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A Less Damaging Patterning Regime for a Successful Integration of Ultra Low-k Materials in Modern Nanoelectronic Devices

Published online by Cambridge University Press:  03 August 2011

Sven Zimmermann*
Affiliation:
Fraunhofer ENAS, Department Back-end of Line, D-09126 Chemnitz, Germany
Nicole Ahner
Affiliation:
Chemnitz University of Technology, Center for Microtechnologies, D-09107 Chemnitz, Germany
Tobias Fischer
Affiliation:
Chemnitz University of Technology, Center for Microtechnologies, D-09107 Chemnitz, Germany
Matthias Schaller
Affiliation:
GLOBALFOUNDRIES Inc., D-01109 Dresden, Germany
Stefan E. Schulz
Affiliation:
Fraunhofer ENAS, Department Back-end of Line, D-09126 Chemnitz, Germany Chemnitz University of Technology, Center for Microtechnologies, D-09107 Chemnitz, Germany
Thomas Gessner
Affiliation:
Fraunhofer ENAS, Department Back-end of Line, D-09126 Chemnitz, Germany Chemnitz University of Technology, Center for Microtechnologies, D-09107 Chemnitz, Germany
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Abstract

This paper describes a three-step process regime for the integration of porous SiCOH based ultra low-k materials in existing copper damascene technologies. During the work with these complex and sensitive materials, it became more and more clear, that a successful patterning depends not only on the etch step but also on the adjustment between the etch and the following cleaning and k-restore processes. The presented process regime starts with a reactive ion etch process for trench patterning followed by a post etch clean to remove etch residues. Finally a k-restore process was performed to repair the damaged regions in the trench sidewalls. In this work it became clear, that the etch chemistry influences not only the results of the etch process ostensibly sidewall damage but also kind and effect of the post etch clean. Each plasma composition results in the necessity of a customized post etch cleaning solution. Finally a k-restore process using Hexamethyldisilazane (HMDS) as restore chemical was demonstrated successfully. Enhanced temperatures and an additional UV-treatment are possibilities to promote the restore effect.

Type
Research Article
Copyright
Copyright © Materials Research Society 2011

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References

REFERENCES

[1] Baklanov, M.R. et al. : Proceedings of the 8th International Conference on Solid-State and Integrated Circuit Technology ICSICT 2006, pp. 291, 2006 Google Scholar
[2] Ahner, N., Schulz, S.E. et al. , ECS Trans. 25, Iss. 5 (2009), p. 87 Google Scholar
[3] Grill, A. et al. : Journal of Applied Physics, vol. 94, no. 10 (2003), pp. 6697 Google Scholar
[4] Uchida, S. et al. : Journal of Applied Physics, vol. 103 (2008), pp. 073303–1Google Scholar
[5] Zimmermann, S. et al. : Microelectronic Engineering, vol. 87 (2010), pp. 337 Google Scholar
[6] Coburn, J.W. et al. : IBM Journal of Research and Development, 23, no. 1 (1979), pp. 33 Google Scholar
[7] Fury, M.A., Electrochem. Soc. Proc., 200313 (2003), pp. 311 Google Scholar
[8] Rajagopalan, T. et al. , Appl. Surf. Sci. 252 (2006), pp. 6323 Google Scholar