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Eluding Metal Contamination in CMOS Front-End Fabrication by Nanocrystal Formation Process

Published online by Cambridge University Press:  20 April 2011

Zengtao Liu
Affiliation:
School of Electrical and Computer Engineering, Cornell University Ithaca, NY 14850
Chungho Lee
Affiliation:
School of Electrical and Computer Engineering, Cornell University Ithaca, NY 14850
Gen Pei
Affiliation:
School of Electrical and Computer Engineering, Cornell University Ithaca, NY 14850
Venkat Narayanan
Affiliation:
School of Electrical and Computer Engineering, Cornell University Ithaca, NY 14850
Edwin C. Kan
Affiliation:
School of Electrical and Computer Engineering, Cornell University Ithaca, NY 14850
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Abstract

A technique to form metal nanocrystals on silicon or thin SiO2 film by Rapid Thermal Annealing (RTA) of thin metal film is developed and integrated into standard CMOS processing to make EEPROM devices and improve metal-semiconductor contact resistance. I-V and C-V measurements are carried out on MOSFETs and MOS capacitors containing Au, Ag, Pt, and Si nanocrystals as floating gate for universal mobility and minority carrier lifetime extraction. Mobility around 300 cm2/V-sec and minority carrier lifetime within 0.02 ∼ 0.1 μsec are observed for all cases including the control samples that do not go through the metal nanocrystal formation process, which suggests that the substrate is virtually free from metal contamination. Using this technique, thicker metal film can potentially be achieved as well by stitching thin metal layers on top of the nanocrystals.

Type
Research Article
Copyright
Copyright © Materials Research Society 2002

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References

[1] Wong, H.-S. P., Frank, D. J., Solomon, P. M., Wann, C. H. J., and Welser, J. J., Proc. IEEE, 87, 537 (1999).Google Scholar
[2] Lu, Q., Yeo, Y. C., Ranade, P., Takeuchi, H., King, T.-J., Hu, C., Song, S. C., Luan, H. F., and Kwong, D., Proc. Symp. VLSI Technology, 72 (2000).Google Scholar
[3] Shimada, H., Hirano, Y., Ushiki, T., Ino, K., and Ohmi, T., IEEE Trans. Electron Devices, 44, 1903 (1997).Google Scholar
[4] Liu, Z., Narayanan, V., Kim, M., Pei, G., and Kan, E. C., Tech. Dig. Device Research Conference, 79 (2001).Google Scholar
[5] Kedzierski, J., Yuan, P., Anderson, E. H., Bokor, J., King, T.-J., and Hu, C., IEDM Tech. Dig., 57 (2000).Google Scholar
[6] Narayanan, V., Liu, Z., Shen, Y. N., Kim, M., and Kan, E. C., IEDM Tech. Dig., 365 (2000).Google Scholar
[7] Tucker, J. R., Proc. Advanced Workshop on Frontiers in Elec., 97 (1997).Google Scholar
[8] Campbell, S. A., The Science and Engineering of Microelectronic Fabrication, Oxford University Press (1996).Google Scholar
[9] Suo, Z. and Zhang, Z., Phys. Rev. B, 58, 5116 (1998).Google Scholar
[10] Bonnell, D. A., Liang, Y., Wagner, M., Carroll, D., and Bühle, M., Acta Mater., 46, 2263 (1998).Google Scholar
[11] Takagi, S., Toriumi, A., Iwase, M., and Tango, H., IEEE Trans. Electron Devices, 41, 2357 (1994).Google Scholar
[12] Pierret, R. F., IEEE Trans. Electron Devices, ED–19, 869 (1972).Google Scholar