Hostname: page-component-8448b6f56d-mp689 Total loading time: 0 Render date: 2024-04-23T10:55:19.668Z Has data issue: false hasContentIssue false

In-Situ Synthesis of Intermetallic Matrix Composites

Published online by Cambridge University Press:  15 February 2011

Dilip M. Shah
Affiliation:
Pratt & Whitney, 400 Main St., E. Hartford, CT. 06108
Donald L. Anton
Affiliation:
United Technologies Research Center, Silver Lane, E. Hartford, CT. 06108
Get access

Abstract

In pursuing the development of intermetallics as high temperature structural materials, a composite approach is considered necessary for achieving room temperature toughness. If not further qualified, the term “composite” generally implies the application of mechanical processes by which a strong reinforcing phase is dispersed in the matrix, often as aligned continuous fibers. While this approach appears simple and promising in principle, in practice it is limited by the availability of compatible fibers, controlled processing, and microstructural homogeneity and reproducibility. Alternatively, the composite microstructures may be created in-situ either synthetically or naturally. In synthetically derived composites, the desired phases may be deposited layer by layer using such techniques as chemical vapor deposition (CVD), and potentially a variety of lithographic techniques may be employed to control the microstructure. However, such techniques are currently rate limited and not well developed for the large dimensions required for structural composites. In contrast, the in-situ composites, which rely on phase separation by either eutectic solidification or solid state precipitation, are economical and especially well suited for generating naturally compatible ductile phase toughened composites with uniform fine scale microstructures. This paper attempts to classify these approaches in perspective, discuss the benefit of in-situ composites relying on the natural phase separation mechanisms, and review the current activities with emphasis on the concept of ductile phase toughening.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Brahney, J. H., Aerospace Engineering, August 1990, 17.Google Scholar
2. Anton, D. L. and Shah, D. M., in High Temperature Ordered Intermetallic Alloys IV, edited by Johnson, L. A., Pope, D. P. and Stiegler, J. O. (Mater. Res. Soc. Proc. 213, Pittsburgh, PA 1991)p.733.Google Scholar
3. Shah, D. M. and Anton, D. L. in High Temperature Ordered Intermetallic Alloys IV, edited by Johnson, L. A., Pope, D. P. and Stiegler, J. O. (Mater. Res. Soc. Proc. 2–3, Pittsburgh, PA 1991)p.63.Google Scholar
4. Fleisher, R.L., Briant, C..L. and Field, R. D. in High Temperature Ordered Intermetallic Alloys IV, edited by A.Johnson, L., Pope, D. P. and Stiegler, J. O. (Mater. Res. Soc. Proc. 213, Pittsburgh, PA 1991)p.463.Google Scholar
5. Anton, D. L. and Shah, D. M., This Proceedings.Google Scholar
6. Rowe, R. G. and Skelly, D. W., This Proceedings.Google Scholar
7 Ashby, M. F., in Strengthening Methods in Crystals, edited by Kelly, A. and Nicholson, R. B. ( Elsvier, New York, 1971)Google Scholar
8. Bouse, G. K. and Mihalisin, J. R. in Superalloys. Supercomposites and Superceramics, edited by Tien, J.K. and Caulfield, T. (Academic Press, Boston, 1989), p. 105.Google Scholar
9. Elliott, David J., Microlithography Process Technology for IC Fabrication, McGraw-Hill, New York, 1986.Google Scholar
10. Jain, Faquir C., University of Connecticut, (Private Communication).Google Scholar
11. Koskinen, J. and Johnson, H. H., Material Research Society Symposium Proceedings, 130,1989.Google Scholar
12 Gettelman, Ken M., “Stereolithography: Fast Model Making,” Modem Machine Shop, October 1989, pp. 100–107.Google Scholar
13. Ashby, M. F., Blunt, F. J. and Bannister, M., Acta Metall., 32 18471857, (1989).Google Scholar
14. Deve, H. E. and Maloney, M. J., Acta Metall. Mater., 32, 22752284, (1991).Google Scholar
15. Cao, H. C. et al., Acta Metall., 37, 29692977, (1989).Google Scholar
16. Shah, D. M. and Anton, D. L., Materials Science and Engineering A, A153, 402409,(1992)Google Scholar
17. Mazdiyasni, S. and Miracle, D. B. in Intermetallic Matrix Composites edited by Anton, D. L., Martin, P. L., Miracle, D. B. and McMeeking, R., (Mater. Res. Soc. Proc. 194, Pittsburgh, PA 1990)p.155.Google Scholar
18. Bertero, G., Hofmeister, W. H., Robinson, M. B. and Bayuzick, R. J., Met.Trans. A, 22, 2713(1991).CrossRefGoogle Scholar
19. Johnson, D., Joslin, S. and Oliver, Ben F., This Proceedings.Google Scholar
20. Chang, Keh-Minn, This Proceedings.Google Scholar
21. Pope, D. P. and Romanow, W. J. (Private Communication).Google Scholar
22. Darolia, R., JOM, March 1991, 44.Google Scholar
23. Subramanian, P. R. et al. in Intermetallic Matrix Composites edited by Anton, D. L., Martin, P. L., Miracle, D. B. and McMeeking, R., (Mater. Res. Soc. Proc. 194, Pittsburgh, PA 1990)p. 147.Google Scholar
24. Mendiratta, M. G., Levandowski, J. J. and Dimiduk, D. M., Metall. Trans. A, 22, 1573(1991).Google Scholar
25. Frommeyer, G., Rosenkranz, R. and Ludecke, C., Z. Metallkde, 81, 30(1990).Google Scholar
26. Es-Souni, M. et al. in Prc. Int. Symp. on Intermetallic Compounds (JIMIS-6), The Japan Institute of Metals, Sendai, 1991, p.525.Google Scholar
27. Sauthoff, G., Materials Science and Engineering, 1992, To be published.Google Scholar
28. Mason, D. and Aken, D. Van, in “High Temperature Intermetallic Matrix Composites,” DOD-G-AFOSR-90–0141 Annual Progress Report, March 1992, p. 15.Google Scholar
29. Thoma, D. J. and Perepezko, J. H., Material Science and Engineering, A155,1992, (To be published).Google Scholar
30. Anton, D. L. and Shah, D. M. in Intermetallic Matrix Composites edited by Anton, D. L., Martin, P. L., Miracle, D. B. and McMeeking, R., (Mater. Res. Soc. Proc. 194, Pittsburgh, PA 1990)p.45.Google Scholar