Hostname: page-component-8448b6f56d-jr42d Total loading time: 0 Render date: 2024-04-25T04:27:45.341Z Has data issue: false hasContentIssue false
  • English
  • Français

Crystallographic characterization of fluorapatite glass-ceramics synthesized from industrial waste

Published online by Cambridge University Press:  05 September 2017

Chee W. Loy ,
Khamirul A. Matori ,
Norhazlin Zainuddin ,
Andrew E. Whitten ,
Christine Rehm ,
Liliana de Campo ,
Anna Sokolova  and
Siegbert Schmid
Chee W. Loy
Affiliation:
School of Chemistry, The University of Sydney, Sydney NSW 2006, Australia
Khamirul A. Matori
Affiliation:
Department of Physics, Universiti Putra Malaysia, UPM Serdang 43400, Malaysia
Norhazlin Zainuddin
Affiliation:
Department of Chemistry, Universiti Putra Malaysia, UPM Serdang 43400, Malaysia
Andrew E. Whitten
Affiliation:
Australian Centre for Neutron Scattering, Australian Nuclear Science and Technology Organisation, Lucas Heights, NSW 2234, Australia
Christine Rehm
Affiliation:
Australian Centre for Neutron Scattering, Australian Nuclear Science and Technology Organisation, Lucas Heights, NSW 2234, Australia
Liliana de Campo
Affiliation:
Australian Centre for Neutron Scattering, Australian Nuclear Science and Technology Organisation, Lucas Heights, NSW 2234, Australia
Anna Sokolova
Affiliation:
Australian Centre for Neutron Scattering, Australian Nuclear Science and Technology Organisation, Lucas Heights, NSW 2234, Australia
Siegbert Schmid*
Affiliation:
School of Chemistry, The University of Sydney, Sydney NSW 2006, Australia
*
a)Author to whom correspondence should be addressed. Electronic mail: siegbert.schmid@sydney.edu.au
Get access Rights & Permissions [Opens in a new window]

Abstract

A series of phase transformations of a novel fluoroaluminosilicate glass forming a range of fluorapatite glass-ceramics on sintering are reported. The sintering process induces formation of fluorapatite, mullite, and anorthite phases within the amorphous silicate matrices of the glass-ceramics. The fluoroaluminosilicate glass, SiO2–Al2O3–P2O5–CaO–CaF2, is prepared from waste materials, such as rice husk ash, pacific oyster shells, and disposable aluminium cans. The thermally induced crystallographic and microstructure evolution of the fluoroaluminosilicate glass towards the fluorapatite glass-ceramics, with applications in dental and bone restoration, are investigated by powder X-ray diffraction and small-angle neutron-scattering techniques.

Keywords

fluorapatitemulliteanorthitespinodal decompositionglass-ceramic
Type
Technical Articles
Information
Powder Diffraction , Volume 32 , Supplement S2 , December 2017 , pp. S61 - S65
Check for updates
Copyright
Copyright © International Centre for Diffraction Data 2017 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Arnold, O., Bilheux, J. C., Borreguero, J. M., Buts, A., Campbell, S. I., Chapon, L., Doucet, M., Draper, N., Ferraz Leal, R., Gigg, M. A., Lynch, V. E., Markvardsen, A., Mikkelson, D. J., Mikkelson, R. L., Miller, R., Palmen, K., Parker, P., Passos, G., Perring, T. G., Peterson, P. F., Ren, S., Reuter, M. A., Savici, A. T., Taylor, J. W., Taylor, R. J., Tolchenov, R., Zhou, W., and Zikovsky, J. (2014). “Mantid – data analysis and visualization package for neutron scattering and μSR experiments,” Nucl. Instrum. Methods Phys. Res. 764, 156–166.Google Scholar
Denry, I. and Holloway, J. A. (2014). “Low temperature sintering of fluorapatite glass-ceramics,” Dent. Mater. 30(2), 112–121.Google Scholar
Dessai, R. R., Desa, J. A. E., Sen, D., and Mazumder, S. (2013). “Effects of pressure and temperature on pore structure of ceramic synthesized from rice husk: a small angle neutron scattering investigation,” J. Alloys Compd. 564, 125–129.CrossRefGoogle Scholar
Dixon, T., Romanak, K., Neades, S., and Chadwick, A. (2013). “Getting science and technology into international climate policy: carbon dioxide capture and storage in the UNFCCC,” Energy Proc. 37, 7590–7595.CrossRefGoogle Scholar
Duminis, T., Shahid, S., and Hill, R. G. (2017). “Apatite glass-ceramics: a review,” Front. Mater. 3(59), 1–15.Google Scholar
Favvas, E. P. and Mitropoulos, A. Ch. (2008). “What is spinodal decomposition,” J. Eng. Sci. Technol. Rev. 1, 25–27.Google Scholar
Hill, R. and Calver, A. (2007). “Real-time nucleation and crystallization studies of fluorapatite glass-ceramics using small-angle neutron scattering and neutron diffraction,” J. Am. Ceram. Soc. 90(3), 763–768.Google Scholar
Nayak, J. P. and Bera, J. (2010). “Effect of sintering temperature on medical behavior and bioactivity of sol-gel synthesized bioglass-ceramics using rice husk ash as a silica source,” Appl. Surf. Sci. 257, 458–462.Google Scholar
O'Donnell, M. D., Karpukhina, N., Calver, A. I., Law, R. V., Bubb, N., Stamboulis, A., and Hill, R. G. (2010). “Real time neutron diffraction and solid state NMR of high strength apatite-mullite glass ceramic,” J. Non-Cryst. Solids 356, 2693–2698.CrossRefGoogle Scholar
Rafferty, A., Clifford, A., Hill, R., Wood, D., Samuneva, B., and Dimitrova-Lukacs, M. (2000). “Influence of fluorine content in apatite-mullite glass-ceramics,” J. Am. Ceram. Soc. 83(11), 2833–2838.Google Scholar
Sokolova, A., Christoforidis, J., Eltobaji, A., Barnes, J., Darmann, F., Whitten, A. E., and Campo, L.de. (2016). “BILBY: time-of-flight small angle scattering instrument,” Neutron News 27, 9–13.Google Scholar
Srinivasreddy, A. B., McCarthy, T. J., and Lume, E. (2013). “Effect of rice husk ash on workability and strength of concrete,” 26th Biennial Concrete Institute of Australia's National Concrete (Concrete 2013), 1–10.Google Scholar
Wolfe, L. A. and Boyde, A. (1992). “Biocompatibility test on a novel glass-ceramic system,” J. Appl. Biomater. 3, 217–224.Google Scholar