An enhanced concentration of phosphorus has been found at the stratigraphic level of the disappearance of Ediacaran taxa in two areas, the Cis-Dniester region and the Moscow syneclise, on the East European Platform (EEP). The isotope composition of neodymium was determined in Fe sulphide and phosphorite in the same beds. Measured εNd(t) values in diagenetic phosphate nodules are similar to those in iron sulphide from the same layer. During the Ediacaran − Early Cambrian, accumulation of radiogenic Nd in the epeiric basins on the EEP increased progressively from −17.9 and −19.4 in pyrite from the sequence bottom to −7.9 and −8.5 in the Early Cambrian pyrite of the central part of the EEP. The Ediacaran phosphate nodules show εNd(t) ranging from −12.9 to −15.0, while that in the Early Cambrian nodules is typically c. −9.0. These data indicate the secular change in Nd isotope composition of the water reservoir on the EEP from Ediacaran to Cambrian.

A Nd isotope map of early Cambrian epeiric basins has been inferred from the Nd isotopic signature recorded in phosphatic Small Shelly Fossils. The most radiogenic εNd(t) values characterize water reservoirs along the Avalonian and Cadomian belts, while εNd(t) values of −10 to −20 were obtained in Laurentia and East Gondwanan Australia and China. Such a distribution of Nd isotope signatures results from the different provenance of early Cambrian epeiric seas: juvenile magmatic arcs and/or cordilleran for Mongolia, Siberia, Iberia and adjacent terranes, and cratonic sources for Laurentia and East Gondwana. Biogenic apatite of Small Shelly Fossils may be a useful tool for mapping of Nd isotope composition and documenting water mass exchange between discrete basins.