A novel photocatalyst Tm3+/Yb3+–co-doped bismuth molybdate (Bi2MoO6) were synthesized via the hydrothermal method. The samples were characterized through X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectra, and photoluminescence. XPS characterization confirmed the doped rare earth elements. Analysis of the optical properties explained the up-conversion process and its effect on the photocatalytic performance. The as-synthesized samples were employed to decompose Rhodamine B to value its photocatalytic activities under visible light irradiation. The doped samples showed an enhanced photocatalytic activity compared with the bare Bi2MoO6. When the ratio of Tm3+ and Yb3+ was 0.5:5, the degradation efficiency was the highest of 96.1% within 25 min, which was higher than that (74.9%) of pure Bi2MoO6. Moreover, the photocatalytic mechanism of improving the photocatalytic properties was discussed. Besides, the sample showed a super stability in photocatalytic activity. A novel catalyst for industrial pollutant degradation was proposed.

The onset of thermal convection in a rapidly rotating spherical shell is studied by linear stability analysis based on the fully compressible Navier–Stokes equations. Compressibility is quantified by the number of density scale heights $N_{\unicode[STIX]{x1D70C}}$, which measures the intensity of density stratification of the motionless, polytropic base state. The nearly adiabatic flow with polytropic index $n=1.499<n_{a}=1.5$ is considered, where $n_{a}$ is the adiabatic polytropic index. By investigating the stability of the base state with respect to the disturbance of specified wavenumber, the instability process is found to be sensitive to the Prandtl number $Pr$ and to $N_{\unicode[STIX]{x1D70C}}$. For large $Pr$ and small $N_{\unicode[STIX]{x1D70C}}$, the quasi-geostrophic columnar mode loses stability first; while for relatively small $Pr$ a new quasi-geostrophic compressible mode is identified, which becomes unstable first under strong density stratification. The inertial mode can also occur first for relatively small $Pr$ and a certain intensity of density stratification in the parameter range considered. Although the Rayleigh numbers $Ra$ for the onsets of the quasi-geostrophic compressible mode and columnar mode are different by several orders of magnitude, we find that they follow very similar scaling laws with the Taylor number. The critical $Ra$ for convection onset is found to be always positive, in contrast with previous results based on the widely used anelastic model that convection can occur at negative $Ra$. By evaluating the relative magnitude of the time derivative of density perturbation in the continuity equation, we show that the anelastic approximation in the present system cannot be applied in the small-$Ra$ and large-$N_{\unicode[STIX]{x1D70C}}$ regime.

The influences of non-Oberbeck–Boussinesq (NOB) effects on flow instabilities and bifurcation characteristics of Rayleigh–Bénard convection are examined. The working fluid is air with reference Prandtl number $Pr=0.71$ and contained in two-dimensional rigid cavities of finite aspect ratios. The fluid flow is governed by the low-Mach-number equations, accounting for the NOB effects due to large temperature difference involving flow compressibility and variations of fluid viscosity and thermal conductivity with temperature. The intensity of NOB effects is measured by the dimensionless temperature differential $\unicode[STIX]{x1D716}$. Linear stability analysis of the thermal conduction state is performed. An $\unicode[STIX]{x1D716}^{2}$ scaling of the leading-order corrections of critical Rayleigh number $Ra_{cr}$ and disturbance growth rate $\unicode[STIX]{x1D70E}$ due to NOB effects is identified, which is a consequence of an intrinsic symmetry of the system. The influences of weak NOB effects on flow instabilities are further studied by perturbation expansion of linear stability equations with regard to $\unicode[STIX]{x1D716}$, and then the influence of aspect ratio $A$ is investigated in detail. NOB effects are found to enhance (weaken) flow stability in large (narrow) cavities. Detailed contributions of compressibility, viscosity and buoyancy actions on disturbance kinetic energy growth are identified quantitatively by energy analysis. Besides, a weakly nonlinear theory is developed based on centre-manifold reduction to investigate the NOB influences on bifurcation characteristics near convection onset, and amplitude equations are constructed for both codimension-one and -two cases. Rich bifurcation regimes are observed based on amplitude equations and also confirmed by direct numerical simulation. Weakly nonlinear analysis is useful for organizing and understanding these simulation results.

Long-term fertilization experiment has been conducted since 1981 to study the effect of soil management practices on soil fertility, soil carbon and nitrogen sequestration, soil culturable microbe counts and crop yields at the Nanhu Experimental Station in the Hubei Academy of Agricultural Sciences (situated in the middle reach of the Yangtze River and the rice–wheat cropping system). The experiment was designed with the following eight treatments: (1) unfertilized treatment: Control; (2) inorganic nitrogen fertilizer treatment: N; (3) inorganic nitrogen plus inorganic phosphorus fertilizer treatment: NP; (4) inorganic nitrogen, inorganic phosphorus plus inorganic potassium fertilizer treatment: NPK; (5) pig dung compost (manure) treatment: M; (6) inorganic nitrogen fertilizer plus manure: NM; (7) inorganic nitrogen, inorganic phosphorus fertilizer plus manure treatment: NPM and (8) inorganic nitrogen, inorganic phosphorus, inorganic potassium fertilizer plus manure treatment: NPKM. The results showed that long-term application of organic manure in combination with inorganic fertilizer significantly (p < 0.05) increased soil organic C concentrations compared with the corresponding inorganic fertilizers alone. Soil organic C contents were significantly (p < 0.05) increased in balanced application of NPK fertilizers in comparison to unbalanced application of fertilizers. After 30 years of experiment, soil organic C and total N sequestration rate averagely were 0.48 t ha−1 year−1 and 28.3 kg ha−1 year−1 in the fertilized treatments respectively; nevertheless, it were 0.27 t ha−1 year−1 and 9.7 kg ha−1 year−1 in the unfertilized treatment. Application of organic fertilizer in combination with inorganic fertilizer significantly (p < 0.05) increased culturable microbial counts compared with the corresponding inorganic fertilizers alone. The balanced application of NPK fertilizers significantly (p < 0.05) increased culturable microbial counts compared with unbalanced application of fertilizers. The average grain yield of wheat and rice was significantly (p < 0.05) higher in organic manure combined with inorganic fertilizer treatment than in inorganic fertilizer alone and unfertilized control. Therefore, long-term application of organic manure combined with inorganic fertilizer and balanced application of NPK fertilizers could increase soil organic C and total N sequestration, culturable microbial counts and crop grain yields.

Sui SG, Wu MX, King ME, Zhang Y, Ling L, Xu JM, Weng XC, Duan L, Shan BC, Li LJ. Abnormal grey matter in victims of rape with PTSD in Mainland China: a voxel-based morphometry study.

A support vector machine (SVM) method is applied to select K giant stars directly from the spectral features of LAMOST spectra. The performance of the algorithm is assessed using the MILES library. It shows that the completeness of the K giant stars is 87% with only about 6% dwarf contamination. This allows us to select 18,013 K giant stars at |b|>20° and 38,108 at |b|<20° from LAMOST pilot survey data.

We use 63,774 F/G dwarf stars from the LAMOST pilot survey to explore the velocity distribution in the solar neighborhood. The intrinsic UV distribution is reconstructed with a 20-Gaussian model using extreme deconvolution. We find at least two arcs, one extending from (−106, −3) to (94, −27) km/s and the other from (29, −9) to (78, −51) km/s. The arcs are qualitatively consistent with numerical simulations of the resonance induced by the Galactic bar and can be used to constrain its dynamical properties.

Nanoporous silica zeolite thin films are promising candidates for future generation low-dielectric constant (low-k) materials. During the integration with metal interconnects, residual stresses resulting from the packaging processes may cause the low-k thin films to fracture or delaminate from the substrates. To achieve high-quality low-k zeolite thin films, it is important to carefully evaluate their adhesion performance. In this paper, a previously reported laser spallation technique is modified to investigate the interfacial adhesion of zeolite thin film-Si substrate interfaces fabricated using three different methods: spin-on, seeded growth, and in situ growth. The experimental results reported here show that seeded growth generates films with the highest measured adhesion strength (801 ± 68 MPa), followed by the in situ growth (324 ± 17 MPa), then by the spin-on (111 ± 29 MPa). The influence of the deposition method on film–substrate adhesion is discussed. This is the first time that the interfacial strength of zeolite thin films-Si substrates has been quantitatively evaluated. This paper is of great significance for the future applications of low-k zeolite thin film materials.

Future microprocessor technologies will require interlayer dielectric (ILD) materials with a dielectric constant (κ-value) less than 2.5. Organosilicate glass (OSG) materials must be nanoporous to meet this demand. However, the introduction of nanopores creates many integration challenges. These challenges include 1) integrating nanoporous films with low mechanical strength into conventional process flows, 2) managing etch profiles, 3) processinduced damage to the nanoporous ILD, and 4) controlling the metal/nanoporous ILD interface. This paper reviews research to maximize mechanical strength by engineering optimal pore structures, controlling trench bottom roughness induced by etching and understanding its relationship to pore size, repairing plasma damage using silylation chemistry, and sealing a nanoporous surface for barrier metal (liner) deposition.

Nanoporous zeolite thin films are promising candidates as future low dielectric constant (low-k) materials. During the integration process with other semiconductor materials, the residual stresses resulting from the synthesis processes may cause fracture or delamination of the thin films. In order to achieve high quality low-k zeolite thin films, the evaluation of the adhesion performance is important. In this paper, laser spallation technique is utilized to investigate the interfacial adhesion of zeolite thin film-Si substrate interfaces prepared using three different processes. The experimental results demonstrate that the nature of the deposition method has a great effect on the resulted interfacial adhesion of the film-substrate interfaces. This is the first time that the interfacial strength of zeolite thin films-Si substrates is quantitatively evaluated. The results have great significance in the future applications of low-k zeolite thin film materials.

The Chinese distribution system is markedly different from its American equivalent. The bulk of the nation's products, especially producers' goods, are allocated according to the state plan and distributed through state-controlled channels and facilities. As most of the products are purchased by the state there would appear to be no need for sales marketing; the primary function of the distribution system is merely to handle the physical flow of goods. However, goods are often in short supply. Therefore, to ensure an adequate supply of inputs to fulfil the production quotas, numerous purchasing agents are used to locate the necessary inputs for enterprises. Basically, the commodity flow is pulled by the buyers rather than pushed by the sellers. This supply insufficiency leads to many problems, including commodity hoarding by users and producers alike. Consequently, the level of idle inventory is unnecessarily high and the size and speed of the commodity flow reduced.