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Intrinsic Material Limitations in Using Interphase Modification to Alter Fiber-Matrix Adhesion in Composite Materials.

Published online by Cambridge University Press:  21 February 2011

Lawrence T. Drzal*
Affiliation:
Department of Chemical Engineering and Composite Materials and Structures Center, Michigan State University, East Lansing, MI 48824-1326
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Abstract

A very large percentage of studies seeking to improve fiber-matrix adhesion to alter composite properties are directed at the formation of primary chemical bonds between the reinforcement surface and the matrix. The dynamic events that occur when the fiber-matrix interface is formed lead to the creation of an interphase which can have properties quite different from the matrix in addition to any chemical bond formation.

This study has been directed at elucidating the role of these interphase properties themselves on fiber-matrix adhesion. A reinforcement (AS-4 carbon fiber) with a quantifiable surface chemistry and an epoxy matrix have been kept constant through a series of experiments in which the distance between crosslinks of the matrix has been changed. The wettability of the fiber and the degree of chemical bonding to the fiber have not changed but the interfacial shear strength measured for each of these systems has decreased with decreasing matrix modulus. It will be shown that the properties of the matrix and the residual stresses created during processing limit the maximum interfacial shear stress that can be supported by the fiber-matrix interphase.

Type
Research Article
Copyright
Copyright © Materials Research Society 1990

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References

1. Drzal, L. T., “The Epoxy Interphase in Composites,” Review Chapter in Advances in Polymer Science II, Vol.75, Dusek, K., ed., Spring- Verlag, (1985).Google Scholar
2. Drzal, L. T., SAMPE Journal, 19, 7 (1983).Google Scholar
3. Drzal, L. T., Rich, M., and Lloyd, P., J. Adhesion, 16, 130, (1983).Google Scholar
4. Drzal, L. T., Rich, M., Koenig, M., and Lloyd, P., J. Adhesion, 16, 133— 152, (1983).Google Scholar
5. Agrawal, R., and Drzal, L. T., (accepted for publication in J. Adhesion).Google Scholar
6. Hammer, G., and Drzal, L.T., Appl. Surf. Sci., 4, 340 (1980).Google Scholar
7. Engineered Materials Handbook, Vol.1, ASM International (1987)Google Scholar
8. Kelly, A. and Tyson, W. R., Journal of Mechanics and Physics of Solids, 10, 199 (1963).Google Scholar
9. Rich, M. J., and Drzal, L.T., J. Rein. Plast. Comp. 1, 145 (1988).Google Scholar
10. Hook, K., Agrawal, R., and Drzal, L. T., submitted to J. Adhesion.Google Scholar
11. Rosen, B. W., Fibre Composite Materials, Amer. Soc. for Metals, Metals Park, OH (1965)Google Scholar
12. Cox, H. L. British Journal of Applied Physics, 3, 72 (1952).Google Scholar
13. Whitney, J. M. and Drzal, L.T., Toughened Composites, ASTM STP 937, 179196, American Society for Testing and Materials, Philadelphia (1987).Google Scholar
14. Rao, V. and Drzal, L. T., Polymer Composites, accepted for publication.Google Scholar
15. Drzal, L. T., Materials Science and Engineering, accepted for publication.Google Scholar
16. Drzal, L. T., Vacuum, submitted for publication.Google Scholar