Hostname: page-component-84b7d79bbc-g78kv Total loading time: 0 Render date: 2024-07-30T15:32:08.006Z Has data issue: false hasContentIssue false

Temperature Dependence of Ar Sputtering of CoSi2 Thin Films on Si and SiO2

Published online by Cambridge University Press:  28 February 2011

Q. Z. Hong
Affiliation:
IBM Thomas J. Watson Research Center, Yorktown Heights, NY 10598
J. M. E. Harper
Affiliation:
IBM Thomas J. Watson Research Center, Yorktown Heights, NY 10598
Get access

Abstract

The temperature dependence of 300 eV argon ion sputtering of CoSi2 thin films in the range 50–600°C has been investigated. At temperatures above 400°C, the etch rate of CoSi2 on Si is significantly reduced, while the underlying Si reacts with the Co atoms diffusing from the silicide surface. As a result, the silicide layer effectively moves into the substrate during Ar bombardment. During sputtering of CoSi2 on Sio2, the thickness of the silicide layer decreases almost linearly with bombarding time until all the silicide is removed. Similar behavior is observed in low temperature sputtering of CoSi2 on (100) Si and evaporated Si. However, at elevated temperatures (400°C< <600°C), sputtering of CoSi2 on Si undergoes two consecutive stages. During the initial stage, the thickness of the silicide layer decreases at the same rate as that of the silicide on SiO2, and is accompanied by an enrichment in Co concentration near the surface. During the second stage, the etch rate of the silicide is reduced to only one third of the rate during the initial stage.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Wiedersich, H., in Surface Modification and Alloying by Laser, Ion, Electron Beams, edited by Poate, J. M., Foti, G. and Jacobson, D., (Plenum, New York, 1983) p. 261.Google Scholar
2. Fernandez, R., Shreter, U. and Nicolet, M. -A., Nucl. Instrum. Methods 209/210, 513, (1983).Google Scholar
3. Murarka, S. P., J. Vac. Sci. Technol. 17, 775 (1980).Google Scholar
4. Doolittle, L. R., Nucl. Instrum. Methods B 9, 344 (1985).Google Scholar
5. Harper, J. M. E., Motakef, S., and Moy, D., to be published in Appl. Phys. Lett.Google Scholar
6. Cahoon, E. C., Comrie, C. M., and Pretorius, R., Mat. Res. Soc. Symp. Proc. 25 57, (1984).Google Scholar