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Electrically Air-stable ZnO Thin Film Produced by Reactive RF Magnetron Sputtering for Thin Film Transistors Applications

Published online by Cambridge University Press:  31 January 2011

Divine Ngwashi
Affiliation:
dngwashi@dmu.ac.ukndkhan33@yahoo.co.uk
Richard B. M. Cross
Affiliation:
rcross@dmu.ac.uk, De Montfort University, Emerging Technologies Research Centre, The Gateway, Leicester, LE1 9BH, United Kingdom
Shashi Paul
Affiliation:
spaul@dmu.ac.uk, De Montfort University, Emerging Technologies Research Centre, Hawthorn Building, The Gateway, Leicester, LE1 9BH, United Kingdom
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Abstract

The influence of native point defects on the electrical and optical stability of zinc oxide (ZnO) layers in air produced by reactive RF magnetron sputtering is investigated. ZnO thin films are strongly affected by oxygen (O2) molecules in ambient atmosphere. For instance, surface defects such as oxygen vacancies act as adsorption sites of O2 molecules, and the chemisorption of O2 molecules depletes the surface electronic states and reduces channel conductivity. Thin films of ZnO produced have electrical resistivities between 8.6 × 103 and 8.3 × 108 Ω-cm, and were found to be electrically-stable in air. TFTs fabricated using these films exhibited effective mobilities of ∼3 cm2V-1s-1 and the threshold voltage shifts by < 5 V under gate bias stress of 1 MV/cm for up to 104 s.

Type
Research Article
Copyright
Copyright © Materials Research Society 2010

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