Hostname: page-component-848d4c4894-pjpqr Total loading time: 0 Render date: 2024-06-26T08:17:11.754Z Has data issue: false hasContentIssue false

Single-Walled Carbon Nanotube Composites as Hole Injection Layer for Organic Light Emitting Diode Applications

Published online by Cambridge University Press:  01 February 2011

C. C. Oey
Affiliation:
Dept. of Electrical and Electronic Engineering, The University of Hong Kong, Pokfulam Road, Hong Kong
A. B. Djuršić
Affiliation:
Department of Physics, The University of Hong Kong, Pokfulam Road, Hong Kong
C. Y. Kwong
Affiliation:
Dept. of Electrical and Electronic Engineering, The University of Hong Kong, Pokfulam Road, Hong Kong
C. H. Cheung
Affiliation:
Department of Physics, The University of Hong Kong, Pokfulam Road, Hong Kong
W. K. Chan
Affiliation:
Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong
P. C. Chui
Affiliation:
Dept. of Electrical and Electronic Engineering, The University of Hong Kong, Pokfulam Road, Hong Kong
Get access

Abstract

In this work, blends of dispersed short (∼500 nm) single-walled carbon nanotubes (SWCNTs) with poly(3,4-ethylene dioxythiophene):polystyrene sulfonic acid (PEDOT:PSS) were investigated as hole injection layers in OLEDs consisting of N,N′-di(naphthalene-1-yl)-N,N′-diphenylbenzidine (NPB) as a hole transporting and tris-(8-hydroxyquinoline) aluminum (Alq3) as electron transporting and emitting layer. The devices were characterized by electroluminescence and current-voltage measurements. By comparing the performance of devices fabricated using different surfactants (polyethyleneimine (PEI) and Gum Arabic (GA)) in dispersing SWCNTs and those prepared without surfactants, it was found that the use of appropriate surfactants can improve the OLEDs performance. Improved efficiency was obtained for optimized SWCNTs concentration compared to the devices with pure PEDOT:PSS, although maximum luminance is lower. The PEDOT:PSS:SWCNT nanocomposite layers are characterized and the reasons for the improved OLED performance are discussed.

Type
Research Article
Copyright
Copyright © Materials Research Society 2005

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Hung, L.S., Chen, C.H., Materials Science & Engineering R-Reports R39 (2002) 143.Google Scholar
2 Iijima, S., Ichihashi, T., Nature 363 (1993) 603.Google Scholar
3 Guo, T., Nikolaev, P., Thess, A., Colbert, D.T., Smalley, R.E., Chem. Phys. Lett. 243 (1995) 49.Google Scholar
4 Tohji, K., Goto, T., Takahashi, H., Shinoda, Y., Shimizu, N., Jeyadevan, B., Matsuoka, I., Saito, Y., Kasuya, A., Ohsuna, T., Hiraga, K., Ninshina, Y. Nature 383 (1996) 679.Google Scholar
5 Shim, M., Javey, A., Wong, N., Dai, H., J. Am. Chem. Soc. 123 (2001) 11512.Google Scholar
6 Bandyopadhyaya, R., Nativ-Roth, E., Regev, O., Yerushalmi-Rozen, R., Nano Letters 2 (2002) 25.Google Scholar
7 Vigolo, B., Pénicaud, A., Coulon, C., Sauder, C., Pailler, R., Journet, C., Bernier, P., Poulin, P., Science 290 (2000) 1331.Google Scholar
8 Kwon, Y.K., Saito, S., Tomanek, D., Phys. Rev. B 58 (1998) R13314.Google Scholar
9 Carter, S.A., Scott, J.C., Brock, P.J., Appl. Phys. Lett. 71 (1997) 1145.Google Scholar
10 Zhang, Z.F., Deng, Z.B., Liang, C.J., Zhang, M.X., Xu, D.H., Displays 24 (2003) 231.Google Scholar
11 Woo, H. S., Czerw, R., Webster, S., Carroll, D. L., Appl. Phys. Lett. 77 (2000) 1393.Google Scholar