Hostname: page-component-8448b6f56d-gtxcr Total loading time: 0 Render date: 2024-04-23T11:47:05.936Z Has data issue: false hasContentIssue false

Radiocarbon AMS Data Analysis: From Measured Isotopic Ratios to 14C Concentrations

Published online by Cambridge University Press:  18 July 2016

Ugo Zoppi*
Affiliation:
Accium BioSciences Inc., 550 17th Avenue, Suite 550, Seattle, Washington 98122, USA. Email: uzoppi@acciumbio.com
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

Radiocarbon accelerator mass spectrometry (AMS) measurements are always carried out relative to internationally accepted standards with known 14C activities. The determination of accurate 14C concentrations relies on the fact that standards and unknown samples must be measured under the same conditions. When this is not the case, data reduction is either performed by splitting the collected data set into subsets with consistent measurement conditions or by applying correction factors.

This paper introduces a mathematical framework that exploits the intrinsic variability of an AMS system by combining arbitrary measurement parameters into a normalization function. This novel approach allows the en-masse reduction of large data sets by providing individual normalization factors for each data point. Both general features and practicalities necessary for its efficient application are discussed.

Type
Methods, Applications, and Developments
Copyright
Copyright © 2010 by the Arizona Board of Regents on behalf of the University of Arizona 

References

Bronk Ramsey, C, Hedges, REM. 1994. Carbon dioxide sputter source development at Oxford. Nuclear Instruments and Methods in Physics Research B 92(1–4): 100–4.Google Scholar
Bronk Ramsey, C, Hedges, REM. 1997. Hybrid ion sources: radiocarbon measurements from microgram to milligram. Nuclear Instruments and Methods in Physics Research B 123(1–4):539–45.Google Scholar
Donahue, DJ, Linick, TW, Jull, AJT. 1990. Isotope-ratio and background corrections for accelerator mass spectrometry radiocarbon measurements. Radiocarbon 32(2):135–42.Google Scholar
Hua, Q, Zoppi, U, Williams, AA, Smith, AM. 2004. Small-mass AMS radiocarbon analysis at ANTARES. Nuclear Instruments and Methods in Physics Research B 223–224:284–92.Google Scholar
Le Clercq, M, van der Plicht, J, Gröwing, M. 1998. New 14C reference materials with activities of 15 and 50 pMC. Radiocarbon 40(1):295–7.Google Scholar
Mook, W, van der Plicht, J. 1999. Reporting 14C activities and concentrations. Radiocarbon 41(3):227–9.Google Scholar
McNichol, AP, Jull, AJT, Burr, GS. 2001. Converting AMS data to radiocarbon values: considerations and conventions. Radiocarbon 43(2A):313–20.Google Scholar
Puchegger, S, Rom, W, Steier, P. 2000. Automated evaluation of 14C AMS measurements. Nuclear Instruments and Methods in Physics Research B 172(1–4):274–80.Google Scholar
Schneider, RJ, Jones, GA, McNichol, AP, von Reden, KF, Elder, KL, Huang, K, Kessel, ED. 1994. Methods for data screening, flagging and error analysis at the National Ocean Sciences AMS Facility. Nuclear Instruments and Methods in Physics Research B 92(1–4):172–5.Google Scholar
Scott, EM, Cook, GT, Naysmith, P. 2007. Error and uncertainty in radiocarbon measurements. Radiocarbon 49(2):427–40.Google Scholar
Séguin, FH, Schneider, RJ, Jones, GA, von Reden, KF. 1994. Optimized data analysis for AMS radiocarbon dating. Nuclear Instruments and Methods in Physics Research B 92(1–4):176–81.Google Scholar
Steier, P, Dellinger, F, Kutschera, W, Priller, A, Rom, W, Wild, EM. 2004. Pushing the precision limit of 14C AMS. Radiocarbon 46(1):516.Google Scholar
Stuiver, M. 1983. International agreements and the use of the new oxalic acid standards. Radiocarbon 25(2):793–5.Google Scholar
Tumey, SJ, Grabowski, KS, Knies, DL, Mignerey, AC. 2004. Radiocarbon data collection, filtering and analysis at the NRL TEAMS facility. Nuclear Instruments and Methods in Physics Research B 223–224:216–20.Google Scholar
Zoppi, U, Arjomand, A. 2009. Simultaneous AMS determination of 14C content and total carbon mass in biological samples. Nuclear Instruments and Methods in Physics Research B. doi:10.1016/j.nimb.2009.10.159.Google Scholar
Zoppi, U, Crye, J, Song, Q, Arjomand, A. 2007. Performance evaluation of the new AMS system at Accium BioSciences. Radiocarbon 49(1):173–82.Google Scholar