Accumulation rates of biogenic and lithogenic components were studied in 39 turbidite-free, well-dated sediment cores from the northern Indian Ocean to define the proportions of fluvial and eolian input and to reconstruct Quaternary patterns of coastal upwelling. The majority of dust deposited in the western Arabian Sea during the Holocene (about 100 × 106t yr−1) is advected from Arabia by northwesterly winds, which overlie the low-level southwest monsoon. The glacial increase in dust flux to 160 × 106t yr−1 culminated in the northern Arabian Sea, most probably due to (i) entrainment of dust, rich in chlorite, dolomite, and lithogenic carbonate in the then-dry Persian Gulf, and (ii) a southward shift of the mean position of the southwest monsoon during glacial summer. This shift is recorded in reduced accumulation rates of biogenic opal and increased rates of marine carbonate off Somalia and Oman. Both the terrigenous and biogenic sediment records show that the northwesterly winds and the southwest monsoon persisted over the last 27,000 yr, as well as the Asian continental summer heat low. However, the glacial seasonal time span of the southwest monsoon season was much reduced, most likely because of a delay in the seasonal onset of the southwest monsoon.

Marine records from the Reykjanes Ridge indicate ice sheet variations and abrupt climate changes. One of these records, ice-rafted detritus (IRD), serves as a proxy for iceberg discharges that probably indicates ice sheet fluctuations. The IRD records suggest that iceberg discharge 68,000–10,000 yr B.P. happened more frequently than the 7000- to 10,000-yr spacing of the Heinrich events. An IRD peak 67,000 to 63,000 yr B.P. further suggests that the Middle Weichselian glaciation started about 12,000 yr earlier in the North Atlantic than in the Norwegian Sea. Several later IRD events, in contrast, correlate with Norwegian Sea IRD-rich layers and imply coeval ice sheet advances in the North Atlantic and the Norwegian Sea. Coccoliths in a core from the Reykjanes Ridge show distinct peaks in species that record occasional inflow of warm surface water during the last glaciation, as previously reported from the eastern Labrador Sea. High abundances of coccoliths, together with a decrease of Neogloboquadrina pachyderma sin. and relatively low δ18O values, imply enhanced advection of the North Atlantic Current 69,000–67,000 yr B.P., 56,000–54,000 yr B.P., 35,000–33,000 yr B.P., and 26,000–23,000 yr B.P. This advection provided a regional moisture source for extension of ice sheets onto the shelf. In contrast, most of the IRD events are characterized by cold polar surface water masses indicating rapid variations in ocean surface conditions.

Paleoecological records from two Holocene peat bogs in northern Germany are linked by two microscopic volcanic ash layers, correlated by petrology and geochemistry to explosive volcanism on Iceland. The younger “Microlite tephra” cannot be correlated to any known eruption, while the older tephra layer is identified as a deposit of the Hekla 3 eruption. The tephra layers are dated by an age–depth regression of accelerator mass spectrometry 14C ages that have been calibrated and combined in probability distributions. This procedure gives an age of 730–664 cal yr B.C. for the “Microlite tephra” event and 1087–1006 cal yr B.C. for the Hekla 3 event. Accordingly, the tephra layers were deposited during the late Bronze Age. At this time, human settlement slowly increased pressure on the environment, as indicated by changes in woodland pollen composition at the two bogs. The tephra-marker horizons further show that the palynologically defined transition from the Subboreal to the Subatlantic Period is synchronous in the investigated area. However, the macroscopic visible marker in peat, the change from fibrous to sapric peat, the “Schwarztorf-Weißtorf-Kontakt,” is asynchronous. Bog vegetation did not immediately react in unison to a climatic change at this pollen zone boundary; instead, the timing of vegetation change depended on the location within the bog.

Oxygen isotope profiles along the growth axis of fossil bivalve shells of Macoma calcarea were established to reconstruct hydrographical changes in the eastern Laptev Sea since 8400 cal yr B.P. The variability of the oxygen isotopes (δ18O) in the individual records is mainly attributed to variations in the salinity of bottom waters in the Laptev Sea with a modern ratio of 0.50‰/salinity. The high-resolution δ18O profiles exhibit distinct and annual cycles from which the seasonal and annual salinity variations at the investigated site can be reconstructed. Based on the modern analogue approach oxygen isotope profiles of radiocarbon-dated bivalve shells from a sediment core located northeast of the Lena Delta provide seasonal and subdecadal insights into past hydrological conditions and their relation to the Holocene transgressional history of the Laptev Sea shelf. Under the assumption that the modern relationship between δ18Ow and salinity has been constant throughout the time, the δ18O of an 8400-cal-yr-old bivalves would suggest that bottom-water salinity was reduced and the temperature was slightly warmer, both suggesting a stronger mixture of riverine water to the bottom water. Reconstruction of the inundation history of the Laptev Sea shelf indicates local sea level ∼27 m below present at this time and a closer proximity of the site to the coastline and the Lena River mouth. Due to continuing sea level rise and a southward retreat of the river mouth, bottom-water salinity increased at 7200 cal yr B.P. along with an increase in seasonal variability. Conditions comparable to the modern hydrography were achieved by 3800 cal yr B.P.

The Toba volcanic event, one of the largest eruptions during the Quaternary, is documented in marine sediment cores from the northeastern Arabian Sea. On the crest of the Murray Ridge and along the western Indian continental margin, we detected distinct concentration spikes and ash layers of rhyolithic volcanic shards near the marine isotope stage 5–4 boundary with the chemical composition of the “Youngest Toba Tuff.” Time series of the Uk′37-alkenone index, planktic foraminiferal species, magnetic susceptibility, and sediment accumulation rates from this interval show that the Toba event occurred between two warm periods lasting a few millennia. Using Toba as an instantaneous stratigraphic marker for correlation between the marine- and ice-core chronostratigraphies, these two Arabian Sea climatic events correspond to Greenland interstadials 20 and 19, respectively. Our data sets thus depict substantial interstadial/stadial fluctuations in sea-surface temperature and surface-water productivity. We show that variable terrigenous (eolian) sediment supply played a crucial role in transferring and preserving the productivity signal in the sediment record. Within the provided stratigraphic resolution of several decades to centennials, none of these proxies shows a particular impact of the Toba eruption. However, our results are additional support that Toba, despite its exceptional magnitude, had only a minor impact on the evolution of low-latitude monsoonal climate on centennial to millennial time scales.

Downcore studies of planktonic and benthonic foraminifera and δ18O and δ13C in the planktonic foraminifer Neogloboquadrina pachyderma (sin.) in two piston cores from the southern part of the Norwegian Sea suggest large changes in the oceanic circulation pattern at the end of oxygenisotope stage 2 and in the early part of stage 1. Prior to oxygen-isotope Termination IA (16,000–13,000 yr B.P.), an isolated watermass with lower oxygen content and temperature warmer than today existed below a low salinity ice-covered surface layer in the Norwegian Sea. Close to Termination IA, well-oxygenated deep water, probably with positive temperatures, was introduced. This deep water, which must have had physical and/or chemical parameters different from those of present deep water in the Norwegian Sea, could have been introduced from the North Atlantic or been formed within the basin by another mechanism than that which forms the present deep water of the Norwegian Sea. A seasonal ice cover in the southern part of the Norwegian Sea is proposed for the period between Termination IA and the beginning of IB (close to 10,000 yr B.P.). The present situation, with strong influx of warm Atlantic surface-water and deep-water formation by surface cooling, was established at Termination IB.

Two major meltwater events are documented in cores from the NW Labrador Sea. One occurred ca. 20,000 14C yr B.P. in association with deposition of a major detrital carbonate unit. Both prior to and after this event, δ18O values of near-surface planktonic foraminifera were 4.5%, indicating fully enriched glacial values. A younger event (ca. 14,000 14 C yr B.P.) is characterized by a dramatic change in δ18O from 4.5 to 2.0% and coincided with the retreat of ice from the outer SE Baffin Shelf, possibly into Hudson Strait. These meltwater events coincide with Heinrich (H) layers 1 and 2 from North Atlantic sediments. The 14,000 14C yr B.P. meltwater event indicates that the eastern margin of the Laurentide Ice Sheet also underwent rapid retreat at approximately the same time as other ice sheet margins around the NE North Atlantic. A third major detrital carbonate event at the base of HU87-033-009, possibly correlative with Heinrich layer 3, occurred ca. 33,960 ± 675 14 C yr B.P.; however, this is older than the accepted date for H-3 of 27,000 14C yr B.P. and may be H-4.

Climatic reconstruction of glacial to interglacial episodes from oxygen isotopes in sediment cores from the Nordic seas is complicated by strong local meltwater contributions to the oxygen isotope changes. Combination of benthic and planktic foraminiferal isotope data with foraminiferal abundances and ice-rafted debris (IRD) allows separation of local and global effects and subdivision of the marine oxygen isotope events 6.2–5.4, which include the last interglaciation, into: (1) a meltwater phase after glacial stage 6, recorded by large amounts of IRD and low foraminiferal abundance, indicating surface water warming; (2) an IRD-free period with high deposition rates of subpolar foraminifera and other CaCO3 pelagic components, recognized here as the “full” interglaciation; and (3) a phase with the recurrence of IRD and the demise of subpolar species. Comparison of ice-core records and marine data implies that the global climate during the last full interglaciation and that during the postdeglacial Holocene were similar. The records show no significantly different variations in the proxy data. In contrast, the oxygen isotopes of planktic foraminifera and ice cores indicate significant differences during each of the deglacial transitions (Terminations I and II) that preceded these two interglaciations. These suggest that during Termination II the climatic evolution in the Nordic seas was less affected by abrupt changes in ocean–atmosphere circulation than during the last glacial to interglacial transition.

We present two new high-resolution sediment records from the southwestern Iceland and Norwegian Seas that were dated by numerous 14C ages up to 54 14C ka bp. Based on various lines of evidence, the local 14C reservoir effect was restricted to 400–1600 yr. The planktic stable isotope records reveal several meltwater spikes that were sampled with an average time resolution of 50 yr in PS2644 and 130 yr in core 23071 during isotope stage 3. Most of the δ18O spikes correlate peak-by-peak to the stadials and cold rebounds of the Dansgaard-Oeschger cycles in the annual-layer counted GISP2 ice core, with the major spikes reflecting the Heinrich events 1–6. This correlation indicates large fluctuations in the calibration of 14C ages between 20 and 54 14C ka bp. Generally the results confirm the 14C age shifts as predicted by the geomagnetic model of Laj, Mazaud and Duplessy (1996). However, the amplitude and speed of the abrupt decrease and subsequent major increase of our 14C shifts after 45 14C ka bp clearly exceed the geomagnetic prediction near 40–43 and 32–34 calendar (cal) ka bp. At these times, the geomagnetic field intensity minima linked to the Laschamp and the Mono Lake excursions and confirmed by a local geomagnetic record, probably led to a sudden increase in cosmogenic 14C and 10Be production, giving rise to excess 14C in the atmosphere of up to 1200%.

The optimum operating conditions providing minimum run-time and running costs have been studied theoretically for a thermal diffusion plant to be used for the enrichment of the radiocarbon isotope from finite sample size.

The calculations are based on a simple approximate model of the enrichment process, regarding the isotope separation column as operating under quasi-stationary state conditions. The temporal variation of the isotope accumulation is given by a single exponential term. From comparison with the numerical solution of the separation tube equation, approximate models of this simple type appear hardly sufficient for analytical work but seem well suited for optimization calculations. For column operation not too close to the equilibrium state, the approximate run-times were found accurate within 0.2 d.

The approximate model has been applied to a column of the concentric type, operated on gaseous methane. Cross-section configuration and temperatures were not varied (hot and cold wall radii: 2.0 and 2.6cm, respectively; hot and cold wall temperatures: 400°C and 14°C, respectively). The column transport coefficients used were derived from measurements. Run-time was minimized by optimizing both the operating pressure and the sample collection mode for different total sample size (range studied: 24 to 100 g), mass of enriched sample (1.8, 2.4, and 3.0 g), enrichment factor (12, 15, and 20) and column length (8 to 18 m). Optimum working pressures are between 1 and 2 atm. Usually, about 90 percent of the enriched sample mass is extracted favorably from the column itself, the length of the sampling section being about 2.5 to 5 m. Typical runtimes are between 3 days and 2 weeks, and isotope yield may reach 90 percent.

Optimum operating conditions have also been calculated for other column configurations reported in literature and are compared with the experimental results.