Hostname: page-component-848d4c4894-tn8tq Total loading time: 0 Render date: 2024-06-28T21:52:20.156Z Has data issue: false hasContentIssue false

Passivation of Gaas by Novel P2S5/(NH4)2Sx Sulfurization Techniques

Published online by Cambridge University Press:  25 February 2011

J. T. Hsieh
Affiliation:
Department of Electrical Engineering National Tsing Hua University, Hsin-chu, Taiwan, R.O.C.
C. Y. Sun
Affiliation:
Departmment of Electronic Engineering, National Taiwan Institute of Technology, Taipei, Taiwan, R.O.C.
H. L. Hwang
Affiliation:
Department of Electrical Engineering National Tsing Hua University, Hsin-chu, Taiwan, R.O.C.
Get access

Abstract

A new surface passivation technique using P2S5/(NH4)2S on GaAs was investigated, and the results are compared with those of the (NH4)2Sx treatment. With this new surface treatment, the effective barrier heights for both Al- and Au—GaAs Schottky diodes were found to vary with the metal work functions, which is a clear evidence of the lower surface state density. Results of I—V measurements show that P2S5/(NH4)2S—passivated diodes have lower reverse leakage current and higher effective barrier height than those of the (NH4)2Sx -treated ones. Auger Electron Spectroscopy, X—ray photoelectron spectroscopy and Raman scattering measurements were done to characterize the surfaces including their compositions and surface band bending. In this paper, interpretations on this novel passivation effect is also provided.

Type
Research Article
Copyright
Copyright © Materials Research Society 1993

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] Pande, K.P. and Gutierrez, D., Appl. Phys. Lett. 46, 416 (1985).Google Scholar
[2] Hsieh, J. T., Sun, C. Y. and Hwang, H. L., J. Appl. Phys. (submitted).Google Scholar
[3] Spindt, C. T., Besser, R. S., Cao, R., Miyano, K., Helms, C. R., and Spicer, W. E., Appl. Phys. Lett. 54, 1148 (1989).Google Scholar
[4] Sugahara, H. and Oshima, M., J. Appl. Phys. 69, 4349 (1991).Google Scholar
[5] Schwartz, G. P. and Gualtieri, G. J., J. Elect.rochem. Soc. 133, 1266 (1986).Google Scholar