Hostname: page-component-7479d7b7d-k7p5g Total loading time: 0 Render date: 2024-07-08T11:55:38.286Z Has data issue: false hasContentIssue false
  • English
  • Français

A Numerical Model for the Corrosion of Copper Nuclear Fuel Waste Containers

Published online by Cambridge University Press:  15 February 2011

F. King  and
M. Kolář
F. King
Affiliation:
Atomic Energy of Canada Limited, Whiteshell Laboratories, Pinawa, Manitoba, Canada R0E 1L0.
M. Kolář
Affiliation:
Atomic Energy of Canada Limited, Whiteshell Laboratories, Pinawa, Manitoba, Canada R0E 1L0.
Get access

Abstract

A model is presented for the prediction of the long-term corrosion behaviour of Cu nuclear fuel waste containers. The model is based on a kinetic description of the processes involved in the uniform corrosion of Cu in a conceptual Canadian disposal vault. The 1-dimensional, multilayer model accounts for mass-transport, electrochemical and chemical processes and predicts the spatial and temporal variations of the concentrations of various dissolved, precipitated and adsorbed species, as well as the time dependence of the corrosion rate and the corrosion potential (ECORR). The variation of [O2], [Cu(II)] and ECORR with time can also be used to predict the maximum period over which localized corrosion processes, such as pitting or stress corrosion, may occur. Predictions from the model suggest that 25-mm-thick Cu containers will not fail due to uniform corrosion or pitting in periods <106 a.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 412: Symposium V – Scientific Basis for Nuclear Waste Management XIX , 1995 , 555
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Shoesmith, D.W., Ikeda, B.M. and King, F. in Modelling Aqueous Corrosion, Trethewey, K.R. and Roberge, P.R. (eds.), NATO ASI Series (Kluwer, Boston, 1994), p. 201.Google Scholar
2. Werme, L., Sellin, P. and Kjellbert, N., Swedish Nuclear Fuel and Waste Management Company Technical Report, TR 92-26 (1992).Google Scholar
3. Kolář, M. and King, F. in Scientific Basis for Nuclear Waste Management XIX, Murphy, W.M. and Knecht, D. eds. (Mater. Res. Soc. Proc. 412 Pittsburgh, PA, 1996).Google Scholar
4. King, F. and Litke, C.D., AECL Report, AECL-9571 (1989).Google Scholar
5. King, F., Litke, C.D., Tang, Y. and Greidanus, G., unpublished data.Google Scholar
6. King, F., Litke, C.D. and Tang, Y., J. Electroanal. Chem. 384, 105–113 (1995).Google Scholar
7. King, F., Quinn, M.J. and Litke, C.D., J. Electroanal. Chem. 385, 45–55 (1995).Google Scholar
8. King, F., Litke, C.D., Quinn, M.J. and LeNeveu, D.M., Corros. Sci. 37, 833–851 (1995).Google Scholar
9. King, F. and Litke, C.D. in Scientific Basis for Nuclear Waste Management XII, Lutze, W. and Ewing, R.C. eds. (Mater. Res. Soc. Proc., 127, Pittsburgh, PA, 1989) pp. 403–409.Google Scholar
10. King, F., Litke, C.D. and Ryan, S.R., Corros. Sci. 33, 1979–1995 (1992)Google Scholar
11. Litke, C.D., Ryan, S.R. and King, F., AECL Report, AECL-10397 (1992).Google Scholar
12. King, F., Tang, Y., Quinn, M.J. and Litke, C.D. in CORROSION/95, NACE International, Houston, TX, paper #424 (1995).Google Scholar
13. King, F. and Ryan, S.R., unpublished data.Google Scholar
14. Ryan, S.R. and King, F., AECL Report, AECL- 11062, COG-I-94–125 (1994).Google Scholar
15. King, F., Appl. Geochem. 10, 477–487 (1995).Google Scholar
16. King, F. and LeNeveu, D.M. in FOCUS '91, American Nuclear Society, La Grange Park, IL, pps. 253–261(1992).Google Scholar
17. Shoesmith, D.W., King, F. and Ikeda, B.M. in Scientific Basis for Nuclear Waste Management XIX, Murphy, W.M. and Knecht, D. eds. (Mater. Res. Soc. Proc. 412 Pittsburgh, PA, 1996).Google Scholar
18. King, F., AECL Report, AECL- 11472, COG-95–520 (1995).Google Scholar
19. Oscarson, D.W., Hume, H.B. and King, F., Clays Clay Minerals 42, 731–736 (1994).Google Scholar
20. Kolář, M. and King, F., AECL Report, AECL- 11473, COG-95–521 (1995).Google Scholar
21. Gascoyne, M., AECL Technical Record, TR-714, COG-95–487 (1995).Google Scholar
22. Malmström, M., Banwart, S., Duro, L., Wersin, P. and Bruno, J., Swedish Nuclear Fuel and Waste Management Company Technical Report, TR 95-01 (1995).Google Scholar
23. Hallberg, R.O., Ostlund, P. and Wadsten, T., Appl. Geochem. 3, 273–280 (1988).Google Scholar
24. King, F. and Kolář, M. in CORROSION/95, NACE International, Houston, TX, paper #425 (1995).Google Scholar
25. King, F., LeNeveu, D.M. and Jobe, D.J. in Scientific Basis for Nuclear Waste Management XVII, Barkatt, A. and Konynenburg, R.A. Van eds. (Mater. Res. Soc. Proc. 333, Pittsburgh, PA, 1994) pp. 901–908.Google Scholar
26. Benjamin, L.A., Hardie, D. and Parkins, R.N., Br. Corros. J. 23, 89–95 (1988).Google Scholar
27. Lucey, V.F., Br. Corros. J. 2 175–185 (1967).Google Scholar