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Synthesis and characterization of periodic porous benzene-silica hybrid powders with cubic and hexagonal symmetries

Published online by Cambridge University Press:  01 February 2011

Valérie Goletto ,
Anne-Claire Bled ,
Gregor Trimmel ,
Michel Wong Chi Man ,
Hee-Gweon Woo ,
Dominique Durand  and
Florence Babonneau
Valérie Goletto
Affiliation:
Chimie de la Matière Condensée, UPMC/CNRS, Paris, France. fb@ccr.jussieu.fr
Anne-Claire Bled
Affiliation:
Chimie de la Matière Condensée, UPMC/CNRS, Paris, France. fb@ccr.jussieu.fr
Gregor Trimmel
Affiliation:
Chimie de la Matière Condensée, UPMC/CNRS, Paris, France. fb@ccr.jussieu.fr
Michel Wong Chi Man
Affiliation:
Département de Chimie Organique Fine, Université de Montpellier II, France.
Hee-Gweon Woo
Affiliation:
Dept. of Chemistry, Chonnam National University, Kwangju, Korea
Dominique Durand
Affiliation:
LURE, Université Paris-Sud, Orsay, France
Florence Babonneau
Affiliation:
Chimie de la Matière Condensée, UPMC/CNRS, Paris, France. fb@ccr.jussieu.fr
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Abstract

Organosilica powders with uniformly distributed bridging benzene groups have been synthesized from the condensation of bis- or tris-(triethoxysilyl)benzene in the presence of cetyltrimethylammoniumbromide. The syntheses were performed under strong acidic conditions and the organic groups were always incorporated without cleavage of the Si-C bonds as indicated by solid state MAS NMR studies. Depending on the nature of the precursors, materials with different ordering were obtained: a 2D-hexagonal (p6m) phase was formed from the 1,3-bis(triethoxysilyl)benzene, whereas the 1,4-bis(triethoxysilyl)benzene lead to a cubic Pm3n phase. The surfactant was removed either by solvent extraction or by controlled calcination, which did not affect the mesostructure of the materials.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 726: Symposium Q – Hybrid Organic-Inorganic Materials , 2002 , Q6.14
Copyright
Copyright © Materials Research Society 2002

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