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Preparation of Vitrified TEM Samples for the Direct Observation of Sol and Gel Structures

Published online by Cambridge University Press:  21 February 2011

Joseph K. Bailey ,
Jayesh R. Bellare  and
Martha L. Mecartney
Joseph K. Bailey
Affiliation:
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455.
Jayesh R. Bellare
Affiliation:
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455.
Martha L. Mecartney
Affiliation:
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455.
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Abstract

Direct observation of structure in liquid phase materials is made possible by a cryo-vitrification technique in which a thin liquid sample is frozen at a high cooling rate to prevent crystallization. We have applied this technique to observe the evolution of structure in ceramic sols and gels using TEM. The sample preparation technique is described in detail and results obtained from colloidal and polymeric sols and gels are presented to show the usefulness of the technique. Artifacts arising from radiation damage and beam heating are also discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 115: Symposium W – Specimen Preparation for Transmission Electron Microscopy of Materials I , 1987 , 69
Copyright
Copyright © Materials Research Society 1988

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References

REFERENCES

1. Adrian, M., Dubochet, J., Lepault, J., and McDowall, A. W., Nature 308, 32 (1984).CrossRefGoogle Scholar
2. Bellare, J. R., Davis, H. T., Scriven, L. E., and Talmon, Y., in Proceedings of the Xith International Congress on Electron Microscopy, edited by Imura, T., Maruse, S., and Suzuki, T. (The Japanese Society of Electron Microscopy, Tokyo, 1986), pp. 367–370.Google Scholar
3. Talmon, Y., Colloids and Surfaces, 12, 237 (1987).Google Scholar
4. Dale Schaefer, W. and Keefer, K. D., in Better Ceramics Through Chemistry, edited by Brinker, C. J., Clark, D. E., and Ulrich, D. R. (Mater. Res. Soc. Proc. 32, Pittsburgh, PA 1984), pp. 1–14.Google Scholar
5. Craievich, A., Aegerter, M. A., Santos, D. I. dos, Woignier, T., and Zarzycki, J., J. Non-Crystalline Solids, 86, 394–406 (1986).CrossRefGoogle Scholar
6. Visca, M. and Matijevic, E., J. Colloid Interface Sci., 68 (2), 260–270 (1979).Google Scholar
7. Stewart, R. F. and Sutton, D., in Better Ceramics Through Chemistry II, edited by Brinker, C. J., Clark, D. E., and Ulrich, D. R. (Mater. Res. Soc. Proc. 73, Pittsburgh, PA 1986) pp. 281–286.Google Scholar
8. Bellare, J., Bailey, J. K., and Mecartney, M. L., in Ultrastructure Processing of Advanced Ceramics, edited by Mackenzie, J. D. (John Wiley and Sons, New York, 1987).Google Scholar
9. Bellare, J., Bailey, J. K., and Mecartney, M. L., in Proceedings of the 45th Annual Meeting oftheklcrn Microscopy Society of America, edited by Bailey, G. W. (San Francisco Press, San Francisco, 1987), pp. 356–357.Google Scholar
10. Vinson, P., in Proceedings of the 45th Annual Meeting oftheklcrn Microscopy Society of America, edited by Bailey, G. W. (San Francisco Press, San Francisco, 1987), pp. 644–645.Google Scholar
11. Bellare, J., in Proceedings of the 44th Annual Meeting of the Electron Microscopy Society of America, edited by Bailey, G. W. (San Francisco Press, San Francisco, 1986), pp. 236–237.CrossRefGoogle Scholar
12. Brinker, C. J., Keefer, K. D., Schaefer, D. W., and Ashley, C. S., J. Non-Crystalline Solids 48, 47–64 (1982).Google Scholar
13. Bellare, J., Sheehan, J., Davis, H. T., and Scriven, L. E., These proceedings.Google Scholar