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Usaxs and X-Ray Microscopy Investigations on Silica and Precursors of Zeolites

Published online by Cambridge University Press:  25 February 2011

Theo P. M. Beelen ,
Wim H. Dokter ,
Harold F. van Garderen ,
Rutger A. van Santen ,
Mike T. Browne  and
Graeme R. Morrison
Theo P. M. Beelen
Affiliation:
Eindhoven University of Technology, P.O. Box 513, 5600 MB EINDHOVEN, The Netherlands
Wim H. Dokter
Affiliation:
Eindhoven University of Technology, P.O. Box 513, 5600 MB EINDHOVEN, The Netherlands
Harold F. van Garderen
Affiliation:
Eindhoven University of Technology, P.O. Box 513, 5600 MB EINDHOVEN, The Netherlands
Rutger A. van Santen
Affiliation:
Eindhoven University of Technology, P.O. Box 513, 5600 MB EINDHOVEN, The Netherlands
Mike T. Browne
Affiliation:
King's College, University of London, Strand, London WC2R 2LS, United Kingdom
Graeme R. Morrison
Affiliation:
King's College, University of London, Strand, London WC2R 2LS, United Kingdom
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Abstract

Combination of SAXS and USAXS measurements provide an extended q-range (0.006–3.0 nm-1) to study fractal growth of both aging silica gel as well as precursors of zeolite-A. Mass (silica) and surface (zeolite) fractals are observed. Scanning transmission X-ray microscopy (STXM) proves to be an extremely useful technique to obtain direct images of wet samples in the 0.1–100 micron range, confirming the SAXS/USAXS results on even larger length scales.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 271: Symposium N – Better Ceramics Through Chemistry V , 1992 , 263
Copyright
Copyright © Materials Research Society 1992

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References

REFERENCES

1. Iler, R. K., The Chemistry of Silica (J. Wiley & Sons, New York, 1979)Google Scholar
2. Beelen, T. P. M., Wijnen, P. W. J. G., Vonk, C. G. and van Santen, R. A., Cat. Letters 3, 209 (1989)Google Scholar
3. Wijnen, P. W. J. G., PhD thesis, Eindhoven University of Technology, 1990 Google Scholar
4. Martin, J. E. and Hurd, A. J., J. Appl. Cryst. 20, 61 (1987)CrossRefGoogle Scholar
5. Brinker, C. J. and Scherer, G. W., Sol-Gel Science (Academic Press, Boston, 1990)Google Scholar
6. Wijnen, P. W. J. G., Beelen, T. P. M., Rummens, C. P. J., Saeijs, H. C. P. L., de Haan, J. W., van de Ven, L. J. M. and van Santen, R. A., J. Coll. Interf. Sci. 145(1), 17 (1991)Google Scholar
7. Pope, E. J. A. and Mackenzie, J. D., J. Non-CrystSolids 87, 185 (1986)Google Scholar
8. Wijnen, P. W. J. G., Beelen, T. P. M., de Haan, J. W., van de Ven, L. J. M. and van Santen, R. A., Coll. & Surf. 45, 255 (1990)Google Scholar
9. Hendricks, W. M., Bell, A. T. and Radke, C. J., J. Phys. Chem 95, 9519 (1991)Google Scholar
10. van Bekkum, H., Flanigen, E. M. and Jansen, J. C., Introduction to Zeolite Science and Practice (Elsevier, Amsterdam, 1991)Google Scholar
11. Cabane, B., Dubois, M., Lefaucheux, F. and Robert, M. C., J. Non-cryst. Solids 119, 121 (1990)Google Scholar
12. Ramsay, J. D. F., Chem. Soc. Rev. 15, 335 (1986)Google Scholar
13. Teixeira, J., in On Growth and Form,, edited by Stanley, H. E. and Ostrowski, N. (M. Nijhoff, Dordrecht, 1986)Google Scholar
14. Wijnen, P. W. J. G., Beelen, T. P. M., Rummens, C. P. J., Saeijs, H. C. P. L. and van Santen, R. A., J. Appl. Cryst. 24, 759 (1991)Google Scholar
15. Schaefer, D. W., Martin, J. E., Wiltzius, P. and Cannel, D. S., Phys. Rev. Letters 52, 2371 (1984)Google Scholar
16. North, A. N., Dore, J. C., Mackie, A. R., Howe, A. M. and Harries, J., Nucl. Instr. Meth. Phys. Res. B47, 283 (1990)Google Scholar
17. Diakun, G. P. and Harries, J. E. in Synchrotron Radiation in Biophysics, edited by Hasnain, S. S. (Ellis Harwood Limited, 1990) p. 243 Google Scholar
18. Bellare, J., Bailey, J. K. and Mecartney, M. L., in Ultrastructure Processing of Advanced Ceramics, edited by Mackenzie, J. and Ulrich, D. (J. Wiley & Sons, New York, 1988), p. 835 Google Scholar
19. Morrison, G. R., Beswetherick, J. T., Browne, M. T., Burge, R. E., Cave, R. C., Charalambous, P. S., Duke, P. J., Foster, G. F., Hare, A. R., Michette, A. G., Morris, D., Potts, A. W. and Taguchi, T., in X-Ray Microscopy in Biology and Medicine, edited by Shinohara, K. et al. (Japan Sci. Soc. Press, Tokyo, 1990) p. 99–108 Google Scholar
20. Morrison, G. R. and Burge, R. E. in Synchrotron Radiation in Biophysics, edited by Hasnain, S. S. (Ellis Harwood Limited, 1990) p. 330 Google Scholar
21. Morrison, G. R., Bridgewater, S., Browne, M. T., Burge, R. E., Cave, R. C., Charalambous, P. S., Foster, G. F., Hare, A. R., Michette, A. G., Morris, D. and Taguchi, T., Rev. Sci. Instrum. 60(7), 2464 (1989)Google Scholar
22. Vonk, C. G., J. Appl. Cryst. 9, 433 (1976)Google Scholar
23. Cotton, J. P. in Neutron. X-ray and Light Scattering, edited by Linder, P. and Zemb, Th. (North Holland, Amsterdam, 1991) p. 24 Google Scholar
24. Feigin, L. A. and Svergun, D. I., Structure Analysis by Small-Angle X-Ray and Neutron Scattering (Plenum Press, New York, 1987)Google Scholar
25. Juliien, R. and Botet, R., Aggregation and Fractal Aggregates (World Scientific, Singapore, 1987)Google Scholar
26. Mandelbrot, B., in Les Objects Fractals (Flammarion, Paris, 1975)Google Scholar
27. Tuel, A., Dantry, P., Hommel, H., Legrand, A. P. and Morawski, J. C., Progr. Coll. Polym. Sci. 76, 32 (1988)Google Scholar
28. Tence, M., Chevalier, J. P. and Julien, R., J. Phys. 47, 1989 (1986)Google Scholar