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Raman Measurements on Graphite Modified by High Power Laser Irradiation1

Published online by Cambridge University Press:  25 February 2011

J. Steinbeck ,
G. Braunstein ,
M.S. Dresselhaus ,
B.S. Elman  and
T. Venkatesan
J. Steinbeck
Affiliation:
Massachusetts Institute of Technology, Cambridge, MA
G. Braunstein
Affiliation:
Massachusetts Institute of Technology, Cambridge, MA
M.S. Dresselhaus
Affiliation:
Massachusetts Institute of Technology, Cambridge, MA
B.S. Elman
Affiliation:
GTE Research Laboratory, Waltham, MA
T. Venkatesan
Affiliation:
Bell Communications Research, Murray Hill, MA
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Abstract

The behavior of highly anisotropic materials under short pulses of high power laser irradiation has been studied by irradiating highly oriented pyrolytic graphite (HOPG) with 30 nsec Ruby-laser pulses with energy densities between 0.1 and 5.0J/cm2. Raman spectroscopy has been used to investigate the laser-induced modifications to the crystalline structure as a function of laser energy density of the laser pulse. A Raman microprobe was used to investigate the spatial variations of these near-surface regions. The irradiation of HOPG with energy densities above ~ 0.6J/cm2 leads to the appearance of the ~ 1360 cm-1 disorder-induced line in the first order Raman spectrum. The intensity of the ~ 1360cm-1 line increases with increasing laser energy density. As the energy density of the laser pulse reaches about 1.0J/cm2, the ~ 1360cm-1 line and the ~ 1580cm-1 Raman-allowed mode broaden and coalesce into a broad asymmetric band, indicating the formation of a highly disordered region, consistent with RBS-channeling measurements. However, as the laser energy density of the laser pulses is further increased above 3.0J/cm2, the two Raman lines narrow and can again be resolved suggesting laser-induced crystallization. The Raman results are consistent with high resolution electron microscopy observations showing the formation of randomly oriented crystallites. Raman Microprobe spectra revealed three separate regions of behavior: (i) an outer unirradiated region where the material appears HOPG-like with a thin layer of material coating the surface, (ii) an inner irradiated region where the structure is uniform, but disordered, and (iii) an intermediate region between the other regions where the structure is highly disordered. The changes in structure of the inner region are consistent with the behavior observed with RBS and conventional Raman spectra. The identification of an amorphous carbon-like layer on the outer region is consistent with a large thermomechanical stress at the graphite surface, introduced by the high power laser pulse, and known to occur in metals.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 35: Symposium A – Energy Beam-Solid Interactions and Transient Thermal Processing/1984 , 1984 , 219
Copyright
Copyright © Materials Research Society 1985

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Footnotes

1

The MIT authors acknowledge NSF Grant #DMR 83-10482 for the support of their portion of the work.

References

REFERENCES

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