A 40.9 m ice core was recovered from Far East Rongbuk Glacier (FER), Qomolangma (Mount Everest), Himalaya, and an 80.4 m core from neighboring East Rongbuk Glacier (ER). Both are dated by seasonal variations of δ18O and major-ionic profiles, together with references of β-activity peaks. In this paper we compare the chemical records of these two cores to show post-depositional modification processes. The smoothed β18O profiles of the two cores show a similar trend. However, the mean β18O value of the FER core for the period 1954—96 is 3.12%o less than that of the corresponding part of the ER core, and the major-ionic profiles of the two cores differ considerably. We suggest that melting-away of the snow layer deposited during the pre-monsoon season may account for lower β18O values of the FER than of the ER core, and higher terrestrial ion concentrations in the FER core for the period 1957-63 may contribute to changes by chemical reactions in the presence of snowmelting. The significantly decreased NH4 and, to a lesser degree, SO42 concentrations in the FER core could be caused by the ion elution process that moved most chemicals away with runoff.

From its original formulation in 1990 the International Trans-Antarctic Scientific Expedition (ITASE) has had as its primary aim the collection and interpretation of a continent-wide array of environmental parameters assembled through the coordinated efforts of scientists from several nations. ITASE offers the ground-based opportunities of traditional-style traverse travel coupled with the modern technology of GPS, crevasse detecting radar, satellite communications and multidisciplinary research. By operating predominantly in the mode of an oversnow traverse, ITASE offers scientists the opportunity to experience the dynamic range of the Antarctic environment. ITASE also offers an important interactive venue for research similar to that afforded by oceanographic research vessels and large polar field camps, without the cost of the former or the lack of mobility of the latter. More importantly, the combination of disciplines represented by ITASE provides a unique, multidimensional (space and time) view of the ice sheet and its history. ITASE has now collected >20 000km of snow radar, recovered more than 240 firn/ice cores (total length 7000 m), remotely penetrated to ~4000m into the ice sheet, and sampled the atmosphere to heights of >20 km.

The net surface snow accumulation on the Antarctic ice sheet is determined by a combination of precipitation, sublimation and wind redistribution. We present a 1 year record of hourly snow-height measurements that shows its seasonal variability. The measurements were made with an ultrasonic sensor mounted on an automatic weather station (AWS) installed at LGB69, Princess Elizabeth Land, Antarctica (70.835˚S, 77.075˚E; 1850 ma.s.l.). The average accumulation at this site is approximately 0.70 m snow a–1. Throughout the winter, between April and September, there was little change in surface snow height. The strongest accumulation occurred during the period October–March, with four episodic increases occurring during 2002. These episodic events coincided with obvious humidity ‘pulses’ and decreases of incoming solar radiation as recorded by the AWS. Observations of the total cloud amount at Davis station, 160 km north-northeast of LGB69, showed good correlation with major accumulation events recorded at LGB69. There was an obvious anticorrelation between the lowest cloud height at Davis and the daily accumulation rate at LGB69. Although there was no correlation over the total year between wind speed and accumulation at LGB69, large individual accumulation events are associated with episodes of strong wind. Strong accumulation events at LGB69 are associated with major storms in the region and inland transport of moist air masses from the coast.

High-resolution chemical records from an 80.4m ice core from the central Himalaya demonstrate climatic and environmental changes since 1844. the chronological net accumulation series shows a sharp decrease from the mid-1950s, which is coincident with the widely observed glacier retreat. A negative correlation is found between the ice-core δ18O record and the monsoon precipitation for Indian region 7. the temporal variation of the terrestrial ions (Ca2+ and Mg2+) is controlled by both the monsoon precipitation for Indian regions 3,7 and 8, located directly south and west of the Himalaya, and the dust-storm duration and frequency in the northern arid regions, such as the Taklimakan desert, China. the NH4+ profile is fairly flat until the 1940s, then substantially increases until the end of the 1980s, with a slight decrease during the 1990s which may reflect new agricultural practices. the SO42– and NO3– profiles show an apparent increasing trend, especially during the period 1940s–80s. Moreover, SO42– concentrations for the East Rongbuk Glacier core are roughly double that of the nearby Dasuopu core at Xixabangma, Himalaya, due to local human activity including that of climbing teams who use gasoline for cooking, energy and transport.

During an inland traverse expedition along the route from Zhongshan station on the coast to Dome A (about 4200ma.s.l.; 1400 km from Zhongshan) in East Antarctica in 1998/99, three snow pits with a depth of 2.1–3.3m were sampled continuously. Snow pits were located at sites 800–1100km from the coast, with altitudes varying from 2850 to 3760 m. The samples were analyzed for stable oxygen isotope and major ions. Seasonal variations in δ18O are not clear, so initial dating was made through comparison of concentration profiles of major ions and then adjusted according to the visible stratigraphy. Generally, average ionic concentrations decrease with increasing altitude and hence distance from the coast, but NH4+ and Ca2+ have relatively high values at a site 1000 km inland. Ionic concentrations tend to increase with depth at lower altitudes, but the opposite is true at higher altitudes. Accumulation rates increase with depth at site DT401 (3760ma.s.l.; 1097 km from Zhongshan) and decrease at DT364 (3380ma.s.l.; 1022 km from Zhongshan) and DT263 (2850ma.s.l.; 820 km from Zhongshan), suggesting that differences in regional trends exist. In all snow pits, Na+ and Cl– concentration profiles have a very good positive correlation. Profiles of nssSO42– in the pits show quite different features. At 3760ma.s.l, no remarkable nssSO42– peaks can be distinguished, but one and three peak sets are quite striking at 3380 and 2850 m, respectively.

The continental regions of China are extensively covered by snow during winter. In this paper, the seasonal snow cover in the Tien Shan and Altay mountains is observed and analyzed, based on the characteristics of the dry-cold snow cover accumulating under the continental climatic conditions in northwest China. Compared with the humid-warm snow cover, the dry-cold snow cover is characterized mainly by small density, low water content, large temperature gradient, thick depth hoar, etc., and its metamorphism is dominated by the thermal exchange and the pressure of the overlying snow layers. According to the observed data, the solar radiation flux on the snow surface is dominated by a negative balance in the arid areas in China during the snow season; the albedo on the new-fallen-snow surface is up to 96%, and the transmission depth of shortwave radiation in dry-cold snow cover is 28 cm. During the snowmelt season in spring, the thickness of the depth hoar can occupy 80% of the whole snow cover.

A 36C1 peak has been found at about 37 ka BP in the Guliya ice core, drilled from the Qinghai-Tibetan Plateau. This peak is indicative of enhanced cosmogenic isotope production in the atmosphere, rather than a change in accumulation rate. Comparison with the records of 10Be and 36C1 in ice cores from Antarctica and Greenland indicates that peaks of the cosmogenic isotopes are global, and that they can be used as time markers for dating ice cores. Interestingly, the 37 ka BP global event coincided with a cold period.

This paper reports the lead concentration and flux (where accumulation rate is available) along the route of the 1990 International Trans-Antarctic Expedition. The lead concentration in Larsen Ice Shelf and Antarctic Peninsula, the western part of the route, was 7.4 ± 4.1 pg g−1. The lead concentration in East Antarctic snow (South Pole to Mirny station) was 2 3 times higher than that in West Antarctica (Larsen Ice Shelf to South Pole). Taking into account the difference in site conditions, the difference between the above value over this area in 1989 and the value of 6.3 ±3.3 pg g−1 at a site within this area in 1980 (Wolff and Peel, 1985) is not significant. Because the relative contribution of soil dust, volcanoes and the oceans to lead concentration in Antarctica is about 0.5 pg g−1 under modern climatic conditions (Boutron and Patterson, 1987), it is believed that the lead in Antarctic surface snow is dominated by pollution input. The lead-concentration increase from west to east over the trans-Antarctic route suggests that remote Antarctica has been impacted by anthropogenic activities. The lowest lead flux (0.064 ng cn-2 a−1) was on the Antarctic Plateau, mainly reflecting the background global pollution. The mean flux of 0.273 ng cnT2 a−1 in the western part of the route (Larsen Ice Shelf to the Ellsworth Mountains) may result from the pollution input from the Southern Hemisphere. In addition to the influence of global and/or hemispheric pollution, local activities (notably the use of leaded gasolene) appear to have affected the region from Pionerskaya to Mirny.

The Lambert Glacier basin is a region of the East Antarctic ice sheet with a distinctive topography. Accumulation data derived from cane measurements are available from recent inland traverses in the western part of the basin, together with data on stable isotopes and visible stratigraphy of shallow cores and snow pits. These data suggest that snow accumulation has decreased since the 1930s by 16-37%, but that since the late 1980s it has been increasing. Temperature records from the nearby coastal station, Mawson, show no clear trend. Although the data are from only the western part of the basin, these results are quite different from those in many other regions of Antarctica. Further investigations are needed in this potentially exceptional region.

Through comparison of snow-pit NO3– profiles from central East Antarctica and the northern Qinghai-Tibetan Plateau (QTP), we conclude that NO3– peaks in the uppermost surface snow layers in central East Antarctica are not related to an atmospheric signal and that they need to be accounted for by post-depositional effects. Such effects, however, are not found in the snow-pit NO3– profiles from the northern QTP. NO3– can be deposited as a gas (HNO3–) or as a neutral salt, particularly by reaction with ammonia to form NH4NO3, or fixed by sea salt or terrestrial dust (Mulvaney and others, 1998). Thus, a difference in speciation between NO3– in snow layers in East Antarctica and at the northern QTP is suggested as the reason for the different post-depositional processes of NO3– in the two areas.

Stable oxygen isotope ratios (δ18O) of three shallow ice cores (extending back to 1963) from Urümqi glacier No. 1 at the headwater of Urümqi river, Tien Shan, northwest China, were used to test the relationship between δ18O and contemporaneous surface air temperature (Ta). The ice cores were dated using the seasonal stable-isotopic signals, and seven insoluble particulate β-activity horizons associated with known nuclear tests. Although a strong positive relationship exists between δ18O in precipitation and Ta at our study site, this relationship is not preserved between the annually averaged ice-core δ18O records and the local temperature due to post-depositional modification. These results indicate that the processes forming the ice-core chemical records in areas of high melt must be understood before the δ18O record can be confidently interpreted as a climatic indicator.

A 43 year oxalate record has been recovered in a 14.08m ice core from Ürümqi glacier No. 1 (43˚06’N, 86˚49’ E), a mid-latitude glacier at Ürümqi river head, Tien Shan, western China. Averaging 3.6±9.2 ng g–1 the oxalate has a background level <2 ng g–1 with sporadic concentration enhancements. Most of the spikes reach beyond 10 ng g–1 and have durations 51 year. the oxalate variation correlates with that in Far East Rongbuk Glacier (27˚59’N, 86˚55’ E), Qomolangma (Mount Everest), which is located 1600 kmawayacross the Qinghai–Tibetan Plateau and Taklimakandesert. Although the concentration enhancement in the latter is much higher, and lasts longer, oxalate reaches its highest concentration in both cores at the same time, during winter. the correlation of oxalate records suggests that the two areas may have had the same kind of local sources, but with a much larger (COO)22– flux in the Qomolangma area, or that they may have had a common source in the Indian subcontinent through the longitudinal atmospheric circulation. the concentration variation in the past 40 years coincides with industrial/economic development in southern Asia, and is mainly due to anthropogenic pollution.

A 15.2 m deep firn core and a 2.7 m snow pit were drilled in the western side of Lambert Glacier basin, East Antarctica, in January 1993. the sampling site LGB16 (72.8˚ S, 57.3˚ E) is located about 650 km from the coast, at approximately 2690ma.s.l. the concentration of methanesulfonate (MSA) was determined in the firn core and snow pit. the continuous MSA record from LGB16, spanning about 60 years from 1933 to 1992, displays a decreasing trend in general, and sharp differences between the upper 10.2 m (corresponding to AD 1952) and the bottom part from 10.2 to 15.2 m. the mean MSA concentration for the whole core is 11.3±14.5 ng g–1; for the upper 10.2 m it is 9.3 ±6.3 ng g–1, compared to 15.4±23.0 ng g–1 for the bottom part. the bottom part has a greater number of high MSA peaks, which is consistent with the Cl– and, to a lesser extent, Na+ records for this core. A negative correlation was observed between sea-ice area for the South Indian Ocean sector (40–90˚E) and MSA concentration in LGB16. No significant link was observed between the high MSA concentration and El Niño events at this location.

Surface mass-balance studies and climatic records from firn cores show remarkable differences between the east and west sides of the Lambert Glacier basin (LGB). The spatial distribution of the surface accumulation is influenced by the atmospheric moisture flux, and by the surface wind field, which is largely determined by topography. Atmospheric water-vapor budget data for the ice-sheet sector covering the basin (45–90˚ E) show that on the east side of the LGB the moisture flux is poleward, averaging 18 kgm–1 s–1 in 1988, while for the west side it is Equatorward, averaging 5 kgm–1 s–1. A similar pattern, but with much lower transport of vapor flux, is seen across 70˚ S. Two firn cores from the east side of the basin and two from the west side were analyzed to determine accumulation-rate and temperature-proxy variations for the past 50 years. The trends were opposite on the different sides of the basin. Similar opposing trends are seen in meteorological records from Davis and Mawson coastal stations, situated on the east and west sides of the LGB respectively. There is a good correlation between the accumulation/18O record in ice cores from the eastern LGB and the sea-level pressure (obtained from the US National Centers for Environmental Prediction/US National Center for Atmospheric Research (NCEP/NCAR) re-analyses) of a Southern Indian Ocean low (SIOL), but not between the SIOL and the records from the western LGB. This study reveals that variations in local circulation could alter at least the annual to decadal time-scale climate records, and may result in completely different climate histories between adjacent areas.

The Chinese National Antarctic Research Expedition (GHINARE) carried out three traverses from Zhongshan station to Dome A, Princess Elizabeth Land and Inaccessible Area, East Antarctic ice sheet, during the 1996/97 to 1998/99 Antarctic field seasons. The expeditions are part of the Chinese International Trans-Antarctic Scientific Expedition program. In this project, glaciological investigations of mass balance, ice temperature, ice flow, stratigraphy in snow pits and snow/firn ice cores, as well as the glaciochemical study of surface snow and shallow ice cores, have been carried out. In the 1998/99 field season, CHINARE extended the traverse route to 1128 km inland from Zhongshan station. The density profiles show that firnification over Princess Elizabeth Land and Inaccessible Area (290–1100 km along the route) is fairly slow, and the accumulation rate recovered from snow pits along the initial 460 km of the route is 4.6–21 cm (46–210 kg m–2a–1 ) water equivalent. The initial 460 km of the route can be divided into four sections based on the differences of accumulation rate. This pattern approximately coincides with the study on the Lambert Glacier basin (LGB) by Australian scientists. During the past 50 years, the trends of both air temperature and accumulation rate show a slight increase in this area, in contrast to the west side of the LGB. Data on surface accumulation rates and their spatial and temporal variability over ice-drainage areas such as the LGB are essential for precise mass-balance calculation of the whole ice sheet, and are important for driving ice-sheet models and testing atmospheric models.

Glaciochemical analysis of surface snow samples, collected along a profile crossing the Antarctic ice sheet from the Larsen Ice Shelf, Antarctic Peninsula, via the Antarctic Plateau through South Pole, Vostok and Komsomolskaya to Mirny station (at the east margin of East Antarctica), shows that the Weddell Sea region is an important channel for air masses to the high plateau of the Antarctic ice sheet (>2000 m a.s.l.). This opinion is supported by the following. (1) The fluxes of sea-salt ions such as Na+, Mg2 + and CF display a decreasing trend from the west to the east of interior Antarctica. In |eneral, as sea-salt aerosols are injected into the atmosphere over the Antarctic ice sheet from the Weddell Sea, large aerosols tend to decrease. For the inland plateau, few large particles of sea-salt aerosol reach the area, and the sea-salt concentration levels are low (2) The high altitude of the East Antarctic plateau, as well as the polar cold high-pressure system, obstruct the intrusive air masses mainly from the South Indian Ocean sector. (3) For the coastal regions of the East Antarctic ice sheet, the elevation rises to 2000 m over a distance from several to several tens of km. High concentrations of sea salt exist in snow in East Antarctica but are limited to a narrow coastal zone. (4) Fluxes of calcium and non-sea-salt sulfate in snow from the interior plateau do not display an eastward-decreasing trend. Since calcium is mainly derived from crustal sources, and nssSO42- is a secondary aerosol, this again confirms that the eastward-declining tendency of sea-salt ions indicates the transfer direction of precipitation vapor.

A 2.7 m snow pit was sampled in the Lambert Glacier basin, about 650 km from the coast. Concentrations of methanesulfonic acid (MSA) and non-sea-salt SO42- (nssSO42-) show distinct variation with depth in the snow pit. The seasonal variation of MSA is used to date the snow-pit samples. MSA concentration is in the range 1.922.0 μgkg−1 with a mean of 7.0 μgkg-1. The mean nssSO42- concentration is 41.5 μgkg−1 with a range of 0-87 μgkg−1. The nssSO42- ∼ concentration was calculated by subtracting the sea-salt sulfate contribution using Nai as a conservative tracer. The nssSO42– contributes about 80% of the total sulfate in the snow pit. The mean mass ratio of MSA to nssSO42- 0.176, is much higher than that measured in the low to mid-latitudes, but is very close to the ratio in snow at the South Pole. El Chichon and Hudson volcanic eruptions do not significantly perturb the nssS042- concentrations at this site. MSA concentrations are anticorrelated with sea-ice area for the South Indian Ocean sector between 40° and 90° E, suggesting enhanced MSA production accompanying low sea-ice coverage.

Ice cores recovered for paleoclimatic and/or paleoenvironmental reconstructions in the Tien Shan and Qinghai–Tibetan Plateau often encounter cracks. Although we expect that cracks opened to surface meltwater will inevitably change ice-core records, we do not know how and to what extent records are influenced. An ice core retrieved from glacier No. 1 at Ürümqi river head, Tien Shan, China, exhibits a crack nearly 2.5 m long that has admitted meltwater, forming secondary ice within the fracture. A small inclusion of the infiltrated ice in sampling is shown to reduce δ18O by an extent of Holocene vs Last Glacial Maximum while enhancing significantly the pH, conductivity and the following ionic species: CH3COO–, and CO(COO)22–. of the parameters increased, and HCOO– are the most affected, being enhanced nearly six-fold in the fractured section compared to the non-fractured sections, followed by CO(COO)22– and electrical conductivity measurement (ECM). Despite the alteration, primary fluctuations of some parameters are still recognizable. This suggests that if the infiltrated ice can be avoided in the sampling operation, ice cores with cracks may still provide authentic records. This shows the need to pay close attention to physical characteristics of ice cores in order to identify such secondary ice.

Comparison of the terminus locations of Rongbuk Glacier, Mount Everest, measured in 1966 and 1997 shows that in the past 30 years the glacier has retreated 170–270 m equivalent to a retreat speed of 5.5–8.7 m a–1 . During summer 1997, a 15 m firn core was recovered from Dasuopu glacier (28°23’ N, 85°44’ E; 7000 m a.s.D on the northwest margin of Xixabangma Feng, Xizang (Tibet). The seasonal variations of δ18O values in the core indicate that monsoon signals are clearly recorded in the glacier. δ18O values are controlled by the amount effect in the monsoon season; more negative δ18O is representative of the monsoon season in snow layers. Analysis of the relationship between ice-core δ18O, sampled from 6500 m a.s.l. on the north side of Mount Everest, and instrumental series representing regional-scale precipitation, atmospheric circulation and temperature suggests a change in the relative influence of these parameters on δ18O since the 1940s. The results of the comparison add to and lengthen the sparse array of instrument data available for the Tibetan (Qinghai-Xizang) Plateau and demonstrate a recent decline in moisture flux for at least the southern part of the plateau. Glacier retreat, associated with a recent increase in temperature in the region, is coincident with this period of decreased moisture flux.