The surface coating of a gas reaction electrode with layered double hydroxides (LDHs) featuring various electrode catalyst activities was prepared via electrodeposition and the subsequent crystal growth of LDHs. LDH formation was confirmed by X-ray diffraction and Raman scattering measurements after subsequent crystal growth on respective electrodeposited precursor films in Ni-Fe and Zn-Al LDH systems. However, the crystal growth of LDHs in Ni-Mn and Cu-Mn systems was observed on the Mg-Al LDH-electrodeposited films. LDH films were also deposited on the surface of a carbon paper electrode with a rugged surface via electrodeposition and subsequent crystal growth. Using the prepared LDH-coated carbon paper electrodes, the electrode catalytic activity for the oxygen reduction reaction (ORR) was examined. For Ni-Mn, Ni-Al and Ni-Fe LDH-coated carbon paper electrodes, the threshold voltages of the ORR decreased. Hence, the LDHs electrodeposited on a gas reaction electrode have high electrochemical catalytic activity for the ORR.

Tuberculosis (TB) in immigrants is becoming a challenge in eliminating TB in Japan. We investigated the epidemiology of TB in foreign students in Japan in 2015–2019. A total of 2007 foreign students with TB whose median age was 22.5 years (1243 (61.9%) were males) were registered. The notification rates peaked in 2016 at 164.0 per 100 000 population and decreased towards 2019. Of the 2007, 535 were from Vietnam, 444 from China and 395 from Nepal. The notification rates were 596.6 per 100 000 person-years (PYs) for Myanmar, 595.4 for the Philippines and 438.6 for Cambodia. The rates were much higher than those of the general populations in their countries of origin for Myanmar, the Philippines, Cambodia, Indonesia, Nepal, Mongolia, Vietnam and China. In comparison with the years 2010–2014, the notification rates for foreign students decreased for the students from Nepal, Vietnam and China. The TB notification rate of the foreign students in Japan can be a good surrogate indicator for the risk of TB among the immigrant subpopulation in Japan and should continuously be monitored. Those who are at higher risk of TB may be annually screened for TB to prevent TB outbreaks.

We present ALMA detection of the [O iii] 88 μm line and 850 μm dust continuum emission in a Y-dropout Lyman break galaxy, MACS0416_Y1. The [O iii] detection confirms the object with a spectroscopic redshift to be z = 8.3118±0.0003. The 850 μm continuum intensity (0.14 mJy) implies a large dust mass on the order of 4×106M⊙. The ultraviolet-to-far infrared spectral energy distribution modeling, where the [O iii] emissivity model is incorporated, suggests the presence of a young (τage ≍ 4 Myr), star-forming (SFR ≍ 60M⊙yr−1), and moderately metal-polluted (Z ≍ 0.2Z⊙) stellar component with a stellar mass of 3 × 108M⊙. An analytic dust mass evolution model with a single episode of star formation does not reproduce the metallicity and dust mass in ≍ 4 Myr, suggesting an underlying evolved stellar component as the origin of the dust mass.

Extended abstract of a paper presented at Microscopy and Microanalysis 2012 in Phoenix, Arizona, USA, July 29 – August 2, 2012.

New copper rich alloys with elemental additions of transition metals and group IIIA and IVA elements have been prepared by casting and rapid solidification. The prepared alloys show very interesting microstructures; a thick surface layer with nanocrystalline eutectic like structure, while in the bulk the microstructure is coarser lamellar or dendritic. Their microhardness was found to be exceptionally high for Cu rich alloys, reaching values of 450-550HV. Furthermore, the microhardness of the surface layer is higher than that in the bulk, indicating that these alloys can be considered for a variety of applications including tribological and structural.

The Tono uranium deposit (Gifu Prefecture, central Japan) was formed about 10 million years ago and available evidence suggests that this deposit has remained stable, i.e. uranium has not migrated significantly since then. Substantial field and modeling work is being carried out to better understand the hydrogeological and geochemical processes affecting or governing uranium transport and immobilization in and around the Tono uranium deposit. A systems analysis approach has been applied to the Tono deposit natural analogue project. Application of a systems analysis approach to a generic research project is novel and is different from prevailing applications. Previous applications of a systems analysis approach have been principally concerned with performance and safety assessments for radioactive waste disposal. The systems analysis approach provides a convenient framework for this project, having been used in the Tono Natural Analogue Project (TAP) to:

• define the system to be studied;

• identify features, events and processes (FEPs) associated with this system;

• identify external factors (EFEPs) which are likely to have influenced the Tono area or study site or uranium deposit;

• define interactions between pairs of FEPs; and

• develop credible scenarios for evolution of the area or uranium deposit.

The results from the systems analysis approach allow us to:

• develop possible scenarios for how the Tono area or study site evolved,

• evaluate uncertainty and how it propagates backwards in time,

• link field characterization data with predictive modeling, and

• identify gaps in data and, hence, identify additional characterization needs.

The US Constitution preserves the right of the people to petition the government for redress of grievances. This right allows individuals to request private legislation from Congress and, as such, private bill petitions involve individual claims or pleas for relief for a specified person, or persons. Private petitions to Congress fall into two principal categories: claims against the US government (e.g., claims stemming from automobile accidents with government vehicles) and relief from immigration and naturalization laws. Although private laws concerning immigration and naturalization have influenced later public legislation by highlighting areas in need of reform, the private laws have limited application. Other than serving as precedent for subsequent private legislation for similarly situated individuals making requests for enactment of private laws, the laws do not benefit anyone other than the named beneficiaries of the bills.

The joint Nagra/JNC Radionuclide Retardation Programme has now been ongoing for 15 years with the main aim of direct testing of radionuclide transport models in as realistic a manner as possible. A large programme of field, laboratory and natural analogue studies has been carried out at the Grimsel Test Site in the central Swiss Alps and the Kamaishi In Situ Test Site in north-east Japan. The understanding and modelling of both the processes and the structures influencing radionuclide transport/retardation in fractured host rocks have matured as has the experimental technology, which has contributed to develop confidence in the applicability of the underlying research models in a repository performance assessment. In this paper, the successes and set-backs of this programme are discussed as is the general approach to the thorough testing of the process models and of model assumptions. In addition, a set of key findings is presented, involving discussions on the enhancement of confidence through the program.

It is known that any k-uniform family with covering number t has at most ktt-covers. In this paper, we deal with intersecting families and give better upper bounds for the number of t-covers. Let pt(k) be the maximum number of t-covers in any k-uniform intersecting families with covering number t. We prove that, for a fixed t,

formula here

In the cases of t=4 and 5, we also prove that the coefficient of kt−1 in pt(k) is exactly (t2).

The objective of this study is to develop a conceptual flow-path model for nuclide migration in fractured crystalline rock at the Kamaishi In-Situ Test Site because improvement of existing models of matrix diffusion |e.g. 1,2|, based on realistic geological data, is necessary for a better understanding of nuclide migration into rock matrix. Data from field observations indicate that fractures at the Kamaishi In-Situ Test Site can be classified into three types; type A with a zone of fracture fillings, type B with a zone of fracture fillings and an altered zone, type C consisting of several fractures with a zone of fracture fillings and an altered zone. Fracture type B was studied in detail by laboratory experiments because type B is predominant in the studied area with more than 60 % of a total of 400 fractures observed in the fracture mapping. Data from laboratory experiments on core, crosscutting a water-bearing fracture and the surrounding rock, indicate that the zone of fracture fillings and the altered zone in the vicinity of the fracture contain flow-paths in which nuclides can migrate and be trapped. The fracture fillings contain more interconnected and permeable flow-paths than the altered and unaltered zones. This implies that migrating nuclides can access flow-paths in the altered zone. The altered zone adjacent to the zone of the fracture fillings contains flow-paths such as microfractures, cracks within quartz, and grain boundaries between altered minerals, through which nuclides will migrate from the fracture fillings into the altered zone and be trapped. The fracture fillings and the specimen of the altered zone have higher sorption capacity than the specimen of the unaltered zone. These data suggest that retention of nuclides can be expected in the vicinity of the fracture. In conclusion, a conceptual flow-path model consisting of a zone of fracture fillings, an altered zone, and an unaltered zone has been developed for a better understanding of nuclide migration in fracture type B.

The process of the phase transformation of evaporated films of TiO0.5 has been demonstrated by in situ annealing using an electron microscope. Single crystals of the δ-phase, whose structure is identified with Andersson's hexagonal model, precipitate during annealing. Crystal structure images in cooperation with the calculated images reveal that the inner parts of the δ-phase crystal have various thickness. The transition structures I and II having ordered vacancies of titanium and oxygen respectively also appear on annealing. The difference in the distortion of their lattices from the parent rock-salt type lattice suggests that the effective atomic volume of titanium is larger than that of oxygen in the crystal of the transition structure. The observed transformations, α-phase → δ ;phase → transition structure, are explained by consideration of the structural relationships among these phases.