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Lithium Insertion Compounds

Published online by Cambridge University Press:  21 February 2011

J.B. Goodenough ,
A. Manthiram ,
A.C.W.P. James  and
P. Strobel
J.B. Goodenough
Affiliation:
Center for Materials Science & Engineering, ETC 5.160University of Texas at Austin, Austin, TX 78712-1084
A. Manthiram
Affiliation:
Center for Materials Science & Engineering, ETC 5.160University of Texas at Austin, Austin, TX 78712-1084
A.C.W.P. James
Affiliation:
Center for Materials Science & Engineering, ETC 5.160University of Texas at Austin, Austin, TX 78712-1084
P. Strobel
Affiliation:
CNRS, Laboratoire de Crystallographie 166X-38042 GRENOBLE Cedex (France)
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Abstract

The topotactic insertion/extraction of lithium in layered oxides and sulfides is compared with that in the oxo- and thiospinel frameworks [M2]X4 for both the technical interest of tailoring secondary-battery cathode materials and the scientific interest of exploring narrow-band phenomena and magnetic interactions in compounds and/or phases not accessible by conventional high-temperature techniques. It is pointed out that in layered LiyCoO 2 the higher voltages accessible in oxides is compatible with the higher Li+ -ion mobilities needed in power cells, but that fast three-dimensional Li+ -ion conduction in oxides requires a framework structure such as the monoclinic/orthorhombic Fe2(MO4)3 structure stabilized by M = Mo, W, and S. The influence of the counter cation on the working redox potential is illustrated by a 0.6 eV shift in the Fe3+/2+ redox couple on going from M = Mo or W to M = S.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 135: Symposium M – Solid State Ionics I , 1988 , 391
Copyright
Copyright © Materials Research Society 1989

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