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Compound formation properties of very finely layered Mg/Al laminate composite (“super laminate composite”) were investigated. Almost uniform Mg17Al12 compound was obtained by heat treatment of the super laminate at 673K in less than 0.6ks(10 minutes). The rate control process of the compound formation is thought to be the diffusion of Mg in Al. Hydrogenation properties of thus obtained Mg17Al12 compound were also studied and its absorption capacity and dissociation pressure were almost the same as those previously reported material, which was prepared by a longer time heat treatment.
We have prepared Mg/Pd laminate composites with (Mg/Pd)=6, 3 and 2.5 atom ratios, by a super lamination technique. The homogeneous Mg-Pd intermetallic compounds, Mg6Pd, Mg3Pd and Mg5Pd2, are formed during the initial activation process. We investigated the hydrogen storage properties of these materials. The compounds can reversibly absorb and desorb a large amount of hydrogen, up to 1.46˜0.9 H/M, at 573 K. Except for the Mg5Pd2-hydrogen system, the pressure composition-isotherms show two plateaux. The mechanism of the phase transition during hydrogenation/dehydrogenation was analyzed by in-situ XRD measurements. These intermetallic compounds absorb and desorb hydrogen through reversible multistage disproportionation and recombination processes.
Microstructures and hydrogen storage properties of Mg/Cu super-laminates were compared to clarify the effect of initial activation. The initial activation change micro/nano-structures of Mg/Cu super-laminates into Mg2Cu with layered structure in fine grain size of about 1μm and pores highly dispersed between layers in sub-micrometer size. Large surface area, dense defects and short diffusion distance for the reaction enable Mg/Cu super-laminates to absorb hydrogen very quickly.
Super-laminates have been attracting attention since co-authors Ueda et al. reported that Mg/Cu super-laminates showed reversible hydrogenation and dehydrogenation at 473K. The Mg/Cu super-laminates were prepared by a repetitive fold and roll method. Initial activation at 573 K led the super-laminates to absorb hydrogen at 473K. TEM observations of micro/nano-structures in the super-laminates were performed in order to clarify the process of hydrogenation and dehydrogenation at 473K, The as-rolled Mg/Cu super-laminates have laminated structures in size of sub-micrometer thickness composed of Mg and Cu layers with dense lattice defects. The super-laminates after initial activation keep laminated structure and have uniformly distributed pores with a sub-micrometer diameter. It is considered that these micro/nano-structures of Mg/Cu super-laminates lead to lower dehydrogenation temperature and better kinetics, which would contribute to achieve high performance hydrogen storage materials.
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