Hostname: page-component-848d4c4894-75dct Total loading time: 0 Render date: 2024-05-09T03:18:50.082Z Has data issue: false hasContentIssue false
  • English
  • Français

Electrochemical Synthesis and Characterization of NaCuO2

Published online by Cambridge University Press:  21 February 2011

Gerald L. Roberts  and
Susan M. Kauzlarich
Gerald L. Roberts
Affiliation:
Department of Chemistry, University of California, Davis, CA 95616 Chemistry and Materials Science Department, University of California, Lawrence Livermore National Laboratory Livermore, CA 94550
Susan M. Kauzlarich
Affiliation:
Department of Chemistry, University of California, Davis, CA 95616
Get access

Abstract

NaCuO2 has been prepared via electrodeposition from a sodium hydroxide/potassium hydroxide melt and characterized by single crystal and powder X-ray diffraction, magnetic susceptibility, and resistivity. Clusters of blue-black plate-like and needle crystals are grown at positive potentials on a platinum anode with a platinum or a zirconium crucible serving as the cathode and a platinum reference electrode. Details of the electrochemical procedure are described, along with a cyclic voltammogram. NaCuO2 exhibits temperature independent paramagnetism over the temperature range 30 – 300 K. Its room temperature resistivity is greater than 106 Ω-cm.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 346: Symposium N – Better Ceramics Through Chemistry VI , 1994 , 457
Copyright
Copyright © Materials Research Society 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1 (a) Hoppe, R., Hestermann, V.K., Schenk, F., Z. anorg. Chem. 367, 275 (1969). (b) V.K. Hestermann, R. Hoppe, ibid., 367, 261 (1969); ibid., 367, 270 (1969); V.K. Wahl, W. Klemm, ibid., 270,69 (1952).Google Scholar
2 Pickardt, J., Paulus, W., Schmalz, M., Schollhorn, R., J. Sol. State Chem. 89, 308 (1990).Google Scholar
3 Norton, M. L., Tang, H., Chem. Mater. 3, 431 (1991).Google Scholar
4 Nagata, Y., Suzuki, N., Uchida, T., Mosley, W. D., Klavins, P., Shelton, R. N., Physica C 195, 195 (1992).Google Scholar
5 Chaillout, C., Dürr, J., Escribe-Filippini, C., Fournier, T., Marcus, J., Marezio, M., J. Sol. State Chem. 93, 63 (1991).Google Scholar
6 Rosamilia, J. M., Glarum, S. H., Cava, R. J., Batlogg, B., Miller, B., Physica C 182, 285 (1991).Google Scholar
7 Bezzenberger, R., Schollhorn, R., Eur. J. Sol. State Inorg. Chem. 30, 435 (1993).Google Scholar
8 Friedman, T. L., Stacy, A. M., J. Sol. State Chem. 109, 203 (1994).Google Scholar
9 Roberts, G. L., Kauzlarich, S. M., Glass, R. S., J. C. Estill, Chem. Mater. 5, 1645 (1993).Google Scholar
10 Macdonald, D. D., J. Electrochera Soc. 12, 651 (1974).Google Scholar
11 Slezak, P., Wieckowski, A., J. Electrochem. Soc. 138, 1038 (1991).Google Scholar
12 Castro, A. M., Medina, Lunade, Marchiano, S. L., Arvi'a, A. J., J. Appl. Electrochem. 8, 121 (1978).Google Scholar
13 Ambrose, J., Barradas, R. G., Shoesmith, D. W., Electroanalytical Chemistry and Interfacial Electrochemistry 47, 47 (1973).Google Scholar
14 Bard, A. J., Eds., Encyclopedia of the Electrochemistry of the Elements, vol. 2 (Dekker, 1974).Google Scholar
15 Raspi, G., Zanello, P., Cinquantini, A., Corti, P., Analytica Chimica Acta 66, 435 (1973).Google Scholar
16 Ogorevc, B., Tavcar, G., Hudnik, V., Pejovnik, S., J. Electroanal. Chem. 351, 81 (1993).Google Scholar
17 Hampson, N. A., Lee, J. B., Macdonald, K. I., J. Electroanal. Chem. 32, 165 (1971).Google Scholar
18 Russo, R. E., McLarnon, F. R., Spear, J. D., Caims, E. J., J. Electrochem. Soc. 134, 2783 (1987).Google Scholar
19 Eluard, A., Tremillon, B., J. Electroanal. Chem. 18, 277 (1968).Google Scholar
20 Pourbaix, M., Atlas of Electrochemical Equilibria in Aqueous Solutions (Pergamon Press, New York, 1966).Google Scholar
21 Weiser, H. B., Inorganic Colloid Chemistry: The Hydrous Oxides and Hydroxides (John Wiley & Sons, Inc., New York, 1935), vol. 2.Google Scholar
22 Inman, D., White, S. H., J. Appl. Electrochem. 8, 375 (1978).Google Scholar
23 Imai, K., Koike, M., Sawa, H., Takei, H., J. Cryst. Growth 128, 808 (1993); K. Imai, M. Koike, H. Takei, H. Sawa, D. Shiomi, K. Nozawa, M. Kinoshita, J. Phys. Soc. Jap. 61, 1819(1992).Google Scholar