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Structure-Property Relationships in the Toughening of Poly(Methyl Methacrylate) by Sub-Micron Size, Multiple-Layer Particles

Published online by Cambridge University Press:  15 February 2011

A. C. Archer
Affiliation:
Polymer Science and Technology Group, Manchester Materials Science Centre, UMIST, Grosvenor St., Manchester, M1 7HS, United Kingdom
P. A. Lovell
Affiliation:
Polymer Science and Technology Group, Manchester Materials Science Centre, UMIST, Grosvenor St., Manchester, M1 7HS, United Kingdom
J. McDonald
Affiliation:
Polymer Science and Technology Group, Manchester Materials Science Centre, UMIST, Grosvenor St., Manchester, M1 7HS, United Kingdom
M. N. Sherratt
Affiliation:
Polymer Science and Technology Group, Manchester Materials Science Centre, UMIST, Grosvenor St., Manchester, M1 7HS, United Kingdom
R. J. Young
Affiliation:
Polymer Science and Technology Group, Manchester Materials Science Centre, UMIST, Grosvenor St., Manchester, M1 7HS, United Kingdom
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Abstract

Rubber-toughened poly(methyl methacrylate) materials have been prepared by blending poly(methyl methacrylate) with specially-synthesised, refractive index matched particles containing two, three and four radially-alternating rubbery and glassy layers. The paper describes the effects upon mechanical properties of (i) two-, three- and four-layer particle structure and (ii) particle diameter and glassy core size for three-layer particles.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

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References

REFERENCES

1. (a) Rohm and Haas Company, Brit. Patent No. 1 340 025 (1973); (b) Rohm and Haas Company, Brit. Patent No. 1 414 187 (1975); (c) E.I. Du Pont de Nemours and Company, Gt. Brit. Patent Appl. No.2 039 496A (1979)Google Scholar
2. (a) Lovell, P.A., McDonald, J., Saunders, D.E.J., Sherratt, M.N. and Young, R.J., Advances in Chemistry Series 233, American Chemical Society, Washington, in press; (b) P.A. Lovell, J. McDonald, D.E.J. Saunders and R.J. Young, submitted to PolymerGoogle Scholar
3. Williams, J.G., EGF Fracture Testing Protocol, March 1990 Google Scholar
4. Lovell, P.A., McDonald, J., Saunders, D.E.J., Sherratt, M.N. and Young, R.J., Plast. Rubb. Comp. Proc. Appl. 16, 37 (1991)Google Scholar
5. Sue, H-J. and Yee, A.F., J. Mat. Sci., 24, 1447 (1989)CrossRefGoogle Scholar
6. Heatley, F., Lovell, P.A. and McDonald, J., submitted to Eur. Polym. J.Google Scholar