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Phonons and Free Carriers in a Strained Hexagonal GaN-AlN Superlattice Measured by Infrared Ellipsometry and Raman Spectroscopy

Published online by Cambridge University Press:  03 September 2012

M. Schubert
Affiliation:
Center for Microelectronic and Optical Materials Research, University of Nebraska, Lincoln, NE 68588-0511, U.S.A Abteilung Halbleiterphysik, Institut fur Experimentelle Physik II, Universitat Leipzig, Vor dem Hospitaltor 1, D-04103 Leipzig, Germany
A. Kasic
Affiliation:
Abteilung Halbleiterphysik, Institut fur Experimentelle Physik II, Universitat Leipzig, Vor dem Hospitaltor 1, D-04103 Leipzig, Germany
T.E. Tiwald
Affiliation:
Center for Microelectronic and Optical Materials Research, University of Nebraska, Lincoln, NE 68588-0511, U.S.A
J.A. Woollam
Affiliation:
Center for Microelectronic and Optical Materials Research, University of Nebraska, Lincoln, NE 68588-0511, U.S.A
V. Harle
Affiliation:
4. Physikalisches Institut, Universitat Stuttgart, Pfaffenwaldring 57, D-70569 Stuttgart, Germany now with Osram Opto Semiconductors, Wernerwerkstr., D-93049 Regensburg, Germany
F. Scholz
Affiliation:
4. Physikalisches Institut, Universitat Stuttgart, Pfaffenwaldring 57, D-70569 Stuttgart, Germany
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Abstract

Phonon and free-carrier effects in a strained hexagonal (α) {GaN}l-{AlN}m superlattice (SL) heterostructure (l = 8 nm, m = 3 nm) are studied by infrared spectroscopic ellipsometry (IRSE) and micro (µ)-Raman scattering. Growth of the heterostructures was performed by metal-organic vapor phase epitaxy (MOVPE) on (0001) sapphire. An unstrained 1 µm-thick α-GaN layer was deposited prior to the SL. SL phonon modes are identified combining results from both IRSE and µ-Raman techniques. The shift of the GaN-sublayer phonon modes is used to estimate an average compressive SL stress of σxx ∼ - 4.3 GPa. The IRSE data reveal a free-carrier concentration of ne ∼ 5×1018 cm−3 within the undoped SL GaN-sublayers. According to the vertical carrier confinement, the free-carrier mobility is anisotropic, and the lateral mobility ( µ ∼ 400 cm2/Vs, polarization E⊥c-axis) exceeds the vertical mobility (µ ∼ 24 cm2/Vs, E∥c) by one order of magnitude.

Type
Research Article
Copyright
Copyright © Materials Research Society 1999

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