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Sorption, dissipation, and leaching of metsulfuron in Colorado soils

Published online by Cambridge University Press:  12 June 2017

Brian K. Cranmer
Affiliation:
Department of Bioagricultural Sciences and Pest Management, Colorado State University, Fort Collins, CO 80523
Philip Westra
Affiliation:
Department of Bioagricultural Sciences and Pest Management, Colorado State University, Fort Collins, CO 80523

Extract

Metsulfuron sorption, dissipation, and leaching were studied in six Colorado soils. Sorption was studied in the laboratory by batch equilibration of soil horizons from the surface to 1 m deep found in each study area. Kd was correlated to several soil parameters with pH (-0.773) and percent organic matter (OM) (0.666) the strongest, although low. Kd generally decreased with depth at each site and ranged from 0.10 to 0.83 among surface soils. The lowest Kd was in the soil with the highest pH. Leaching and dissipation were studied by high-performance liquid chromatography/ultraviolet analysis of field samples collected 1 m deep. Bromide ion as conservative tracer was applied concurrently with metsulfuron at the four dryland and two irrigated sites. In most cases, metsulfuron was found only in upper horizons, and the half-life ranged from 11.8 to 27.7 d, the shortest being in the soil with highest percent OM and lowest pH. Very little leaching below the surface horizon was detected in any soil.

Type
Soil, Air, and Water
Copyright
Copyright © 1999 by the Weed Science Society of America 

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References

Literature Cited

Abadalla, N. A. and Lear, B. 1975. Determination of inorganic bromide in soils and plant tissues with a bromide selective-ion electrode. Commun. Soil Sci. Plant Anal. 6:489494.Google Scholar
Anderson, R. L. 1985. Environmental effects of metsulfuron-methyl and chlorsulfuron bioactivity in soil. J. Environ. Qual. 14:517521.Google Scholar
Beyer, E. M. Jr., Duffy, M. J., Hay, J. V., and Schleuter, D. D. 1988. Sulfonylureas. Pages 117189 in Kearney, P.C. and Kaufman, D.D. ed. Herbicides: Chemistry, Degradation, and Mode of Action. Volume 3. New York: M. Dekker.Google Scholar
Brewster, B. D. and Appleby, A. P. 1983. Response of wheat (Triticum aestivum) and rotation crops to chlorsulfuron. Weed Sci. 31:861865.Google Scholar
Brown, H. M. 1990. Mode of action, crop selectivity, and soil relations of sulfonylurea herbicides. Pestic. Sci. 29:263281.CrossRefGoogle Scholar
Duffy, M. J., Hanafey, M. K., Linn, D. M., Russell, M. H., and Peter, C. J. 1987. Predicting sulfonylurea herbicide behavior under field conditions. Pages 541547 in Proceedings of the British Crop Protection Conference—Weeds.Google Scholar
Frederickson, D. R. and Shea, P. J. 1986. Effect of soil pH on degradation movement and plant uptake of chlorsulfuron. Weed Sci. 34:328332.Google Scholar
James, T. K., Klaffenbach, P., Holland, P. T., and Rahman, A. 1995. Degradation of primisulfuron-methyl and metsulfuron-methyl in soil. Weed Res. 35:113120.CrossRefGoogle Scholar
Joshi, M., Brown, H. M., and Romesser, J. A. 1985. Degradation of chlorsulfuron by soil microorganisms. Weed Sci. 33:888893.Google Scholar
Junnila, S., Heinonen-Tanksi, H., Erviö, L. R., and Laitinen, P. 1994. Phytotoxic persistence and microbiological effects of chlorsulfuron and metsulfuron in Finnish soils. Weed Res. 34:413423.Google Scholar
Kotoula-Syka, E., Eleftherohorinos, I. G., Gagianas, A. A., and Sficas, A. G. 1993. Persistence and preemergence applications of chlorsulfuron, metsulfuron, triasulfuron, and tribenuron in three soils in Greece. Weed Sci. 41:246250.Google Scholar
Mersie, W. and Foy, C. L. 1985. Phytotoxicity and adsorption of chlorsulfuron as affected by soil properties. Weed Sci. 33:564568.CrossRefGoogle Scholar
Nichols, P. H. and Evans, A. A. 1985. Adsorption and movement in soils of chlorsulfuron and other weak acids. Pages 333339 in Proceedings of the British Crop Protection Conference—Weeds.Google Scholar
Nillson, H. and Hallgreen, E. 1990. Persistence and mobility of chlorsulfuron (Glean 20 DF) and metsulfuron-methyl (Ally 20 DF) in an arable soil with high pH-level: two field experiments on the island of Gotland during 1987 and 1988. Pages 101113 in Proceedings of the Swedish Crop Protection Conference. Uppsala, Sweden: Swedish University of Agricultural Science.Google Scholar
Onken, A., Hargrove, R., Wendt, C., and Wilke, O. 1975. The use of a specific ion electrode for determination of bromide in soils. Soil Sci. Soc. Am. Proc. 39:12231225.Google Scholar
Peterson, M. A. and Arnold, W. E. 1985. Response of rotational crops to soil residues of chlorsulfuron. Weed Sci. 34:131136.Google Scholar
Shea, P. 1986. Chlorsulfuron dissociation and adsorption on selected adsorbents and soils. Weed Sci. 34:474478.CrossRefGoogle Scholar
Thirunarayanan, K., Zimdahl, R. L., and Smika, D. E. 1985. Chlorsulfuron adsorption and degradation in soil. Weed Sci. 33:558563.Google Scholar
Vicari, A., Catizone, P., and Zimdahl, R. L. 1994. Persistence and mobility of chlorsulfuron and metsulfuron under different soil and climatic conditions. Weed Res. 34:147155.Google Scholar
Wadd, D. J. and Drennan, D.S.H. 1989. A field study of the persistence and leaching of chlorsulfuron and metsulfuron-methyl. Pages 11331138 in Proceedings of the British Crop Protection Conference—Weeds.Google Scholar
Walker, A. and Barnes, A. 1981. Simulation of herbicide persistence in soil: a revised computer model. Pestic. Sci. 12:123132.Google Scholar
Walker, A. and Brown, P. A. 1983. Measurement and prediction of chlorsulfuron persistence in soil. Bull. Environ. Contain. Toxicol. 30:365372.CrossRefGoogle ScholarPubMed
Walker, A. and Welch, S. J. 1989. The relative movement and persistence in soil of chlorsulfuron, metsulfuron-methyl, and triasulfuron. Weed Res. 29:375383.Google Scholar
Walker, A., Cotterill, E. G., and Welch, S. J. 1989. Adsorption and degradation of chlorsulfuron and metsulfuron-methyl in soils from different depths. Weed Res. 29:281287.Google Scholar
Wiese, A. F., Wood, M. L., and Chenault, E. W. 1988. Persistence of sulfonylureas in Pullman clay loam. Weed Technol. 2:251256.Google Scholar
Zimdahl, R. L. and Fithian, W. A. 1984. Chlorsulfuron Soil Persistence. Research Progress Report of the Western Society of Weed Science.Google Scholar