between kaolin and metakaolin in concentrated lime solutions. Journal of Colloid and Interface Science, 339, 103–109.CrossRefGoogle ScholarPubMed
Kulkarni, M.R., Revanth, T., Acharya, A. & Bhat, P. (2017) Removal of crystal violet dye from aqueous solution using water hyacinth: equilibrium, kinetics and thermodynamics study. Resource-Efficient Technologies, 3, 71–77.CrossRefGoogle Scholar
Kumar, R. & Ahmed, R. (2011) Biosorption of hazardous crystal violet dye from aqueous solution onto treated ginger waste (TGW). Desalination, 265, 112–118.CrossRefGoogle Scholar
Li, D., Yang, Y., Li, C. & Liu, Y. (2017) A mechanistic study on decontaminationof methyl orange dyes from aqueous phase by mesoporous pulp waste and polyaniline. Environmental Research, 154, 139–144.CrossRefGoogle Scholar
Liew, J., Wang, Y., Fang, Y., Mwamulima, T., Song, S. & Peng, C. (2018) Removal of crystal violet and methylene blue from aqueous solutions using the fly ash-based adsorbent material-supported zero-valent iron. Journal of Molecular Liquids, 250, 468–476.Google Scholar
Lin, J. & Wang, L. (2009) Comparison between linear and non-linear forms of pseudo-first-order and pseudo-second-order adsorption kinetic models for the removal of methylene blue by activated carbon. Frontiers of Environmental Science & Engineering, 3, 320–324.CrossRefGoogle Scholar
Li, X., Li, B., Xu, J., Wang, Q., Pang, X., Gao, X. et al. (2010) Synthesis and characterization of Ln-ZSM-5/MCM-41 (Ln = La, Ce) by using kaolin as raw material. Applied Clay Science, 50, 81–86.CrossRefGoogle Scholar
Miklos, D.B., Remy, C., Jekel, M., Linden, K.G., Drewes, J.E. & Hübner, U. (2018) Evaluation of advanced oxidation processes for water and wastewater treatment: a critical review. Water Research, 139, 118–131.CrossRefGoogle ScholarPubMed
Miyah, Y., Lahrichi, A., Idrissi, M., Boujraf, S., Taouda, H. & Zerrouq, F. (2017) Assessment of adsorption kinetics for removal potential of crystal violet dye from aqueous solutions using Moroccan pyrophyllite. Journal of the Association of Arab Universities for Basic and Applied Sciences, 23, 20–28.CrossRefGoogle Scholar
Mobarak, M., Selim, A.Q., Mohammed, E.A. & Seliem, M.K. (2018) A superior adsorbent of CTAB/H2O2 solution modified organic carbon rich-clay for hexavalent chromium and methyl orange uptake from solutions. Journal of Molecular Liquids, 259, 384–397.CrossRefGoogle Scholar
Monash, P., Niwas, R. & Pugazhenthi, G. (2011) Utilization of ball clay adsorbents for the removal of crystal violet dye from aqueous solution. Clean Technology and Environmental Policy, 13, 141–151.CrossRefGoogle Scholar
Mouni, L., Belkhiri, L., Bollinger, J.C., Bouzaza, A., Assadi, A., Tirri, A. et al. (2018) Removal of methylene blue from aqueous solutions by adsorption on kaolin: kinetic and equilibrium studies. Applied Clay Science, 153, 38–45.CrossRefGoogle Scholar
Muayad, E., Hubert, R., Ahmed, B., Hani, K., Mohammed, H. & Jan, W. (2015) Development of inorganic polymer by alkali-activation of untreated kaolinitic clay: reaction stoichiometry, strength and dimensional stability. Construction and Building Materials, 91, 251–259.Google Scholar
Nadaroglu, H., Kalkan, E., Celebi, N. & Tasgin, E. (2015) Removal of Reactive Black 5 from wastewater using natural clinoptilolite modified with apolaccase. Clay Minerals, 50, 65–75.CrossRefGoogle Scholar
Nandi, B.K., Goswami, A., Das, A.K., Mondal, B. & Purkait, M.K. (2008) Kinetic and equilibrium studies on the adsorption of crystal violet dye using kaolin as an adsorbent. Separation Science and Technology, 43, 1382–1403.CrossRefGoogle Scholar
Nasuha, N. & Hameed, B.H. (2011) Adsorption of methylene blue from aqueous solution onto NaOH-modified rejected tea. Chemical Engineering Journal, 166, 783–786.CrossRefGoogle Scholar
Pavan, F.A., Gushikem, Y., Mazzocato, A.C., Dias, S.L. & Lima, E.C. (2007) Statistical design of experiments as tool for optimizing the batch conditions to methylene blue biosorption on yellow passion fruit and mandarin peels. Dyes and Pigments, 72, 256–266.CrossRefGoogle Scholar
Puri, G. & Sumana, G. (2018) Highly effective adsorption of crystal violet dye from contaminated water using graphene oxide intercalated montmorillonite nanocomposite. Applied Clay Science, 166, 102–112.CrossRefGoogle Scholar
Rezazadeh, M., Baghdadi, M., Mehrdadi, N. & Abdoli, M.A. (2021) Adsorption of crystal violet dye by agricultural rice bran waste: isotherms, kinetics, modeling and influencing factors. Environmental Engineering Research, 26, 1–10.Google Scholar
Rida, K., Bouraoui, S. & Hadnine, S. (2013) Adsorption of methylene blue from aqueous solution by kaolin and zeolite. Applied Clay Science, 83–84, 99–105.CrossRefGoogle Scholar
Rytwo, G., Nir, S. & Margulies, L. (1993) Competitive adsorption of methylene blue and crystal violet to montmorillonite. Clay Minerals, 1, 139–143.CrossRefGoogle Scholar
San Cristóbal, A.G., Castelló, R., Martín Luengo, M.A. & Vizcayno, C. (2010) Zeolites prepared from calcined and mechanically modified kaolins: a comparative study. Applied Clay Science, 49, 239–246.CrossRefGoogle Scholar
Sarabadan, M., Bashiri, H. & Mousavi, S.M. (2019a) Adsorption of crystal violet dye by a zeolite–montmorillonite nano-adsorbent: modelling, kinetic and equilibrium studies. Clay Minerals, 54, 357–368.CrossRefGoogle Scholar
Sarabadan, M., Bashiri, H. & Mousavi, S.M. (2019b) Removal of crystal violet dye by an efficient and low cost adsorbent: modelling, kinetic, equilibrium and thermodynamic studies. Korean Journal of Chemical Engineering, 36, 1575–1586.CrossRefGoogle Scholar
Sarabadan, M., Bashiri, H. & Mousavi, S.M. (2021) Modelling, kinetics and equilibrium studies of crystal violet adsorption on modified montmorillonite by sodium dodecyl sulfate and hyamine surfactants. Clay Minerals, 56, 16–27.CrossRefGoogle Scholar
Sargin, I. & Unlu, N. (2013) Insights into cationic methyl violet 6B dye–kaolinite interactions: kinetic, equilibrium and thermodynamic studies. Clay Minerals, 48, 85–95.CrossRefGoogle Scholar
Sarma, G.K., Gupta, S.S. & Bhattacharyya, G.G. (2019) Removal of hazardous basic dyes from aqueous solution by adsorption onto kaolinite and acid-treated kaolinite: kinetics, isotherm and mechanistic study. SN Applied Sciences, 1, 211.CrossRefGoogle Scholar
Sharma, P., Kaur, H., Sharma, M. & Sahore, V. (2011) A review on applicability of naturally available adsorbents for the removal of hazardous dyes from aqueous waste. Environmental Monitoring and Assessment, 183, 151–195.CrossRefGoogle ScholarPubMed
Sharma, P., Borah, D.J., Das, P. & Das, M.R. (2015) Cationic and anionic dye removal from aqueous solution using montmorillonite clay: evaluation of adsorption parameters and mechanism. Desalination and Water Treatment, 57, 8372–8388.CrossRefGoogle Scholar
Srinivasan, S. & Sadavisam, S.K. (2021) Biodegradation of textile azo dyes by textile effluent non-adapted and adapted Aeromonas hydrophila. Environmental Research, 194, 110643.CrossRefGoogle ScholarPubMed
Thommes, M., Kaneko, K., Neimark, A.V., Olivier, J.P., Rodriguez-Reinoso, F., Rouquerol, J. & Sing, K.S.W. (2015) Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure and Applied Chemistry, 87, 1051–1069.CrossRefGoogle Scholar
Varjani, S., Rakholiya, P., Ng, H.Y., You, S. & Teixeira, J.A. (2020) Microbial degradation of dyes: an overview. Bioresource Technology, 314, 123728.CrossRefGoogle ScholarPubMed
Vishwakarma, M.C., Tiwari, P., Joshi, S.K., Sharma, H. & Bhandari, N.S. (2018) Adsorption of Cu(II) ion onto activated Eupatorium adenophorum and Acer oblongum; thermodynamic, kinetics and equilibrium studies. Chemical Science Transactions, 7, 445–463.Google Scholar
Volzone, C. & Ortiga, J. (2006) Removal of gases by thermal-acid leached kaolinitic clays: influence of mineralogical composition. Applied Clay Science, 32, 87–93.CrossRefGoogle Scholar
Xia, Y., Azaiez, J. & Hill, J.M. (2018) Erroneous application of pseudo-second-order adsorption kinetics model: ignored assumptions and spurious correlations. Industrial & Engineering Chemistry Research, 57, 2705–2709.CrossRefGoogle Scholar
Yagub, M.T., Sen, T.K., Afroze, S. & Ang, H.M. (2014) Dye and its removal from aqueous solution by adsorption: a review. Advances in Colloid and Interface Science, 209, 172–184.CrossRefGoogle ScholarPubMed
Yaseen, D.A. & Scholz, M. (2019) Textile dye wastewater characteristics and constituents of synthetic ef uents: a critical review. International Journal of Environnmental Sciences and Technology, 16, 1193–1126.Google Scholar