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Spectroscopy Analysis of the Ring Opening Reaction in Functionalized Spiropyran Films

Published online by Cambridge University Press:  01 February 2011

Raúl J. Delgado-Macuil
Affiliation:
Centro de Investigación en Biotecnología Aplicada del IPN. Tepetitla Tlaxcala. 90700., México.
Marlon Rojas-López
Affiliation:
Centro de Investigación en Biotecnología Aplicada del IPN. Tepetitla Tlaxcala. 90700., México.
Valentín L. Gayou
Affiliation:
Centro de Investigación en Biotecnología Aplicada del IPN. Tepetitla Tlaxcala. 90700., México.
Abdu Orduña-Díaz
Affiliation:
Centro de Investigación en Biotecnología Aplicada del IPN. Tepetitla Tlaxcala. 90700., México.
Joel Díaz-Reyes
Affiliation:
Centro de Investigación en Biotecnología Aplicada del IPN. Tepetitla Tlaxcala. 90700., México.
Virginia Camacho-Pernas
Affiliation:
Universidad Politécnica de Puebla, Carrera de Electrónica y Telecomunicaciones. Puebla, Pue.México. Author contact: rdelgadom@ipn.mx
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Abstract

In this work we used the Fourier Transform Infrared spectroscopy and UV/Vis spectroscopy to analyze the behaviour of self-ensemble films of spiropyran when the films were irradiated by UV. In UV/Vis spectroscopy is possible observe the generation of the absorption peak, at 575 nm, associated to the merocyanine state when the ring-opening process is induced by UV light. In ATR the kinetics of the ring-opening was determinate too; following the spectra changes in real time.

Type
Research Article
Copyright
Copyright © Materials Research Society 2010

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References

REFERENCES

1. Ulman, A., Introduction to thin organic films: From Langmuir-Blodgett to Self-Assembly, Academic press: Boston, 1991.Google Scholar
2. Rowe, G.K. and Creager, S.E., Langmuir 7, 2307 (1991)Google Scholar
3. Hockett, L.A. and Creager, S.E., Langmuir 11, 2318 (1995).Google Scholar
4. Steinberg, S., Tor, Y., Sabatini, E., Rubinstein, I., J. Am. Chem. Soc. 113, 5176 (1991).Google Scholar
5. Evans, D., Wampler, R.J., Phys. Chem. B. 103, 4666 (1999).Google Scholar
6. Rojas, M.T., Kaifer, A.E., J. Am. Chem. Soc. 117, 5883 (1995).Google Scholar
7. Ramos-Garcia, R., Delgado-Macuil, R., Iturbe-Castillo, D., de los Santos, E. Gonzalez, Soriano-Corral, F., Opt. Quantum Electr. 35, 641 (2003).Google Scholar
8. Crano, J. and Guglielmetti, R. Organic Photochromic and Thermochromic Compunds Vol 2 Kluwer Academic Chapters 1–2 New York 1999.Google Scholar
9. Feldheim, D.L., Keating, C.D., Chem. Soc. Rev. 27, 1 (1998).Google Scholar
10. Walter, D.G., Campbell, D. J., Mirkin, C.A., J. Phys Chem. B. 103, 402 (1999).Google Scholar
11. Fisher, E. and Hirshberg, Y., J. Chem. Soc. 4522 (1952).Google Scholar
12. Bobrovsky, A., Boiko, N., Shibaev, V., Adv. Mat. 11, 1025 (1999).Google Scholar
13. Delgado-Macuil, R., Rojas-Lopez, M., Gayou, V.L., Orduña-Díaz, A., Diaz-Reyes, J., Mat. Characterization 58, 771 (2007).Google Scholar
14. Hoon, L., Jaung, Y., Jeong, S., Bull. Korean Chem. Soc. 23, 1045 (2002).Google Scholar
15. Takayanagi, M., Nakata, M., Ozaki, Y., Iriyama, K., Tasumi, M., J. Mol. Struct. 407, 239 (1997).Google Scholar
16. Chibisov, A. and Gorner, H., J. Phys. Chem. A 101, 4305 (1997).Google Scholar
17. Khimenko, V., Chibisov, A., Gorner, H., J. Phys. Chem. A 101, 7304 (1997).Google Scholar
18. Wojtyk, J., Wasey, A., Kazmaier, P., Hoz, S., Buncel, E., J. Phys. Chem. A 104, 9046 (2000).Google Scholar
19. Schiele, C. and Arnold, G., Tetrahedron Lett. 13, 1191 (1967).Google Scholar
20. Guiliano, M., Davin-Pretelli, E., Mille, G., Chouteau, J., Guglielmetti, R., Helv. Chim. Act. 61, 1072 (1978).Google Scholar