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Exploratory Studies of New NLO and Piezoelectric Polymers

Published online by Cambridge University Press:  21 February 2011

H. K. Hall Jr. ,
Anne B. Padias ,
Francesco Fuso ,
Zhende NI ,
Michael A. Mitchell  and
Thomas M. Leslie
H. K. Hall Jr.
Affiliation:
Carl S. Marvel Laboratories, Chemistry Department, University of Arizona, Tucson, AZ 85721
Anne B. Padias
Affiliation:
Carl S. Marvel Laboratories, Chemistry Department, University of Arizona, Tucson, AZ 85721
Francesco Fuso
Affiliation:
Carl S. Marvel Laboratories, Chemistry Department, University of Arizona, Tucson, AZ 85721
Zhende NI
Affiliation:
Carl S. Marvel Laboratories, Chemistry Department, University of Arizona, Tucson, AZ 85721
Michael A. Mitchell
Affiliation:
Carl S. Marvel Laboratories, Chemistry Department, University of Arizona, Tucson, AZ 85721
Thomas M. Leslie
Affiliation:
Hoechst-Celanese Co., 86 Morris Avenue, Summit, NJ 07901
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Abstract

Synthetic efforts toward novel NLO and piezoelectric polymers are described. NLO-phores are incorporated in the main chain of a polymer with all the dipoles in the same direction by polycondensation of AB-monomers. The polymers containing p-alkoxy-α-cyanocinnamate units in the backbone show cooperative enhancement of SHG in solution. For comparison, p-thio-α-cyanocinnamate is incorporated in the main chain and in the side chain of polymers. Novel potentially piezoelectric polymers synthesized include polymers containing multicyanocyclobutyl or -cyclopropyl groups and acrylonitrile copolymers.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 175: Symposium S – Multifunctional Materials , 1989 , 51
Copyright
Copyright © Materials Research Society 1990

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References

1. Non-linear Optical and Electroactive Polymers, edited by Prasad, P.N. and Ulrich, D.R. (Plenum Press, New York, 1988).Google Scholar
2. Non-linear Optical Effects in Organic Polymers, edited by Messier, J., Kajzar, F., Prasad, P. and Ulrich, D. (Kluwer Academic Publishers, Dordrecht, 1989).Google Scholar
3. Willand, C.S., Feth, S.E., Scozzafava, M., Williams, D.J., Green, G.D., Weinschenk, J.I. III, Hall, H.K. Jr.., and Mulvaney, J.E., p. 107 in Ref. 1.Google Scholar
4. Green, G.D., Hall, H.K. Jr.,, Mulvaney, J.E., Noonan, J. and Williams, D.J., Macromolecules 20, 716 (1987).Google Scholar
5. Green, G.D., WEinschenk, J.I. III, Mulvaney, J.E. and Hall, H.K. Jr., Macromolecules 20, 722 (1987).Google Scholar
6. Fuso, F. and Hall, H.K. Jr., Macromolecules (submitted).Google Scholar
7. Paley, M.S., Harris, J.M., Looser, H., Baumert, J.C., Borklund, G.C., Jundt, D. and Twieg, R.J., J. Org. Chem. 54, 3774 (1989).Google Scholar
8. Ni, Z., Leslie, T.M. and Hall, H.K. Jr., Macromolecules (submitted).Google Scholar
9. Lovinger, A. J. in Developments in Crystalline Polymers, Vol. 1, edited by Bassett, D.C. (Applied Science, London, 1982).Google Scholar
10. Miyata, S., Yoshikawa, M., Tasaka, S., and Ko, M., Polymer Journal 12, 857 (1980).Google Scholar
11. Minkin, V.I., Osipov, O.A., and Zhdanov, Y.A., Dipole Moments in Organic Chemistry, translation edited by Vaughan, W.E., (Plenum Press, New York, 1970).Google Scholar
12. Dewar, M.J.S., Zoebisch, E.G., Healy, E.F., and Stewart, J.J.P., J. Am. Chem. Soc. 107, 3902 (1985).Google Scholar
13. Mori, S., Kakuchi, T., Padias, A.B. and Hall, H.K. Jr., J. Polym. Sci., Polym. Chem. Ed. (in press).Google Scholar
14. Padias, A.B. and Hall, H.K. Jr., J. Org. Chem. 52, 4536 (1987).Google Scholar
15. Yasuda, S., Wu, G.C., Tanaka, H., Sanui, K. and Ogata, N., J. Polym. Sci., Polym. Chem. Ed. 21, 2609 (1983).Google Scholar
16. Padias, A.B. and Hall, H.K. Jr., (manuscript in preparation).Google Scholar
17. Lee, J. Y. and Hall, H.K. Jr., (manuscript in preparation).Google Scholar
18. Hall, H.K. Jr., Blanchard, E.P. Jr., Cherkofsky, S.C., Sieja, J.B. and Sheppard, W.A., J. Am. Chem. Soc. 93, 110 (1971).Google Scholar
19. Barfield, M., Chan, R.J.H., Hall, H.K. Jr., and Mou, Y.H., Macromolecules 19, 1350 (1986).Google Scholar
20. Oku, J., Hall, H.K. Jr.,, Scheinbeim, J. and Newman, B., Polym. Bull. 17, 135 (1987).Google Scholar
21. Chen, C.S.H., J. Polym. Sci., Polym. Chem. Ed. 14, 2109 (1976).Google Scholar