Synthesis of (Pb0.45Ca0.55)(Fe0.5Nb0.5)1-yTiyO3 (y=0 and 0.1; PCFN and PCFNT) ceramics by a reaction-sintering process was investigated. The mixture of raw materials was pressed and sintered into ceramics without any calcination stage involved. The density 5.88g/cm3 (91.6% of the theoretical value) is reached at 1270°C for 2 h soak time in PCFN. Densification increased as B-site was substituted by 10% Ti and a density value 6.21g/cm3 (98.1% of theoretical value) was obtained after 2 h sintering at 1270°C. Grains are of 4.6–19.3μm in PCFN and 2.5–16.5μm in PCFNT at 1150–1270°C. Grain growth was retarded as the B-site was substituted by 10% Ti in PCFN ceramics.