Hostname: page-component-8448b6f56d-xtgtn Total loading time: 0 Render date: 2024-04-19T05:30:33.244Z Has data issue: false hasContentIssue false

ESR and 230Th/234U dating of speleothems from Aladağlar Mountain Range (AMR) in Turkey

Published online by Cambridge University Press:  20 January 2017

Ülkü Ulusoy*
Affiliation:
Dept. of Physics Engineering, Hacettepe University, Beytepe, 06800 Ankara, Turkey
Gül Anbar
Affiliation:
Dept. of Physics Engineering, Hacettepe University, Beytepe, 06800 Ankara, Turkey
Serdar Bayarı
Affiliation:
Dept. of Geological Engineering, Hacettepe University, Beytepe, 06800 Ankara, Turkey
Tonguç Uysal
Affiliation:
Earth Sciences and Centre for Microscopy and Microanalysis, University of Queensland, Brisbane, QLD 4072, Australia
*
*Corresponding author. Fax: + 90 312 299 2037. E-mail address:ulusoy@hacettepe.edu.tr (Ü. Ulusoy).

Abstract

Electron spin resonance (ESR) and 230Th/234U ages of speleothem samples collected from karstic caves located around 3000 m elevation in the Aladağlar Mountain Range (AMR), south-central Turkey, were determined in order to provide new insight and information regarding late Pleistocene climate. ESR ages were validated with the 230Th/234U ages of test samples. The ESR ages of 21 different layers of six speleothem samples were found to range mostly between about 59 and 4 ka, which cover the Marine Oxygen Isotope Stages (MIS) MIS 3 to MIS 1. Among all, only six layers appear to have deposited during MIS 8 and 5. Most of the samples dated were deposited during the late glacial stage (MIS 2). It appears that a cooler climate with a perennial and steady recharge was more conducive to speleothem development rather than a warmer climate with seasonal recharge in the AMR during the late Quaternary. This argument supports previous findings that suggest a two -fold increase in last glacial maximum mean precipitation in Turkey with respect to the present value.

Type
Research Article
Copyright
University of Washington

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Akcar, N., Yavuz, V., Ivy-Ochs, S., Kubik, P.W., Vardar, M., and Schluechter, C. Paleoglacial records from Kavron Valley, NE Turkey: field and cosmogenic exposure dating evidence. Quaternary International 164–65, (2007). 170183.Google Scholar
Anbar, G. ESR (Electron Spin Resonance) Studies of Cave Deposits. (M.Sc. Thesis) (2006). Hacettepe University, Turkey. (63 pp. (in Turkish)) Google Scholar
Arakawa, T., and Hori, N. ESR dating of carbonate speleothem rings and late Quaternary climatic changes in the Ryukyu Islands, Japan. Applied Radiation and Isotopes 40, 10–12 (1989). 11431146.CrossRefGoogle Scholar
Bahain, J.J., Sarcia, M.N., Falgueres, C., and Yokoyama, Y. Attempt at ESR dating of tooth enamel from French Middle Pleistocene sites. Applied Radiation Isotopes 44, (1993). 267272.Google Scholar
Bahain, J.J., Yokoyama, Y., Masaoudi, H., Falgueres, C., and Laurent, M. Thermal behaviour of ESR signals observed in various natural carbonates. Quaternary Geochronology (Quaternary Science Reviews) 13, (1994). 671674.Google Scholar
Bayari, C.S., Zreda, M., Ciner, A., Nazik, L., Tork, K., Ozyurt, N.N., Klimchouk, A., and Sarikaya, M.A. The extent of Pleistocene ice cap, glacial deposits and glaciokarst in the Aladaglar Massif: Central Taurids Range, Southern Turkey. XVI INQUA Congress, Paper #55360, XVI INQUA Congress, Reno Nevada USA, 23–30 July 2003, Abstracts. (2003). 144 Google Scholar
Bevington, P.R., and Robinson, D.K. Data Reduction and Error Analysis for Physical Sciences. (2003). McGraw-Hill book Company, Google Scholar
Blackwell, B.A.B. Electron spin resonance (ESR) dating in karst environments. Acta Carsologica 35, 2 (2006). 123153.CrossRefGoogle Scholar
Bourdon, B., Henderson, G.M., Lundstrom, C.C., and Turner, S.P. Uranium-series Geochemistry. Reviews in Mineralogy an Geochemistry, 52. (2003). Mineralogical Society of America, Washington, D.C..Google Scholar
Ciner, A. Recent glaciers and late quaternary glacial deposits of Turkey. Geological Bulletin of Turkey 46, 1 (2003). 5578.Google Scholar
Clark, R.C., Zhao, J.X., Feng, Y.X., Dones, T.J., Jupiter, S., Lough, J., and Padolfi, J.M. Spatial variability of initial 230Th/232Th in modern Porites from the inshore region of the Great Barrier Reef. Geochimica et Cosmochimica Acta 78, (2012). 99118.CrossRefGoogle Scholar
Duval, M., Grün, R., Falgueres, C., Bahain, J.J., and Dolo, J.M. ESR dating of Lower Pleistocene fossil teeth: limits of the single saturating exponential (SSE) function for the equivalent dose determination. Radiation Measurements 44, 5–6 (2009). 477482.Google Scholar
Erdoğu, B., Uysal, T., Özbek, O., and Ulusoy, Ü. Speleothems of Çatalhöyük, Turkey. Mediterranean Arhaeology and Archaeometry 13, 1 (2013). 2130.Google Scholar
Fontugne, M., Kuzucuoglu, C., Karabiyikoglu, M., Hatté, C., and Pastre, J.F. From Pleniglacial to Holocene: a 14C chronostratigraphy of environmental changes in the Konya Plain, Turkey. Quaternary Science Reviews 18, (1999). 573591.Google Scholar
Ford, D. Castleguard Cave. Culver, David C., and White, William B. Encyclopedia of Caves. 2nd ed. (2012). Academic Press, 8994.Google Scholar
Grün, R. ESR Dating Speleothem: Limits of the Method. ESR Dating and Dosimetry. (1985). 6172.Google Scholar
Grün, R. Electron spin resonance (ESR) dating. Quaternary International 1, (1989). 65109.Google Scholar
Grün, R., and Brumby, S. The assessment of errors in past radiation doses extrapolated from ESR/TL dose response data. Radiation Measurements 23, 2–3 (1994). 307315.Google Scholar
Grün, R., Schwarcz, H.P., Ford, D.C., and Hentzsch, B. ESR dating of spring deposited travertine. Quaternary Science Reviews 7, (1988). 429432.Google Scholar
Guerin, G., Mecier, N., and Adamiec, G. Dose-rate conversion factors: update. Ancient TL 29, 1 (2011). 58.Google Scholar
Hellstrom, J. Rapid and accurate U/Th dating using parallel ion-counting multi-collector ICP-MS. Journal of Analytical Atomic Spectrometry 18, (2003). 13461351.Google Scholar
Hennig, G.J., and Geyh, M.A. The first inter-laboratory ESR comparison project phase II: evaluation of equivalent doses (ED) of calcites. Nuclear Tracks 10, 4–6 (1985). 945952.Google Scholar
Ikeya, M. Dating a stalactite by electron paramagnetic resonance. Nature 255, (1975). 4850.CrossRefGoogle Scholar
Ikeya, M. Electron spin resonance as a method of dating. Archaeometry 20, (1978). 147158.Google Scholar
Ikeya, M. Spin resonance ages of brown rings in cave deposits. Naturwissen 65, (1978). 489 CrossRefGoogle Scholar
Ikeya, M. New Applications of ESR-dating, Dosimetry and Microscopy. 2nd ed. (2001). World Scientific, Singapore.Google Scholar
Ikeya, M. Electron paramagnetic resonance. ESR Dating, Dosimetry and Microscopy for Terrestrial and Planetary Materials. (2004). RSC Publishing, 125. (chapter 1) Google Scholar
Ikeya, M., and Ohmura, K. Dating of fossil shells with electron spin resonance. Journal of Geology 89, (1981). 247251.Google Scholar
Imbrie, J., McIntyre, A., Mix, A. Berger, A. et al. Oceanic response to orbital forcing in the late Quaternary: observational and experimental strategies. Climate and Geosciences 285, (1989). Kluwer Academic, Norwell, MA. 121164.Google Scholar
Ivanovich, M., and Harmon, R.S. Uranium Series Disequilibrium: Application to Environmental Problems in the Earth Sciences. (1992). Oxford University Press, Oxford.Google Scholar
Klimchouk, A., Bayari, S., Nazik, L., and Tork, K. Glacial destruction of cave systems in high mountains, with special reference to the Aladaglar massif, Central Taurids, Turkey. Acta Carsologica 35, 2 (2006). 111122.Google Scholar
Ku, T.L., and Liang, Z.C. The dating of impure carbonates with decay-series isotopes. Section A — Accelerators spectrometers detectors and associated equipment. Nuclear Instruments and Methods in Physics Research 223, (1984). 563571. (2–3) Google Scholar
Kuzucuoglu, C. Upper and Late Pleistocene environmental changes in Anatolia, reconstructed from sediment sequences and landforms studies. Proc. of Int. Symp. on Earth System Sci. September 8–10 2004, Istanbul Turkey. (2004). 1927.Google Scholar
Li, W.X., Lundberg, J., Dickin, A.P., Ford, D.C., Schwarcz, H.P., McNutt, R., and Williams, D. High-precision mass-spectrometric uranium series dating of cave deposits and implications for palaeclimate studies. Nature 339, (1989). 534536.CrossRefGoogle Scholar
Lyons, R.G., and Brennan, B.J. Alpha/gamma effectiveness ratios of calcite speleothems. Nuclear Tracks and Radiation Measurements 18, (1991). 223227. (no ½) Google Scholar
McCulloch, M.T., and Mortimer, G. Applications of the 238U–230Th decay series to dating of fossil and modern corals using MC-ICPMS. Australian Journal of Earth Sciences 55, 6 (2008). 955965.CrossRefGoogle Scholar
Muhammad, R.F., Yoshida, D., Tani, A., and Smart, P.L. Implications of electron spin resonance and uranium-series dating techniques on speleothemin the Kinta and Lenggong Valleys, West Malaysia. Advances in ESR Applications 18, (2002). 1926.Google Scholar
Pirouelle, F., Bahain, J.J., Falgueres, C., and Dolo, J.M. Study of the effect of a thermal treatment on the DE determination in ESR dating of speleothems. Quaternary Geochronology 2, (2007). 386391.Google Scholar
Railsback, L.C., Dabous, A.A., Osmond, J.K., and Fleisher, C.J. Petrographic and geochemical screening of speleothems for U-series dating: an example from recrystallized speleothems from Wadi Sannur Cavern, Egypt. Journal of Cave and Karst Studies 64, 2 (2002). 108116.Google Scholar
Rink, W.J. Electron spin resonance (ESR) dating and ESR applications in Quaternary science and archaometry. Radiation Measurements 27, (1997). 9751025.CrossRefGoogle Scholar
Roberts, N. Age, paleoenvironments, and climatic significance of late Pleistocene Konya Lake, Turkey. Quaternary Research 19, (1983). 154171.CrossRefGoogle Scholar
Roberts, N., Black, S., Boyer, P., Eastwood, W., Griffiths, H., Lamb, H., Leng, M., Parish, R., Reed, J., Twigg, D., and Yigitbasioglu, H. Chronology and stratigraphy of late Quaternary sediments in the Konya Basin, Turkey: results from the KOPAL project. Quaternary Science Reviews 18, (1999). 611630.Google Scholar
Sarikaya, M.A., Zreda, M., Ciner, A., and Zweck, C. Cold and wet Last Glacial Maximum on Mount Sandıras, SW Turkey, inferred from cosmogenic dating and glacier modeling. Quaternary Science Reviews 27, 7–8 (2008). 769780.Google Scholar
Sarikaya, M.A., Zreda, M., and Ciner, A. Glaciations and paleoclimate of Mount Erciyes, central Turkey, since the Last Glacial Maximum, inferred from 36Cl cosmogenic dating and glacier modeling. Quaternary Science Reviews 28, 23–24 (2009). 23262341.Google Scholar
Sarikaya, M.A., Ciner, A., and Zreda, M. Quaternary glaciations of Turkey. Ehlers, J., Gibbard, P.L., and Hughes, P.D. Quaternary glaciations-extent and chronology; a closer look. Developments in Quaternary Science 15, (2011). Elsevier Publications, Amsterdam The Netherlands. 393403.CrossRefGoogle Scholar
Sarikaya, M.A., Ciner, A., Haybat, H., and Zreda, M. An early advance of glaciers in Mount Akdağ, SW Turkey, before the global Last Glacial Maximum; insights from cosmogenic nuclides. Quaternary Science Reviews 88, (2014). 96109.Google Scholar
Schellmann, G., Koen, B., and Radtke, U. Electron spin resonance (ESR) dating of Quaternary materials. Eiszeitalter und Gegenwart. Quaternary Science Journal 57, 1–2 (2008). 150178.Google Scholar
Skinner, A.R. ESR dating: is it still an “experimental” technique?. Applied Radiation and Isotopes 52, (2000). 13111316.Google Scholar
Spreitzer, H. Rezente und eiszeitliliche Grenzen der glazialen und periglazialen Höhenstufen im Zentralen Taurus (vorehmlich am Beispiel des Kilikischen Ala Dag. Mitteilungen des Naturwissenschaftlichen Vereines Fur Steiermark 101, (1971). 139162.Google Scholar
Taboroši, D., Hirakawa, K., and Sawagaki, T. Carbonate precipitation along a microclimatic gradient in a Thailand cave — continuum of calcareous tufa and speleothems. Journal of Cave and Karst Studies 67, (2005). 6987.Google Scholar
Törk, K. Written Communication. (2008). MTA, Ankara Turkey.Google Scholar
Ulusoy, Ü. ESR dating of a quartz single crystal from the Menderes Massif—Turkey. Applied Radiation and Isotopes 52, (2000). 13631370.Google Scholar
Ulusoy, Ü. The investigation of ESR dating by using alpha rays, The Society of ESR Applied Metrology. Advances in ESR Applications 18, (2002). 163166.Google Scholar
Ulusoy, Ü. ESR studies of a quartz single crystal from the Menderes Massif—Turkey. Turkish Journal of Physics 27, 4 (2003). 263269.Google Scholar
Ulusoy, Ü. ESR dating of faults: North Anatolian—Turkey and Nojima—Japan Faults. Quaternary Science Reviews 23, (2004). 161174.CrossRefGoogle Scholar
Ulusoy, Ü. ESR studies of Anatolian gypsum. Spectrochimica Acta A 60, (2004). 13591365.CrossRefGoogle ScholarPubMed
Ulusoy, Ü., and Ikeya, M. ESR studies of sepiolites. Applied Magnetic Resonace 18, (2000). 537548.CrossRefGoogle Scholar
Ulusoy, Ü., Anbar, G., Bayarı, S., and Özyurt, N. ESR (Electron Spin Resonance) Dating of the Paleoenvironment Archives Deposited in the Cave. XXVIII European Congress on Molecular Spectroscopy, İ.Ü., 3–8 September 2006, Abstract, İstanbul—Turkey. (2006). Google Scholar
Waltham, A.C., Simms, M.J., Farrant, A.R., and Goldie, H.S. Karst and caves of Great Britain. Geological Conservation Review Series, No 12. (1997). Chapman and Hall, London.Google Scholar
Whitehead, N.E., Lyon, G.L., Claridge, G.C., Sato, H., and Ikeya, M. ESR studies on Antarctic carbonates and sulphates. The Society of ESR Applied Metrology. Advances in ESR Applications 18, (2002). 1118.Google Scholar
Yamamoto, Y., Toyoda, S., Nagasima, K., Igarashi, Y., and Tada, R. The grain size influence on the E' centre observed in quartz of atmospheric deposition at two Japanese cities: a preliminary study. Geochronometria 37, (2010). 912.CrossRefGoogle Scholar
Yokoyama, Y., Quaegebeur, J.P., Bibron, R., and Leger, C. ESR dating of Paleolithic calcite; thermal annealing experiment & trapped electron lifetime. PACT 9, (1983). 372379.Google Scholar
Yokoyama, Y., Bibron, R., and Leger, C. ESR dating of palaeolithic calcite: fundamental studies. Nuclear Tracks 10, 4–6 (1985). 929936.Google Scholar
Young, H.D. Statistical Treatment of Experimental Data. (1962). McGraw-Hill book Company, Google Scholar
Zahno, C., Akçar, N., Yavuz, V., Kubik, P.W., and Schlüchter, C. Surface exposure dating of Late Pleistocene glaciations at the Dedegöl Mountains (Lake Beyşehir, SW Turkey). Journal of Quaternary Science 24, (2009). 10161028.Google Scholar
Zhao, J.X., Hu, K., Collerson, K.D., and Xu, H.K. Thermal ionisation mass spectrometry U-series dating of a hominid site near Nanjing, China. Geology 29, (2001). 2730.2.0.CO;2>CrossRefGoogle Scholar
Zreda, M., and Phillips, F.M. Surface exposure dating by cosmogenic 36Cl accumulation. Beck, C. Dating in Exposed and Surface Contexts. (1994). University of New Mexico Press, Albuquerque. 161184.Google Scholar
Zreda, M., Ciner, A., Sarikaya, M.A., and Bayari, C.S. Glaciers and Late Quaternary glacial deposits of Turkey. XVI INQUA Congress, Paper #55388, XVI INQUA Congress, Reno Nevada USA, 23–30 July 2003, Abstracts. (2003). 72 Google Scholar
Zreda, M., Ciner, A., Bayari, S., and Sarikaya, A. Remarkably extensive early Holocene glaciation in Turkey. EGU 2005, 24–29 April 2005 Vienna. Geophysical Research Abstracts 7, 06068 (2005). Google Scholar
Zreda, M., Ciner, A., Sarikaya, M.A., Zweck, C., and Bayari, S. Remarkably extensive glaciation and fast deglaciation and climate change in Turkey near the Pleistocene–Hologene boundary. Geology Society of America, Geology 39, (2011). 10511054. (no. 11) Google Scholar