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1 results

  • New Borate Structures for Nlo Applications

  • Douglas A. Keszler, Annapoorna Akella, Kathleen I. Schaffers, Theodore Alekel III
  • Journal:
    MRS Online Proceedings Library Archive / Volume 329 / 1993
    Published online by Cambridge University Press:
    15 February 2011, 15
    Print publication:
    1993

  • By considering selected examples of new structure types, guidelines are set forth for the synthesis of new solid-state inorganic borates that are likely to have desirable properties for nonlinear optical applications. The structures of two new, noncentrosymmetric orthoborate fluorides BaCaBO3F and Ba7(BO3)3F5 demonstrate a feasibility for controlling linear optical properties and for producing noncentrosymmetric borates that melt congruently. The structure of SrLi(B3O5)3 represents an additional example of a noncentrosymmetric borate resulting from chirality of the B3O7 ring. In addition to potential practical value, crystals of the type AMOB2O5 (A = K, Rb, and Cs; M = Nb and Ta) provide a unique means for examining the structural dependent interrelationships of linear and nonlinear optical properties.