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Highly Conformal Diffusion Barriers of Amorphous Niobium Nitride

Published online by Cambridge University Press:  10 February 2011

R. G. Gordon
Affiliation:
Harvard University Chemical Laboratories, 12 Oxford Street, Cambridge, MA 02138
X. Liu
Affiliation:
Harvard University Chemical Laboratories, 12 Oxford Street, Cambridge, MA 02138
R. N. R. Broomhall-Dillard
Affiliation:
Harvard University Chemical Laboratories, 12 Oxford Street, Cambridge, MA 02138
Y. Shi
Affiliation:
Chemat Technology, Inc., 19365 Business Center Drive, Northridge, CA 91324
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Abstract

Electrically conductive films of niobium nitride were formed by chemical vapor deposition from tetrakis(diethylamido)niobium and ammonia. The films were found to be highly conformal, with step coverage nearly 100% for substrate temperatures near 350°C. The structure of the films was amorphous by diffraction of X-rays and electrons. The reliability of the films as barriers to diffusion of copper was also tested.

Type
Research Article
Copyright
Copyright © Materials Research Society 1999

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References

1. Rees, W. S., Jr., Editor, “CVD of Nonmetals,” VCH Publishers, Weinheim, Germany, 1996;10.1002/9783527614813Google Scholar
Jones, A. C. and O'Brien, P., “CVD of Compound Semiconductors,” VCH, 1996;10.1002/9783527614639Google Scholar
Kodas, T. and Hampden-Smith, M., Editors, “The Chemistry of Metal CVD,” VCH, 1994.10.1002/9783527615858Google Scholar
2. Eizenberg, M., Littau, K., Ghanayem, S., Liao, M., Mosely, R. and Sinha, A. K., J. Vac. Sci. Technol. A, 13, pp. 590595 (1995).10.1116/1.579791Google Scholar
3. Gordon, R. G., Fix, R. and Hoffman, D., US Patent 5,139,825 (1990).Google Scholar
4. Gordon, R. G., Lu, Y. Z. and Liu, Xinye, “Improved Conformality of CVD Titanium Nitride Films”, Proc. Mater. Res. Soc. Symp., Fall 1998 Meeting (in press, 1999).Google Scholar
5. “The National Technology Roadmap for Semiconductors: Technology Needs,” Semiconductor Industry Association, p. 101 (1997).Google Scholar
6. Smith, P. M., Custer, J. S., Jones, R. V., Maverick, A. W., Roberts, D. A., Norman, J. A. T., Hochberg, A. K., Bai, G., Reid, J. S. and Nicolet, M.-A., Conference Proceedings ULSI XI in 1995, p. 249 (Materials Research Soc., Pittsburgh, PA, 1996); Custer, J. S., Smith, P. M., Jones, R. V., Maverick, A. W., Roberts, D. A, Norman, J. A. T. and Hochberg, A. K., Mat. Res. Soc. Symp. Proc. 427, p. 343 (1996); J. W. Zhao, Z. Wang and W. G. Catabay, US Patent 5,770,520 (1998).Google Scholar
7. Clevenger, L. A., Bojarczuk, N. A., Holloway, K., Harper, J. M. E., C. Cabral Jr., Schad, R. G. and Stolt, L., J. Appl. Phys. 73, p. 300 (1993).Google Scholar
8. Ono, H. and Nakano, T., Japanese Patent Application JP 06275620 A2 940930 (1994).Google Scholar
9. Oya, G. and Ondera, Y., J. Appl. Phys. 45, p. 1389 (1974).10.1063/1.1663418Google Scholar
10. Hieber, K., Thin Solid Films 24, 157 (1974); H.-T. Chiu and W.-P. Chang, J. Mater. Sci. Lett. 11 570 (1992); M. H. Tsai, S. C. Sun, H.-T. Chiu, C. E. Tsai and S.-H. Chuang, Appl. Phys. Lett. 67, p. 1128 (1995).10.1016/0040-6090(74)90261-2Google Scholar
11. Fix, R., Gordon, R. G. and Hoffman, D., Chemistry of Materials 5, p.614 (1993).10.1021/cm00029a007Google Scholar
12. Bradley, D. C. and Thomas, L. H., Can J. Chem. 40, p. 449 (1962).10.1139/v62-072Google Scholar
13. Bradley, D. C. and Thomas, L. H., Can J. Chem. 40, p. 1355 (1962); Y. Takahasgi, N. Onoyama, Y. Ishikawa, S. Motojima and K. Sugiyama, Chem Lett., p. 525 (1978).10.1139/v62-207Google Scholar
14. Obtained from Intel Corporation.Google Scholar