Hostname: page-component-8448b6f56d-qsmjn Total loading time: 0 Render date: 2024-04-16T17:51:51.848Z Has data issue: false hasContentIssue false

Deposition of DLC:H films by C-sputtering assisted CH4-Ar PE-CVD technique

Published online by Cambridge University Press:  28 June 2007

K. Yokota*
Affiliation:
Faculty of Engineering and HRC, Kansai University, Suita, Osaka, 564-8680, Japan
T. Nakatani
Affiliation:
Faculty of Engineering and HRC, Kansai University, Suita, Osaka, 564-8680, Japan
F. Miyashita
Affiliation:
Faculty of Informatics, Kansai University, Takatsuki, Osaka, 569-1095, Japan
Get access

Abstract

Hydrogenated diamond-like carbon (DLC:H) films were deposited on Si substrates by a methane (CH4)-argon (Ar) plasma enhanced chemical vapor deposition (PE-CVD) technique assisted by carbon (C) sputtering. The deposition rates of DLC:H films increased with increasing Ar gas flow rate under a CH4 gas flow rate, and saturated at large Ar gas flow rates. The dielectric constants varied from 2.2 ε0 on DLC:H films deposited without Ar gas flow to 6.3 ε0 on DLC:H films deposited with large Ar gas flow. The CV curve for the sweep of bias voltages from positive to negative was positioned above that of the return sweep of bias voltages from negative to positive because electrons are injected from Si substrates to the surfaces of DLC:H films. The CV curve on the returning bias voltage sweep approached that of the going bias voltage sweep accompanying to an increase in dielectric constant.

Keywords

Type
Research Article
Copyright
© EDP Sciences, 2007

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Borhr, M., Elmansy, Y.A., IEEE Trans. Electron Devices 45, 620 (1998) CrossRef
W.C. Holton, J.R. Hauser, K.W. Kim, W.T. Lynch, in Handbook of Semiconductor Manufacturing Technology, edited by Y. Nishi, R. Doering (Marcel Dekker, New York, 2000)
Lee, W.W., Ho, P.S., MRS Bull. 22, 19 (1997)
K. Endo, Y. Matsubara, in Handbook of Low and High Dielectric Constants and Their Applications, edited by H.S. Nalwa (Academic, San Diego, 1999), p. 141
D.S. Dandy, M.E. Coltrin, in Diamond Films Handbook, edited by J. Asmussen, D.K. Reinhard (Marcel, New York, 2002), pp. 55–118
Endo, K., Tatsumi, T., Appl. Phys. Lett. 68, 2864 (1996) CrossRef
Joint Committee for Powder Diffraction Standards, Powder Diffraction File, Int. Center for Diffraction Data, Park lane, No. 50–1084
Joint Committee for Powder Diffraction Standards, Powder Diffraction File, Int. Center for Diffraction Data, Park lane, No. 50–1086
Master, M.C., Hsu, W.L., Coltrin, M.E., Dandy, D.S., Fox, C., Diamond Relat. Mater. 4, 1000 (1995) CrossRef
P.W. Atkins, Physical Chemistry (Oxford, 1998), p. 942
D.R. Lide, Handbook of Chemistry and Physics, 80th edn. (CRC, Boca Raton, 2007), pp. 12–53
Sakaue, H., Yoshimura, N., Shingubara, S., Takahagi, T., Appl. Phys. Lett. 83, 2226 (2003) CrossRef
Joint Committee for Powder Diffraction Standards, Powder Diffraction File, Int. Center for Diffraction Data, Park lane, No. 17–901
Grill, A., Patel, V., Saenger, K.L., Jahnes, C., Cohen, S.A., Schrott, A.G., Edelstein, D.C., Paraszczak, J.R., Ser. Mater. Res. Soc. Symp. Proc. 443, 155 (1997) CrossRef
S. Habermehl, J. Appl. Phys. 83 4672 (1997)
H. Alexander, in Handbook of Semiconductor Technology, edited by K.A. Jackson, W. Schroter (Wiley, Weinheim, 2000), Chap. 6
D.K. Schroder, Semiconductor Material and Device Characterization, 2nd edn. (Wiley, New York, 1998), Chap. 6
J. Robertson, in Thin Film Diamon, edited by A. Lettington, J.W. Steeds (Chapman, London, 1994), p. 108