Ash layers from Searles Lake, California, were sampled in core of drill hole KM-3, which penetrated 693 m of lacustrine sediment deposited in a playa-lake complex over the past 3.2 my. Lake water changed from moderately saline and slightly alkaline (pH ~7.5) to highly saline 2.04 my ago and to highly saline and alkaline (pH ~9.5) 1.28 my ago. As a result of brines flushing downward, the upper 291 m of sediment, spanning the past 1.28 my, contain highly saline, alkaline pore fluid. Silicic ash layers in contact with highly saline, alkaline pore fluid were first altered to phillipsite and meriinoite and then to K-feldspar and searlesite. The transformation of phillipsite and/or meriinoite to K-feldspar required more than 45,000 years and was largely completed in 140,000 years. Tephra layers in contact with moderately saline, slightly alkaline pore fluid vary from uncemented vitric ash containing minor smectite to bentonites in which glass is wholly altered to smectite, clinoptilolite, analcime, and opal. Layers with much fine tephra are more altered than the coarser, better-sorted layers. Alteration is attributed to hydrolysis in essentially a closed hydrologic system, in which the alteration of glass to smectite raised the pH, aSiO2, and (Na+ + K+)/H+ activity ratio to the level where clinoptilolite formed. Some diffusion and/ or fluid flow is, however, indicated by the loss of SiO2 during the alteration of ash layers to smectite and by anhydrite deposited during and after clinoptilolite in some tuffaceous sandstones.

This paper presents a 27Al and 29Si MAS NMR study of K-feldspars and demonstrates that the spectra are sensitive to variations in the state of Al,Si order. For synthetically annealed samples, the results are in agreement with previous IR spectroscopy (Harris et al., 1989) and demonstrate that Al,Si rearrangement continues after the samples have become monoclinic as determined by powder XRD. NMR methods provide a significantly improved picture of the state of local Al,Si order in such samples. For triclinic samples, measures of the state of Al,Si order (M1 and M2 of 27Al spectra and M2 of 29Si spectra) correlate well with site occupancies determined by powder XRD, but for the monoclinic samples the NMR parameters continue to change whereas the XRD parameters do not. Interpretations based on the NMR results for the synthetically disordered samples are consistent with 1-step disordering, as observed by XRD. 27Al and 29Si MAS NMR is likely to be a useful tool for probing the state of local Al,Si order in a wide variety of natural samples.

Bed I in Olduvai Gorge spans the interval from about 1.7 to 2.0 m.y.a., and all evidences of hominid activity at Olduvai are within the latter half of this period. Bed I was deposited in a closed basin approximately 25 km in average diameter, and it can be subdivided into five lithologically different but partly time-equivalent rock assemblages, or lithologic facies, each of which was deposited in the same geographic environment or closely related series of environments. These lithofacies comprise lake deposits, lake-margin deposits, alluvial-fan deposits, alluvial-plain deposits, and lava flows.

Alluvial-plain deposits form the lowermost part of Bed I, and they presumably interfinger northeastward with lake deposits in an area not now exposed. Discharge of the lavas diplaced the lake westward to a position it occupied through the latter half of the deposition of Bed I. The lake fluctuated greatly in salinity, level, and extent, and at times of low level it was highly saline and generally ranged between 7 and 10 km in average diameter. At times of high level it was as much as 15 km in diameter and was relatively fresh, at least along its southeastern margin. The lake-margin deposits accumulated on the zone of relatively flat terrain that was flooded at times of high level. Lake-margin deposits interfinger eastward with deposits of an alluvial fan of pyroclastic materials produced in an explosive phase of the volcano Olmoti. The climate at the time of Bed I was relatively dry although somewhat wetter than the present climate in the same region today.

The isotopic composition of paleosol carbonates from Olduvai Gorge can be used to give estimates of the paleoclimatic history of East Africa during the Plio-Pleistocene. Oxygen isotopes are indicative of major changes in the isotopic composition of meteoric water, while carbon isotopes are indicative of major changes in the fraction of biomass using the Hatch-Slack (C4) photosynthetic pathway. Three major periods of climatic change in this terrestrial setting occurred at about 1.67, 1.3, and 0.6 myr. These involved major changes in flora as well as major changes in the isotopic composition of meteoric water. Overall, the climate has become warmer and more arid over the past 2.2 myr.

The IntCal09 and Marine09 radiocarbon calibration curves have been revised utilizing newly available and updated data sets from 14C measurements on tree rings, plant macrofossils, speleothems, corals, and foraminifera. The calibration curves were derived from the data using the random walk model (RWM) used to generate IntCal09 and Marine09, which has been revised to account for additional uncertainties and error structures. The new curves were ratified at the 21st International Radiocarbon conference in July 2012 and are available as Supplemental Material at www.radiocarbon.org. The database can be accessed at http://intcal.qub.ac.uk/intcal13/.

The aboriginal thermal processing of Bald Eagle Jasper in Central Pennsylvania is described in terms of the chemical and physical changes that occur in this material. Heat treatment is shown to transform the jasper's geothite component to hematite and to improve its workability by reducing its fracture toughness by one-half. This is accompanied by a yellow to red color change. The role of thermal alteration in the local lithic technology is inferred from laboratory heating experiments and from an analysis of lithic artifacts from the Houserville Site (36 Ce 65), a jasper workshop. The prehistoric utilization of this material is analyzed from a regional perspective. The results have implications for aboriginal social organization in Central Pennsylvania.