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Photoluminescence Characterization of Hydrogenated Nanocrystalline/Amorphous Silicon

Published online by Cambridge University Press:  31 January 2011

Jeremy D Fields
Affiliation:
jefields@mines.edujerfields@gmail.com, Colorado School of Mines, Materials Science, CSM/GRL 231, 1310 Maple St., Golden, Colorado, 80401, United States, 303-384-2106
Craig Taylor
Affiliation:
pctaylor@mines.edu, Colorado School of Mines, Physics, 80401, Colorado, United States
Juliuz George Radziszewski
Affiliation:
chemid@earthlink.net, Colorado School of Mines, Golden, Colorado, United States
David Baker
Affiliation:
dabaker79@gmail.com, Colorado School of Mines, Physics, 80401, Colorado, United States
Guozhen Yue
Affiliation:
gyue@uni-solar.com, United Solar Ovonic LLC, Troy, Michigan, United States
Baojie Yan
Affiliation:
byan@uni-solar.com, United Solar Ovonic LLC, R&D, Troy, Michigan, United States
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Abstract

The photoluminescence in a nc-Si/a-Si:H mixture has been investigated at varying excitation intensities, and temperatures We have also observed changes in the luminescence spectra, which are induced by sequential annealing at temperatures below the a-Si:H crystallization temperature (˜ 600°C). Two predominant luminescence peaks are observed at ˜ 0.95 eV and ˜ 1.30 eV, which are attributed to band tail-to-band tail transitions near the nc-Si grain boundaries and in the a-Si:H bulk, respectively. The 0.95 eV band saturates approaching 500 mW/cm2 excitation intensity. Annealing the nc-Si/a-Si:H mixture brings out a new low energy peak, centered at ˜ 0.70 eV, and which we believe to be due to oxygen defects.

Type
Research Article
Copyright
Copyright © Materials Research Society 2009

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