Herbicides have been a primary means of managing undesirable brush on grazing lands across the southwestern United States for decades. Continued encroachment of honey mesquite and huisache on grazing lands warrants evaluation of treatment life and economics of current and experimental treatments. Treatment life is defined as the time between treatment application and when canopy cover of undesirable brush returns to a competitive level with native forage grasses (i.e., 25% canopy cover for mesquite and 30% canopy cover for huisache). Treatment life of industry-standard herbicides was compared with that of aminocyclopyrachlor plus triclopyr amine (ACP+T) from 10 broadcast-applied honey mesquite and five broadcast-applied huisache trials established from 2007 through 2013 across Texas. On average, the treatment life of industry standard treatments (IST) for huisache was 3 yr. In comparison, huisache canopy cover was only 2.5% in plots treated with ACP+T 3 yr after treatment. The average treatment life of IST for honey mesquite was 8.6 yr, whereas plots treated with ACP+T had just 2% mesquite canopy cover at that time. Improved treatment life of ACP+T compared with IST life was due to higher mortality resulting in more consistent brush canopy reduction. The net present values (NPVs) of ACP+T and IST for both huisache and mesquite were similar until the treatment life of the IST application was reached (3 yr for huisache and 8.6 yr for honey mesquite). At that point, NPVs of the programs diverged as a result of brush competition with desirable forage grasses and additional input costs associated with theoretical follow-up IST necessary to maintain optimum livestock forage production. The ACP+T treatments did not warrant a sequential application over the 12-yr analysis for huisache or 20-yr analysis for honey mesquite that this research covered. These results indicate ACP+T provides cost-effective, long-term control of honey mesquite and huisache.

The Mosbeck Site is in the southern part of the Lake Agassiz basin in northwestern Minnesota. The stratigraphic section at the site consists of seven lithologic units, which are from bottom to top (A) unsorted, pebbly, sandy, silty clay, (B) coarse gravel, (C) silty sand, (D) peat, (E) fine sand, (F) interbedded sand and gravel, and (G) unbedded dirty gravel. The lower few centimeters of unit E are unoxidized and contain black spruce and tamarack driftwood, which has been radiocarbon dated at 9940 ± 160 BP (I-3880). Units C-E contain numerous, well-preserved insect and mollusk remains. These fossils have been compared with modern species, and at least 76 insect and 15 mollusk taxa are present. Assuming that their ecological tolerances have changed little in the past 10,000 years, they provide valuable information about the environment of Lake Agassiz. Few of the insects are now found in the region, indicating that the environment has changed. With few exceptions the species present indicate that the climate and vegetation at the time were similar to the present-day climate and vegetation of southeastern Manitoba.

The lithology and faunal contents of the sediment are interpreted as follows. Unit A is Late Wisconsinan glacial sediment. Unit B is a lag concentrate formed by wave action during a regressive phase of Lake Agassiz. Unit C is the sediment of a small body of water that formed when the level of Lake Agassiz had dropped below the site. The banks were covered with a spruce forest. Open water gave way to swampy conditions, and unit D was formed. Both units C and D were deposited during the low-water Moorhead Phase of Lake Agassiz. Units E and F are shoreline sediment deposited as the lake level rose, drowning the vegetation. Unit G is modern ditch spoil.

Lithium titanate spinel (Li4Ti5O12, or LTS) has received an increasing level of attention as a nanopowder lithium-ion battery anode. Nanopowder electrodes may provide a higher energy density than currently available. Furthermore, the surface of the spinel nanopowder has been studied in air, under vacuum, and at varying temperatures with diffuse reflectance infrared Fourier transform spectroscopy revealing surface hydroxyls, carbonates and water. Applying a TiN thin film, a film that is both conducting and chemically inert to harmful reactions with the solvent/electrolyte, by atomic layer deposition (ALD) may enhance battery cycle life. A 200-layer film was deposited at 500 °C. We have characterized the influence of a TiN thin film on Li-ion battery performance. Total nitrogen content and transmission electron microscopy were used to verify the presence of nitrogen and formation of a thin film, respectively, on LTS. Modifying the powder with an ALD thin film coating produced an anode material with a voltage profile that demonstrated longer charge maintenance with shorter transient periods. It also held a more consistent charge capacity over varying discharge rates in coin cell testing than unmodified LTS.

It was demonstrated, on general thermodynamic grounds, that, in non-hydrostatically stressed elastic systems, phase and grain interfaces undergo morphological destabilization due to different mechanisms of “mass rearrangement”. Destabilization of free surfaces due to the combined action of mass rearrangement in the presence of electrostatic field has been well known since the end of the 19th century. Currently, morphological instabilities of thin solid films with electro-mechanical interactions have found various applications in physics and engineering. In this paper, we investigate the combined effects of the stress driven rearrangement instabilities and the destabilization due to the electro-mechanical interactions. The paper presents relevant results of theoretical studies for ferroelectric thin films. Theoretical analysis involves highly nonlinear equations allowing analytical methods only for the initial stage of unstable growth. At present, we are unable to explore analytically the most important, deeply nonlinear regimes of growth. To avoid this difficulty, we developed numerical tools facilitating the process of solving and interpreting the results by means of visualization of developing morphologies.